Biology:(-)-Isopiperitenone reductase
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Short description: Class of enzymes
(-)-isopiperitenone reductase | |||||||||
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Identifiers | |||||||||
EC number | 1.3.1.82 | ||||||||
Databases | |||||||||
IntEnz | IntEnz view | ||||||||
BRENDA | BRENDA entry | ||||||||
ExPASy | NiceZyme view | ||||||||
KEGG | KEGG entry | ||||||||
MetaCyc | metabolic pathway | ||||||||
PRIAM | profile | ||||||||
PDB structures | RCSB PDB PDBe PDBsum | ||||||||
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(-)-Isopiperitenone reductase (EC 1.3.1.82) is an enzyme with systematic name (+)-cis-isopulegone:NADP+ oxidoreductase.[1][2] It catalyses the following chemical reaction:
- (+)-cis-isopulegone + NADP+ [math]\displaystyle{ \rightleftharpoons }[/math] (-)-isopiperitenone + NADPH + H+
The reaction occurs in the opposite direction.
References
- ↑ "Metabolism of monoterpenes: demonstration that (+)-cis-isopulegone, not piperitenone, is the key intermediate in the conversion of (-)-isopiperitenone to (+)-pulegone in peppermint (Mentha piperita)". Archives of Biochemistry and Biophysics 249 (2): 306–15. September 1986. doi:10.1016/0003-9861(86)90007-x. PMID 3755881.
- ↑ "Monoterpene double-bond reductases of the (-)-menthol biosynthetic pathway: isolation and characterization of cDNAs encoding (-)-isopiperitenone reductase and (+)-pulegone reductase of peppermint". Archives of Biochemistry and Biophysics 418 (1): 80–92. October 2003. doi:10.1016/s0003-9861(03)00390-4. PMID 13679086.
External links
- (-)-isopiperitenone+reductase at the US National Library of Medicine Medical Subject Headings (MeSH)