Chemistry:Diphenylphosphite

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Diphenylphosphite
Diphenylphosphite.png
Names
Preferred IUPAC name
Diphenyl phosphonate
Other names
Phosphonic acid, diphenyl ester
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
UNII
Properties
C12H11O3P
Molar mass 234.191 g·mol−1
Appearance colorless liquid
Density 1.2268 g/cm3
Melting point 12 °C (54 °F; 285 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Diphenylphosphite is a diorganophosphite with the formula (C6H5O)2P(O)H. The molecule is tetrahedral. It is a colorless viscous liquid. The compounds can be prepared by treating phosphorus trichloride with phenol. Many analogues can be prepared similarly. One illustrative reaction, diphenylphosphite, aldehydes, and amines react to afford aminophosphonates (Kabachnik–Fields reaction).[1]

See also

References

  1. Bhagat, Srikant; Chakraborti, Asit K. (2007). "An Extremely Efficient Three-Component Reaction of Aldehydes/Ketones, Amines, and Phosphites Kabachnik-Fields reaction for the Synthesis of α-Aminophosphonates Catalyzed by Magnesium Perchlorate". Journal of Organic Chemistry 72 (4): 1263–1270. doi:10.1021/jo062140i. PMID 17253748.