Chemistry:Vanadium(III) bromide
-iodid.png)
| |
| Names | |
|---|---|
| IUPAC name
Vanadium(III) bromide
| |
| Other names
Vanadium tribromide
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| RTECS number |
|
| |
| |
| Properties | |
| VBr3 | |
| Molar mass | 290.654 g/mol |
| Appearance | Green-black solid |
| Density | 4 g/cm3 |
| soluble | |
| Solubility | soluble in THF (forms adduct) |
| +2890.0·10−6 cm3/mol | |
| Structure | |
| octahedral | |
| Related compounds | |
Other anions
|
Vanadium(III) chloride |
Other cations
|
Titanium(III) bromide Molybdenum(III) bromide |
Related compounds
|
Vanadium(II) bromide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
| |
| Infobox references | |
Vanadium(III) bromide, also known as vanadium tribromide, describes the inorganic compounds with the formula VBr3 and its hydrates. The anhydrous material is a green-black solid. In terms of its structure, the compound is polymeric with octahedral vanadium(III) surrounded by six bromide ligands.
Preparation
VBr3 has been prepared by treatment of vanadium tetrachloride with hydrogen bromide:
- 2 VCl4 + 8 HBr → 2 VBr3 + 8 HCl + Br2
The reaction proceeds via the unstable vanadium(IV) bromide (VBr4), which releases Br2 near room temperature.[1]
It is also possible to prepare vanadium(III) bromide by reacting bromine with vanadium or ferrovanadine:[2]
- 2 V + 3 Br2 → 2 VBr3
- 2 VFe + 6 Br2 → 2 VBr3 + FeBr3
Properties
Physical
Vanadium(III) bromide is present in the form of black, leafy, very hygroscopic crystals with a sometimes greenish sheen. It is soluble in water with green color. Its crystal structure is isotypic to that of vanadium(III) chloride with space group R3c (space group no. 167), a = 6.400 Å, c = 18.53 Å. When heated to temperatures of around 500 °C, a violet gas phase is formed, from which, under suitable conditions, red vanadium(IV) bromide can be separated by rapid cooling, which decomposes at −23 °C.[2]
Chemical
Like vanadium(III) chloride, vanadium(III) bromide forms red-brown soluble complexes with dimethoxyethane and THF, such as mer-VBr3(THF)3.[3]
Aqueous solutions prepared from VBr3 contain the cation trans-[VBr2(H2O)4]+. Evaporation of these solutions give the salt trans-[VBr2(H2O)4]Br.(H2O)2.[4]
Further reading
- Stebler, A.; Leuenberger, B.; Guedel, H. U. "Synthesis and crystal growth of A3M2X9 (A = Cs, Rb; M = Ti, V, Cr; X = Cl, Br)" Inorganic Syntheses (1989), volume 26, pages 377–85.
References
- ↑ Calderazzo, Fausto; Maichle-Mössmer, Cäcilie; Pampaloni, Guido; Strähle, Joachim (1993). "Low-Temperature Syntheses of Vanadium(III) and Molybdenum(IV) Bromides by Halide Exchange". J. Chem. Soc., Dalton Trans. (5): 655–658. doi:10.1039/DT9930000655.
- ↑ 2.0 2.1 Brauer, Georg (1981). Handbuch der präparativen anorganischen Chemie. 3 (3., umgearb. ed.). Stuttgart: Enke. ISBN 978-3-432-87823-2. https://de.wikipedia.org/wiki/Spezial:ISBN-Suche/3432878230.
- ↑ G. W. A. Fowles, G. W. A.; Greene, P. T.; Lester, T. E. "Ether Complexes of Tervalent Titanium and Vanadium" J. Inorg, Nucl. Chem., 1967. Vol. 29. pp. 2365 to 2370.
- ↑ Donovan, William F.; Smith, Peter W. (1975). "Crystal and Molecular Structures of Aquahalogenovanadium(III) Complexes. Part I. X-Ray Crystal Structure of trans-Tetrakisaquadibromo-Vanadium(III) Bromide Dihydrate and the Isomorphous Chloro- Compound". Journal of the Chemical Society, Dalton Transactions (10): 894. doi:10.1039/DT9750000894.
 |  |
