Biology:(4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing)
From HandWiki
Short description: Class of enzymes
| β-phellandrene synthase (geranyl-diphosphate-cyclizing) | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 4.2.3.52 | ||||||||
| CAS number | 137010-34-5 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
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β-Phellandrene synthase (EC 4.2.3.52, geranyl-diphosphate-cyclizing) (phellandrene synthase, (−)-β-phellandrene synthase, (−)-(4S)-β-phellandrene synthase) is an enzyme with systematic name geranyl-diphosphate diphosphate-lyase (cyclizing; β-phellandrene-forming).[1][2][3][4] This enzyme catalyses the following chemical reaction
- geranyl diphosphate [math]\displaystyle{ \rightleftharpoons }[/math] β-phellandrene + diphosphate
This enzyme requires ion Mn2+.
References
- ↑ "Monoterpene synthases of Pinus contorta and related conifers. A new class of terpenoid cyclase". The Journal of Biological Chemistry 269 (6): 4012–20. February 1994. PMID 8307957.
- ↑ "cDNA cloning, characterization, and functional expression of four new monoterpene synthase members of the Tpsd gene family from grand fir (Abies grandis)". Archives of Biochemistry and Biophysics 368 (2): 232–43. August 1999. doi:10.1006/abbi.1999.1332. PMID 10441373.
- ↑ "Isotopically sensitive branching as a tool for evaluating multiple product formation by monoterpene cyclases". Tetrahedron 31: 5933–5944. 1991. doi:10.1016/s0040-4020(01)86486-3.
- ↑ "Hydride shifts in the biosynthesis of the p-menthane monoterpenes alpha-terpinene, gamma-terpinene, and beta-phellandrene". Archives of Biochemistry and Biophysics 301 (2): 361–6. March 1993. doi:10.1006/abbi.1993.1156. PMID 8460944.
External links
- (4S)-beta-phellandrene+synthase+(geranyl-diphosphate-cyclizing) at the US National Library of Medicine Medical Subject Headings (MeSH)
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