Chemistry:Thulium acetylacetonate

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Thulium acetylacetonate
File:Tris(acetylacetonato)thulium.png
Names
Other names
Thulium(III) acetylacetonate
Identifiers
3D model (JSmol)
ChemSpider
Properties
C15H21O6Tm
Molar mass 466.261 g·mol−1
Appearance powder[1]
white powder (trihydrate)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Thulium acetylacetonate is a coordination complex with the chemical formula Tm(C5H7O2)3, or Tm(acac)3 for short. It can be prepared by the reaction of thulium hydroxide and ethanol solution of acetylacetone.[3] Its monohydrate is not volatile in vacuum.[4] The acetonitrile solution of its dihydrate and the dichloromethane solution of 5-[(4-fluorobenzylidene)amino]-8-hydroxyquinoline (HL) react by heating to obtain the complex [Tm4(acac)6(L)63-OH)2].[5]

References

  1. Pierson, H.O. (1999). Handbook of Chemical Vapor Deposition: Principles, Technology and Applications. Materials Science and Process Technology. Elsevier Science. p. 92. ISBN 978-0-8155-1743-6. https://books.google.com/books?id=GIsa4vuJgcUC&pg=PA92. Retrieved 2021-09-16. 
  2. Perry, D.L. (2016). Handbook of Inorganic Compounds. CRC Press. p. 494. ISBN 978-1-4398-1462-8. https://books.google.com/books?id=SFD30BvPBhoC&pg=PA494. Retrieved 2021-09-16. 
  3. Spencer, J.F. (1919). The Metals of the Rare Earths. Monographs on inorganic and physical chemistry. Longmans, Green. p. 153. https://books.google.com/books?id=4xBDAAAAIAAJ&pg=PA153. Retrieved 2021-09-16. 
  4. Friend, J.N. (1917). A Text-book of Inorganic Chemistry. Griffin. p. 438. https://books.google.com/books?id=CwxDAAAAIAAJ&pg=PA438. Retrieved 2021-09-16. 
  5. Hong-Ling Gao; Li Jiang; Shuang Liu; Hai-Yun Shen; Wen-Min Wang; Jian-Zhong Cui (2016). "Multiple magnetic relaxation processes, magnetocaloric effect and fluorescence properties of rhombus-shaped tetranuclear rare earth complexes" (in en). Dalton Transactions 45 (1): 253–264. doi:10.1039/C5DT03790E. ISSN 1477-9226. PMID 26600114. http://xlink.rsc.org/?DOI=C5DT03790E. Retrieved 2021-09-20. 

External reading