Chemistry:Graphene helix

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Short description: Structure consisting of a two-dimensional sheet of graphene wrapped into a helix


A graphene helix, similar to the carbon nanotube, is a structure consisting of a two-dimensional sheet of graphene wrapped into a helix. These graphene sheets can have multiple layers, called multi-walled carbon structures, that add to these helices thus increasing their tensile strength but increasing the difficulty of manufacturing. Using van der Waals interactions it can make structures within one another.

Electrical and magnetic properties

Main page: Physics:Graphene

Electrical

Graphene has very promising electrical properties.[1] Carbon nanotubes are semimetals meaning they are either metallic or semiconducting along the helical axis, this can depend on the curvature of the graphene helix. On top of having both of these properties graphene has a unique and useful is that it is a "zero-overlap semimetal".[2] Carbon helixes allow high electrical transfer over a three-dimensional plane. With the tensile strength, electrical conductivity, and thermal management it is useful for biotechnology.[3]

Magnetic

Similar to the electrical properties electrical fields can be used on a graphene sheet to polarize the bonds and exclusively bond on one side of the graphene sheet.[4]

Thermal

Graphene is a great thermal conductor, but this is paired with being a great insulator perpendicular to the helical axis.[5] These graphene sheets have a thermal conductivity of 3500 W·m−1·K−1, where copper has one of only 385 W·m−1·K−1 .[6]

Physical properties

With the different electrical, magnetic, and thermal properties shows that graphene by itself has many unique characteristics that can be harvested when used as a three dimensional structure. These graphene sheets have a tensile strength of 130,000,000,000 pascals which when compared to 400,000,000 pascals that of industrial steel.[7] This shows the possibilities of what this substance can be used for. Graphene is light when compared to materials like industrial steel because it weighs 0.77 milligrams per square meter.[8] Each of these sheets of graphene are made by single atom wide carbon chains cross linking. These webs of carbon chains look like pages of two dimensional hexagons with the only third dimension being only a single atom wide.

Production

Early synthesis of graphene

One of the first ways that graphene was discovered was taking a piece of masking tape and placing it on a piece of carbon and pulling it off to reveal many small two dimensional graphene sheets. By fabricating graphene with tape does it does create the necessary conditions for these graphene sheets to have the tensile strength previously stated.[9]

Mass production of graphene

The practicality of using tape to separate these sheets from each other does not scale to the production that would be necessary with the new developments of graphene. This becomes a new issue as the quality of the sheets completely determines what can be done with them. At a larger scale graphene can come from chemically exfoliated, natural, mined graphite.[10]

Production of graphene helixes

Arc discharge and laser ablation

These two slightly different processes both have graphene being combusted with electrical currents or by a laser and the graphene helixes will develop when the gaseous phases are separated, but there will need to be excess metals as catalysts.[11]

Chemical vapor deposition

Viewed as a process that has the most promise for the future the graphene helixes can be formed as catalysts are pushed onto the graphene sheets and will create the emerging helix. While needed to be performed at high temperatures the process can easily be activated and deactivated purely by the development of the helical structure.

Medical applications

Sequencing

One of the most interesting applications of a graphene helix would be new ways of unwinding RNA and DNA and using graphene helix's to image these folded apart strands for further sequencing.[12] Having these RNA and XNA bonds pulled apart inside of these graphene helix structures causes the hydrogen bonds to stay intact for more nanoseconds than previously so the sequencing would be more intact. The graphene helix was allowing the XNA to keep its three dimensional structure and allows for the hydrogen bonds to last longer. Overall the thermal and electrical conductivity of these carbon structures has too many different uses because of their strength and weight.

Electrocapillary

Helical graphene tubes have the electrical and physical properties and in addition to the elasticity can fit into smaller capillary systems. These graphene helixes potentially can be used in nano-fluid systems with uses of both actuators and fiber shaped sensors.[13]

Future outlook

These carbon helixes display very advantageous physical properties that make the creation of nanostructures more of a possibility. With possibilities in the 3D printing field of nanotechnologies, they could be providing the scaffolding for future supercapacitors, implants, and energy storage.[14] As the world is decreasing everything in size, computers are the fastest to take advantage of new materials, by miniaturizing more electronics even down the basic wire carrying electricity. There already have been logic gates made by these carbon structures showing the future potential in such material.[15]

Nodal morphology

Lee et al. suggested unique "nodal morphology" as evidence for the helix model for SWNTs,[16] which prevails in high-resolution transmission electron microscopy (HRTEM) and scanning tunneling microscopy (STM) images reported since 1993. The helix model for SWNTs is supported by strain energy calculation. The strain energy of the helical growth of a zigzag or armchair graphene ribbon is just about a quarter that of seamless cylindrical SWNTs. This calculation suggests that the growth of seamless SWNTs may be energetically prohibitive and uncompetitive with the structure proposed here under the conditions of conventional chemical vapor deposition processes. The model addresses previous experimental evidence in the literature, diverse electron diffraction patterns, HRTEM and STM morphologies as well as inconsistencies in the measured mechanical and electrical properties of SWNTs. Electrical property of SWNTs can be regarded as a (zigzag) graphene nanoribbon which is a conductor. In the mode, the chirality is not a necessary condition for the growth of SWNTs and the observation of chirality (or semiconducting properties) in the literature may be the result of an erroneous interpretation of the distortion of the graphene helix.

Based on spiral growth model, further works were carried out to investigate the mechanical properties (evaluation of tensile process by stress distribution).[17]

Recently, Park et al. reinterpreted SWNTs to be a graphene helix via Raman spectroscopy, showing that the typical Raman spectrum for SWNTs is the signature of their helical structure with density functional theory simulation and structure analysis for hydrogenated and dehydrogenated SWNTs samples. They demonstrated that the G- mode at ~1570 cm-1 is unique to opened tubular graphene structures (i.e., graphene helix) of ~2 nm in diameter. They also demonstrate that D mode of ~1350 cm-1 is originated from edge defects of opened SWNTs revealing strong Eigenvectors, which is absent in concentric tubes. They also showed that the analysis for the Raman spectra of SWNTs is consistent with general understanding on Raman analysis of carbon materials.[18]

References

  1. ↑ Li, Dan, and Richard B. Kaner. "Graphene-based materials." Nat Nanotechnol 3 (2008): 101. APA
  2. ↑ "Properties of Graphene" (in en). https://www.graphenea.com/pages/graphene-properties. 
  3. ↑ Lee, Jin-Ho; Park, Soo-Jeong; Choi, Jeong-Woo (2019-02-20). "Electrical Property of Graphene and Its Application to Electrochemical Biosensing". Nanomaterials 9 (2): 297. doi:10.3390/nano9020297. ISSN 2079-4991. PMID 30791566. 
  4. ↑ Zhou, Jian; Wu, Miao Miao; Zhou, Xiao; Sun, Qiang (2009-09-07). "Tuning electronic and magnetic properties of graphene by surface modification". Applied Physics Letters 95 (10): 103108. doi:10.1063/1.3225154. ISSN 0003-6951. Bibcode: 2009ApPhL..95j3108Z. https://aip.scitation.org/doi/abs/10.1063/1.3225154. 
  5. ↑ "Thermodynamics of nanostructures" (in en), Wikipedia, 2020-10-27, https://en.wikipedia.org/w/index.php?title=Thermodynamics_of_nanostructures&oldid=985708224, retrieved 2020-11-16 
  6. ↑ Pop, Eric; Mann, David; Wang, Qian; Goodson, Kenneth; Dai, Hongjie (January 2006). "Thermal Conductance of an Individual Single-Wall Carbon Nanotube above Room Temperature" (in en). Nano Letters 6 (1): 96–100. doi:10.1021/nl052145f. ISSN 1530-6984. PMID 16402794. Bibcode: 2006NanoL...6...96P. https://pubs.acs.org/doi/10.1021/nl052145f. 
  7. ↑ "Properties of Graphene" (in en). https://www.graphenea.com/pages/graphene-properties. 
  8. ↑ "Properties of Graphene" (in en). https://www.graphenea.com/pages/graphene-properties. 
  9. ↑ "How sticky tape trick led to Nobel Prize" (in en-GB). BBC News. 2010-10-05. https://www.bbc.com/news/science-environment-11478645. 
  10. ↑ "Mass-Producing Graphene" (in en). 2018-04-06. https://www.americanscientist.org/article/mass-producing-graphene. 
  11. ↑ "Carbon nanotubes – what they are, how they are made, what they are used for". https://www.nanowerk.com/nanotechnology/introduction/introduction_to_nanotechnology_22.php. 
  12. ↑ Ghosh, Soumadwip; Chakrabarti, Rajarshi (2016-08-25). "Unzipping of Double-Stranded Ribonucleic Acids by Graphene and Single-Walled Carbon Nanotube: Helix Geometry versus Surface Curvature". The Journal of Physical Chemistry C 120 (39): 22681–22693. doi:10.1021/acs.jpcc.6b06943. ISSN 1932-7447. https://pubs.acs.org/doi/full/10.1021/acs.jpcc.6b06943. 
  13. ↑ "Helical Graphene Oxide Fibers as a Stretchable Sensor and Electrocapillary Sucker | Request PDF" (in en). https://www.researchgate.net/publication/301576301. 
  14. ↑ Valenti, Giovanni; Boni, Alessandro; Melchionna, Michele; Cargnello, Matteo; Nasi, Lucia; Bertoni, Giovanni; Gorte, Raymond J.; Marcaccio, Massimo et al. (2016-12-12). "Co-axial heterostructures integrating palladium/titanium dioxide with carbon nanotubes for efficient electrocatalytic hydrogen evolution". Nature Communications 7: 13549. doi:10.1038/ncomms13549. ISSN 2041-1723. PMID 27941752. Bibcode: 2016NatCo...713549V. 
  15. ↑ Martel, R.; Derycke, V.; Lavoie, C.; Appenzeller, J.; Chan, K. K.; Tersoff, J.; Avouris, Ph. (2001-12-03). "Ambipolar Electrical Transport in Semiconducting Single-Wall Carbon Nanotubes". Physical Review Letters 87 (25): 256805. doi:10.1103/PhysRevLett.87.256805. PMID 11736597. Bibcode: 2001PhRvL..87y6805M. https://link.aps.org/doi/10.1103/PhysRevLett.87.256805. 
  16. ↑ Lee, J.-K.; Lee, S.; Kim, J.G.; Min, B.K.; Kim, Y.I.; Lee, K.I.; An, K.H.; John, P. (2014). "Structure of Single-Wall Carbon Nanotubes: A Graphene Helix". Small 10 (16): 3283–90. doi:10.1002/smll.201400884. PMID 24838196. 
  17. ↑ Jhon, Y.I.; Kim, C.; Seo, M.; Cho, W.J.; Lee, S.; John, Y.M. (2016). "Tensile Characterization of Single-Walled Carbon Nanotubes with Helical Structural Defects". Scientific Reports 6: 20324. doi:10.1038/srep20324. PMID 26841708. Bibcode: 2016NatSR...620324J. 
  18. ↑ Park, Y.; Hembram, K.P.S.S.; Yoo, R.; Jang, B.; Lee, W.; Lee, S.-G.; Kim, J.-G.; Kim, Y.I. et al. (2019). "Reinterpretation of Single-Wall Carbon Nanotubes by Raman Spectroscopy". The Journal of Physical Chemistry C xx (22): 14003–14009. doi:10.1021/acs.jpcc.9b02174. 



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