Chemistry:Gregoryite

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Gregoryite
Gregorite.JPG
General
CategoryCarbonate mineral
Formula
(repeating unit)
(Na
2
,K
2
,Ca)CO
3
Strunz classification5.AA.10
Crystal systemHexagonal
Crystal classDihexagonal pyramidal (6mm)
(same H-M symbol)
Space groupP63mc
Unit cella = 5.21
c = 6.58 [Å]; Z = 2
Identification
ColorBrown, milky white
Crystal habitPhenocrysts in carbonatite lava
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.27 (calculated)
Optical propertiesUniaxial
SolubilitySoluble in water
References[1][2][3]

Gregoryite is an anhydrous carbonate mineral that is rich in potassium and sodium[5] with the chemical formula (Na
2
,K
2
,Ca)CO
3
.[1][6][7] It is one of the two main ingredients of natrocarbonatite, found naturally in the lava of Ol Doinyo Lengai volcano of Arusha Region, Tanzania, and the other being nyerereite.[8]

Because of its anhydrous nature, gregoryite reacts quickly with the environment, causing the dark lava to be converted to white substance within hours.[5]

Gregoryite was first described in 1980 and named after the British geologist and author John Walter Gregory (1864–1932), who studied the East African Rift Valley.[1][2] It occurs associated with nyerereite, alabandite, halite, sylvite, fluorite and calcite.[3]

References

  1. 1.0 1.1 1.2 Mindat.org
  2. 2.0 2.1 Webmineral.com
  3. 3.0 3.1 Handbook of Mineralogy
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 "Gregoryite definition". Dictionary of Geology. http://www.theodora.com/geology/glossaryg.html#gregoryite. Retrieved 2011-05-21. 
  6. Mitchell, Roger H.; Bruce A. Kjarsgaard (2010). "Experimental Studies of the System Na2CO3–CaCO3–MgF2 at 0·1 GPa: Implications for the Differentiation and Low-temperature Crystallization of Natrocarbonatite". Journal of Petrology (Oxford Journals) 52 (7–8): 1265–1280. doi:10.1093/petrology/egq069. 
  7. Hay, Richard L (1989). "Holocene carbonatite-nephelinite tephra deposits of Oldoinyo Lengai, Tanzania". Journal of Volcanology and Geothermal Research (Elsevier (Netherlands)) 37 (1): 77–91. doi:10.1016/0377-0273(89)90114-5. Bibcode1989JVGR...37...77H. [|permanent dead link|dead link}}]
  8. "World's Coolest Lava is in Africa". Volcano Watch. USGS Hawaiian Volcano Watch. http://hvo.wr.usgs.gov/volcanowatch/2003/03_04_17.html. Retrieved 2011-05-21.