Chemistry:Rhodonite
| Rhodonite | |
|---|---|
 Rhodonite from San Martín Mine, Chiurucu, Huallanca District, Bolognesi Province, Ancash, Peru Specimen size: 53 mm × 52 mm × 40 mm (2.1 in × 2.0 in × 1.6 in) | |
| General | |
| Category | Inosilicate |
| Formula (repeating unit) | (Mn2+, Fe2+, Mg, Ca)SiO3 |
| Strunz classification | 9.DK.05 |
| Dana classification | 65.04.01.01 |
| Crystal system | Triclinic |
| Crystal class | Pinacoidal (1) (same H–M symbol) |
| Space group | P1 |
| Unit cell | a = 9.758 Å, b = 10.499 Å, c = 12.205 Å; α = 108.58°, β = 102.92°, γ = 82.52°; Z = 20 |
| Identification | |
| Color | Pink, rose-pink to brownish red, red, gray and yellow |
| Crystal habit | Tabular crystals, massive, granular |
| Twinning | Lamellar, composition plane {010} |
| Cleavage | Perfect on {110} and {110}, (110) ^ (110) = 92.5°; good on {001} |
| Fracture | Conchoidal to uneven |
| Mohs scale hardness | 5.5–6.5 |
| |re|er}} | Vitreous to pearly |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Specific gravity | 3.57–3.76 |
| Optical properties | Biaxial (+) |
| Refractive index | nα = 1.711–1.738, nβ = 1.714–1.741, nγ = 1.724–1.751 |
| Birefringence | δ = 0.013 |
| Pleochroism | Weak |
| 2V angle | 58° to 73° (measured), 58° (calculated) |
| Alters to | Exterior commonly black from manganese oxides |
| References | [1][2][3] |
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from grc ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).[5]
Rhodonite crystals often have a thick tabular habit, but are rare. It has a perfect, prismatic cleavage, almost at right angles. The hardness is 5.5–6.5, and the specific gravity is 3.4–3.7; luster is vitreous, being less frequently pearly on cleavage surfaces. The manganese is often partly replaced by iron, magnesium, calcium, and sometimes zinc, which may sometimes be present in considerable amounts; a greyish-brown variety containing as much as 20% of calcium oxide is called bustamite; fowlerite is a zinciferous variety containing 7% of zinc oxide.
The inosilicate (chain silicate) structure of rhodonite has a repeat unit of five silica tetrahedra. The rare polymorph pyroxmangite, formed at different conditions of pressure and temperature, has the same chemical composition but a repeat unit of seven tetrahedra.
Rhodonite has also been worked as an ornamental stone. In the iron and manganese mines at Pajsberg near Filipstad and Långban in Värmland, Sweden, small brilliant and translucent crystals (pajsbergite) and cleavage masses occur. Fowlerite occurs as large, rough crystals, somewhat resembling pink feldspar, with franklinite and zinc ores in granular limestone at Franklin Furnace in New Jersey.
Rhodonite is the official gemstone of the Commonwealth of Massachusetts.[6]
See also
- Enstatite, with MgSiO3 and FeSiO3 end-members
- Khondalite
- Wollastonite, CaSiO3
References
- ↑ Handbook of Mineralogy.
- ↑ Rhodonite, Mindat.org.
- ↑ Rhodonite, Webmineral data.
- ↑ Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ "Minerals Colored by Metal Ions". http://minerals.gps.caltech.edu/color_causes/Metal_Ion/index.html.
- ↑ General Laws of Massachusetts, Chapter 2, Section 15 .
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