Biology:7-epi-alpha-selinene synthase

From HandWiki
Short description: Enzyme
7-epi-α-selinene synthase
Identifiers
EC number4.2.3.86
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum

7-epi-α-Selinene synthase (EC 4.2.3.86) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase (7-epi-α-selinene-forming).[1][2] This enzyme catalyses the following chemical reaction

(2E,6E)-farnesyl diphosphate [math]\displaystyle{ \rightleftharpoons }[/math] 7-epi-α-selinene + diphosphate

The recombinant enzyme from Vitis vinifera forms (+)-valencene and (−)-7-epi-α-selinene.

References

  1. "Vitis vinifera terpenoid cyclases: functional identification of two sesquiterpene synthase cDNAs encoding (+)-valencene synthase and (−)-germacrene D synthase and expression of mono- and sesquiterpene synthases in grapevine flowers and berries". Phytochemistry 65 (19): 2649–59. October 2004. doi:10.1016/j.phytochem.2004.08.017. PMID 15464152. 
  2. "The bouquet of grapevine (Vitis vinifera L. cv. Cabernet Sauvignon) flowers arises from the biosynthesis of sesquiterpene volatiles in pollen grains". Proceedings of the National Academy of Sciences of the United States of America 106 (17): 7245–50. April 2009. doi:10.1073/pnas.0901387106. PMID 19359488. 

External links