Chemistry:Dichloro(1,5‐cyclooctadiene)palladium

From HandWiki
Dichloro(1,5‐cyclooctadiene)palladium
PdCl2(cod).png
Dichloro(1,5‐cyclooctadiene)palladium-from-xtal-3D-bs-17.png
PdCl2(cod)sample.jpg
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 235-161-8
Properties
C8H12Cl2Pd
Molar mass 285.50 g·mol−1
Appearance yellow solid
Density 2.045 g/cm3
Melting point 210 °C (410 °F; 483 K)
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H315, H319, H335
P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Dichloro(1,5‐cyclooctadiene)palladium is the organopalladium compound with the formula PdCl2(C8H12) where C8H12 is cycloocta-1,5-diene (cod) or abbreviated PdCl2(cod). It is a yellow solid that is soluble in chloroform.[1] According to X-ray crystallography, the Pd center is square planar.[2]

See also

References

  1. Shomir Ghosh, Xiang Wang, Anil Guram (2009). "Dichloro(1,5-cyclooctadiene)palladium(II)". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rd113.pub2. ISBN 978-0471936237. 
  2. R. Kumar, A. W. Maverick, F. R. Fronczek, J. R. Doyle, N. C. Baenziger, M. A. M. Howells (1993). "The Pbca polymorph of dichloro(η4-1,5-cyclooctadiene)palladium(II)". Acta Crystallogr. C 49 (10): 1766–1767. doi:10.1107/S0108270193003889.