Chemistry:Bannisterite

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Short description: Silicate mineral
Bannisterite
Bannisterite-d05-124a.jpg
General
CategoryMineral
Formula
(repeating unit)
(Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2O n ~ 5.5
Strunz classification9.EG.75
Dana classification74.1.1.4
Crystal systemMonoclinic
Crystal classPrismatic
H-M Symbol: 2/m
Space groupB2/b
Unit cell8,955.48
Identification
ColorDark brown
CleavagePerfect on {001}
FractureMicaceous
Mohs scale hardness4
|re|er}}Sub-vitreous, resinous, greasy
StreakCreamy white
DiaphaneityTranslucent
Specific gravity2.83 - 2.84
Density2.83 - 2.84
Optical propertiesBiaxial (-)
Refractive indexnα = 1.544 - 1.574
nβ = 1.586 - 1.611
nγ = 1.589 - 1.612
Birefringence0.045
PleochroismVisible
2V angle18°- 28°
DispersionWeak to moderate
r < v
Ultraviolet fluorescenceNone
Common impuritiesZn, Na

Bannisterite is a mineral named in honor of mineralogist and x-ray crystallographer Dr. Frederick Allen Bannister (1901-1970). It is a calcium-dominant member of the ganophyllite group, and was previously identified as ganophyllite in 1936, but otherwise it is structurally related to the stilpnomelane group. It was approved by the IMA in 1967.[2]

Properties

Bannisterite grows in flat platy aggregates. It has smooth cleavages without ruling. It is a pleochroic mineral, which is an optical phenomenon. Depending on which axis the mineral is being inspected on, it appears as it changes colors. on the x axis, the mineral is seen in a colorless to pale yellow color. Common impurities include zinc and sodium. It occurs in sulfuric zinc deposits, as well as at silicate-carbonate hosted zinc deposits. It is associated with quartz, baryte, fluorite, rhodonite, sphalerite, galena, calcite, the apophyllite group and the amphibole supergroup. It doesn't have luminescent properties, under long, or shortwave ultraviolet light. It has a type locality in the Benallt mine in Wales, United Kingdom, and in the Franklin mine, New Jersey, United States.[2] It mainly consists of oxygen (44.64%) silicon (21.43%) and manganese (17.95%), but otherwise contains iron (5.23%), zinc (3.68%), aluminum (2.17%), magnesium (1.89%), hydrogen (1.09%), calcium (0.97%), potassium (0.84%) and sodium (0.12%). It is bladed, meaning it has thin lath-like crystals, and is prismatic, meaning the shape of the crystals are slender prisms. It has a barely detectable radioactivity due to it containing potassium. It has a 11.93 radioactivity measured in Gamma Ray American Petroleum Institute units. The concentration of the mineral measured per GRapi units is 8.39%.[3]

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  2. 2.0 2.1 "Bannisterite". https://www.mindat.org/min-509.html. 
  3. "Bannisterite Mineral Data". http://webmineral.com/data/Bannisterite.shtml#.YVF7nUZBzrs.