Chemistry:Formaldoxime
From HandWiki
Formaldoxime is the organic compound with the formula H
2C=N–OH. It is the oxime of formaldehyde. A colorless liquid, the pure compound tends to polymerize into a cyclic trimer. Aqueous solutions are stable as is the formaldoxime hydrochloride ([H
2C=N(–H)(–OH)]+
Cl−
). It is a reagent in organic synthesis for the conversion of aryl diazonium salts to aryl aldehydes.[1] It is an isomer of formamide.[2]
It is generated by combining hydroxylamine and formaldehyde.[3]
Synonyms
Source:[4]
- Formoxime
- Nitrone
- Formaldehyde oxime
- Formaldoxim
- Methylenenitrone
References
- ↑ De Kimpe, Norbert (2001). "Formaldoxime". E-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rf023. ISBN 0-471-93623-5.
- ↑ Golec, Barbara; Mielke, Zofia (November 12, 2007). "Formaldoxime dimers: Infrared matrix isolation and theoretical study" (in en-US). Journal of Molecular Structure 844-845: 242–249. doi:10.1016/j.molstruc.2007.03.049. ISSN 0022-2860. https://www.sciencedirect.com/science/article/abs/pii/S0022286007002943.
- ↑ S. D. Jolad, S. Rajagopalan (1966). "2-Bromo-4-methylbenzaldehyde". Org. Synth. 46: 13. doi:10.15227/orgsyn.046.0013.
- ↑ PubChem. "Nitrone" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/6350.
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