Chemistry:Zavaritskite

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Zavaritskite
Zavaritskite-89398.jpg
General
CategoryHalide mineral
Formula
(repeating unit)
(BiO)F
Strunz classificationIII/D.10-70
Dana classification10.02.01.01
Crystal systemTetragonal
Crystal classHalide mineral
Identification
ColorColorless to white
Mohs scale hardness2–2.5
|re|er}}Resinous to metallic
StreakGray white
DiaphaneitySubtranslucent to opaque
Specific gravity8.44 gm/cc
Density7.88–9.00 (on average 8.44) g/sm3
Optical propertiesUniaxial (+/−), a = 2.21, b = 2.213, bire = 0.0030
Refractive indexnα = 2.210, nβ = 2.213
Birefringenceδ = 2.210

Zavaritskite is a rare mineral of the halide class, bismuth oxyhalide with the chemical formula (BiO)F.[1][2] It is named after the Soviet geologist and petrographer, academician of the USSR Academy of Sciences Alexander Nikolaevich Zavaritsky. It was discovered in 1962 by Soviet scientists. Zavaritskite is part of matlockite group of minerals.[3][4][5]

Description

Zavaritskite is a gray mineral with a greasy or semi-metallic luster; opaque, only slightly translucent in very small grains. The mineral powder is finely dispersed, colorless. The crystallization process of zavaritskite occurs in a square system, due to which the mineral forms sufficiently fine-grained powder cryptocrystalline aggregates.

The mineral is usually found together with bismuth, topaz, fluorite and others in the oxidized zone of the Sherlovogorsky deposit in Transbaikal. Zavaritskite was first described in 1962 by Soviet scientists E. I. Dolomanova, V. M. Senderova, and M. T. Yanchenko.[6] It is one of the oxidation products of bismuthine, it is extremely rare.

Formation and locations

Zavaritskite is formed secondarily as a weathering product of bismuthinite in bismuth-containing ore deposits. In addition to solid bismuth and bismuthinite, the mineral can also occur in paragenesis with bismutite and gold, among others.

As a rare mineral formation, zavaritskite has only been detected at a few sites, although so far (as of 2018) about 20 sites are known. In addition to Sherlovaya Gora in Russia , zavaritskite was discovered in quartz-topaz-siderophyllite greisen, which cut a granite pluton. Also, the mineral was discovered in Russia at the Nevskoe tungsten-tin deposit near Omsukchan in the Magadan Oblast, at Pitkyaranta in the Republic of Karelia, and at Mount Ploskaya in the Keivy Mountains on the Kola Peninsula.

Other known sites to date are Fielders Hill near Torrington (Clive County) and the Elsmore tin mine in Inverell Shire (Gough County) in the Australian state of New South Wales; the Beauvoir quarry near Échassières in the French département of Allier; the Ebisu pits near Nakatsugawa and Ashio near Nikkō on the Japanese island of Honshu; and several others.[7]

References