Chemistry:Coconinoite
| Coconinoite | |
|---|---|
 | |
| General | |
| Category | Phosphate minerals |
| Formula (repeating unit) | Fe3+2Al2(UO2)2(PO4)4(SO4)(OH)2•20(H2O) |
| Strunz classification | 8.EB.35 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | C2/c |
| Unit cell | a = 12.45(6) Å, b = 12.96(3) Å, c = 17.22(5) Å; β = 105.7°; Z = 4 |
| Identification | |
| Formula mass | 489.01 gram/mol |
| Color | Pale creamy yellow |
| Crystal habit | As lathlike to platy grains, in microcrystalline aggregates seams and crusts. |
| Mohs scale hardness | 1-2 |
| |re|er}} | Adamantine - pearly |
| Streak | White |
| Diaphaneity | Translucent |
| Specific gravity | 2.70 |
| Optical properties | Biaxial (-) |
| Refractive index | nα = 1.550 nβ = 1.588 nγ = 1.590 |
| Birefringence | δ = 0.040 |
| Pleochroism | X = colorless; Y = Z = pale yellow. Orientation: Y = elongation of laths with positive elongation; Y at 8°-25° to elongation of laths with negative elongation. |
| 2V angle | Measured: 28° to 43°, Calculated: 24° |
| Other characteristics |  Radioactive |
| References | [1][2][3] |
Coconinoite is a uranium ore that was discovered in Coconino County, Arizona. It is a phosphate mineral; or uranyl phosphate mineral along with other subclass uranium U6+ minerals like blatonite, boltwoodite, metazeunerite and rutherfordine.
Composition
The chemical formula is Fe2Al2(UO2)2(PO4)4(SO4)(OH)2·20H2O.[5] The chemical formula was derived from the spectrographic analysis.[5]
Physical properties
The mineral has a white streak and a pale creamy yellow color. The mineral occurs as microscopic crystals, the largest found is 6 by 20 micrometers. It is a radioactive mineral, but not fluorescent.[5] Upon heating for dehydration it is found that the mineral loses some of its SO2 at 600 to 800 °C.
Geologic occurrence
It occurs in the oxidized zone of vanadium-poor Colorado Plateau-type uranium deposits of Utah and Arizona. It occurs in association with gypsum, jarosite, limonite, quartz, clay minerals and coalized wood at the Jomac mine, Utah.[3]
Coconinite was first described in 1966 for occurrences in the Huskon Mines, Cameron, Cameron District and the Sun Valley Mine, Vermillion Cliffs District, Coconino County, Arizona. It was named for Coconino County.[2]
References
- ↑ Webmineral data
- ↑ 2.0 2.1 Mindat.org
- ↑ 3.0 3.1 Handbook of Mineralogy
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ 5.0 5.1 5.2 Young.E, Weeks, A.D, and Merowitz, R. (1996) Coconinoite a new mineral from Utah and Arizona. The American Mineralogist 51, 651-663
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