Biology:(+)-car-3-ene synthase
From HandWiki
Short description: Class of enzymes
| (+)-car-3-ene synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 4.2.3.107 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
(+)-Car-3-ene synthase (EC 4.2.3.107, 3-carene cyclase, 3-carene synthase, 3CAR, (+)-3-carene synthase) is an enzyme with systematic name geranyl-diphosphate diphosphate-lyase [cyclizing, (+)-car-3-ene-forming].[1][2][3][4][5][6] This enzyme catalyses the following chemical reaction
- geranyl diphosphate [math]\displaystyle{ \rightleftharpoons }[/math] (+)-car-3-ene + diphosphate
The enzyme reacts with (3S)-linalyl diphosphate twice as rapidly as geranyl diphosphate.
References
- ↑ "Biosynthesis of monoterpenes: regio- and stereochemistry of (+)-3-carene biosynthesis". Archives of Biochemistry and Biophysics 305 (2): 581–7. September 1993. doi:10.1006/abbi.1993.1464. PMID 8373196.
- ↑ "Monoterpene synthases from gymnosperms and angiosperms: stereospecificity and inactivation by cysteinyl- and arginyl-directed modifying reagents". Archives of Biochemistry and Biophysics 320 (2): 257–65. July 1995. doi:10.1016/0003-9861(95)90008-x. PMID 7625832.
- ↑ "Monoterpene synthases of Pinus contorta and related conifers. A new class of terpenoid cyclase". The Journal of Biological Chemistry 269 (6): 4012–20. February 1994. doi:10.1016/S0021-9258(17)41735-2. PMID 8307957.
- ↑ "Traumatic resin defense in Norway spruce (Picea abies): methyl jasmonate-induced terpene synthase gene expression, and cDNA cloning and functional characterization of (+)-3-carene synthase". Plant Molecular Biology 51 (1): 119–33. January 2003. doi:10.1023/A:1020714403780. PMID 12602896.
- ↑ "Targeted isolation, sequence assembly and characterization of two white spruce (Picea glauca) BAC clones for terpenoid synthase and cytochrome P450 genes involved in conifer defence reveal insights into a conifer genome". BMC Plant Biology 9: 106. August 2009. doi:10.1186/1471-2229-9-106. PMID 19656416.
- ↑ "An integrated genomic, proteomic and biochemical analysis of (+)-3-carene biosynthesis in Sitka spruce (Picea sitchensis) genotypes that are resistant or susceptible to white pine weevil". The Plant Journal 65 (6): 936–48. March 2011. doi:10.1111/j.1365-313x.2010.04478.x. PMID 21323772.
External links
- (+)-car-3-ene+synthase at the US National Library of Medicine Medical Subject Headings (MeSH)
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