Chemistry:Gyrolite

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Short description: Rare phyllosilicate mineral crystallizing in spherules
Gyrolite
Gyrolite - Malad quarry, Mumbai, Maharashtra, India.jpg
Spherical colorless gyrolite crystals from Malad quarry, India
General
CategoryPhyllosilicate
Formula
(repeating unit)		NaCa16(Si23Al)O60(OH)8·14H2O
Strunz classification9.EE.30
Dana classification73.2.2c.1
Crystal systemTriclinic
Crystal classPinacoidal (1)
(same H-M symbol)
Space groupP1
Unit cella = 9.74, b = 9.74
c = 22.4 [Å]; α = 95.71°
β = 91.51°, γ = 120.01°; Z = 4
Identification
ColorWhite, colorless, green, yellow or brown
Crystal habitCompact, lamellar, platy
TwinningLamellar
CleavagePerfect on {001}
TenacityBrittle
Mohs scale hardness​2 1⁄2
|re|er}}Vitreous, pearly
DiaphaneityTransparent, translucent, opaque
Density2.45–2.51
Optical propertiesBiaxial (−)
Refractive indexnα = 1.535 nβ = 1.548 nγ = 1.549
Birefringenceδ = 0.0140
References[1][2][3]

Gyrolite, NaCa16(Si23Al)O60(OH)8·14H2O,[2] is a rare silicate mineral (basic sodium calcium silicate hydrate: N-C-S-H, in cement chemist notation) belonging to the class of phyllosilicates. Gyrolite is also often associated with zeolites. It is most commonly found as spherical or radial formations in hydrothermally altered basalt and basaltic tuffs.[2] These formations can be glassy, dull or fibrous in appearance.[5]

Gyrolite is also known as centrallasite, glimmer zeolite or gurolite.[2]

Discovery and natural occurrence

Spherical brown gyrolite crystals from Lonavala quarry, India

It was first described in 1851 for an occurrence at The Storr on the Isle of Skye, Scotland and is named from the ancient Greek word for circle, guros (γῦρος), based on the round form in which it is commonly found.[3]

Minerals associated with gyrolite include apophyllite, okenite and many of the other zeolites.[5] Gyrolite is found in Scotland, Ireland; Italy, Faroe Islands, Greenland, India, Japan, USA, Canada and various other localities.[1][2]

Occurrence in hardened cement paste and concrete

Gyrolite is also mentioned as a rare calcium silicate hydrate (C-S-H) phase in cement chemistry textbooks[6][7] with a simplified formulation: Ca8(Si4O10)3(OH)4 · ~6 H2O, which is consistent with the general formulation given here above, but does not consider the isomorphic substitution of one silicon atom by one aluminum and one sodium atoms in its crystal lattice. Gyrolite may form at higher temperature in oilwell cement muds containing ground granulated blast furnace slags (GGBFS) activated by alkali. It could also form in CEM III cement-based concrete exposed to alkali-silica reaction (ASR) at elevated temperature.

Hydrothermal synthesis

Gyrolite can be synthesized in the laboratory, or industrially, by hydrothermal reaction in the temperature range 150 – 250 °C by reacting CaO and amorphous SiO2, or quartz, in saturated steam in the presence of CaSO4 salts or not.[8][9] At temperature lower than 150 °C, the reaction rate is very slow. At temperature above 250 °C, gyrolite recrystallizes into 1.13 nm tobermorite and xonotlite.[8]

Gyrolite is also one of the rare phases detected in situ along with pectolite by synchrotron X-rays diffraction in hydrothermal synthesis of cement.[10] Synthetic gyrolite has also a large specific surface and could enter industrial applications as oil absorber.[11] Gyrolite globular rosettes resemble that of shlykovite,[12][13] a new natural crystalline C-S-H mineral characterized in 2010 and also to mountainite and rhodesite, other crystalline ASR products of the same family.[14][15][16][17]

See also

References

  1. ↑ 1.0 1.1 "Gyrolite in the Handbook of Mineralogy". http://www.handbookofmineralogy.com/pdfs/gyrolite.pdf. 
  2. ↑ 2.0 2.1 2.2 2.3 2.4 "Gyrolite". http://www.mindat.org/min-1785.html. 
  3. ↑ 3.0 3.1 Dave Barthelmy. "Gyrolite Mineral Data". http://webmineral.com/data/Gyrolite.shtml. 
  4. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. 
  5. ↑ 5.0 5.1 "Gyrolite (Hydrated Calcium Silicate Hydroxide)". Galleries.com. http://www.galleries.com/Gyrolite. Retrieved 2016-02-27. 
  6. ↑ Hewlett, Peter (2003). Lea's chemistry of cement and concrete. See chapter 14.2 Oilwell cement, p. 807. Elsevier. ISBN 0-08-053541-0. 
  7. ↑ Taylor, Harry F.W. (1997). Cement chemistry. See gyrolite at pp. 344 and 348.. Thomas Telford. ISBN 0-7277-2592-0. 
  8. ↑ 8.0 8.1 Siauciunas, R.; Baltakys, K. (2004). "Formation of gyrolite during hydrothermal synthesis in the mixtures of CaO and amorphous SiO2 or quartz". Cement and Concrete Research 34 (11): 2029–2036. doi:10.1016/j.cemconres.2004.03.009. ISSN 0008-8846. 
  9. ↑ Baltakys, K.; Siauciunas, R. (2010). "Influence of gypsum additive on the gyrolite formation process". Cement and Concrete Research 40 (3): 376–383. doi:10.1016/j.cemconres.2009.11.004. ISSN 0008-8846. 
  10. ↑ Shawa, S.; Henderson, C. M. B.; Clark, S. M. (2001). "Hydrothermal synthesis of cement phases: An in situ synchrotron, energy dispersive diffraction study of reaction kinetics and mechanisms". High Pressure Research 20 (1–6): 311–324. doi:10.1080/08957950108206179. ISSN 0895-7959. Bibcode: 2001HPR....20..311S. 
  11. ↑ "Patent application number: 15/034,912. Inventors: Yuuta Tsumura (Naruto-shi), Kazuki Kamai (Naruto-shi), Yukinori Konishi (Naruto-shi), Kazuhiko Tamagawa (Naruto-shi). Powdered gyrolite-type calcium silicate having high oil absorbency and large particle diameter, and production method therefor.". Nov 7, 2014. https://patents.justia.com/patent/20160289081. 
  12. ↑ Zubkova, Natalia V.; Filinchuk, Yaroslav E.; Pekov, Igor V.; Pushcharovsky, Dmitry Yu; Gobechiya, Elena R. (2010-08-01). "Crystal structures of shlykovite and cryptophyllite: comparative crystal chemistry of phyllosilicate minerals of the mountainite family". European Journal of Mineralogy 22 (4): 547–555. doi:10.1127/0935-1221/2010/0022-2041. ISSN 0935-1221. Bibcode: 2010EJMin..22..547Z. https://pubs.geoscienceworld.org/eurjmin/article-abstract/22/4/547/69481/Crystal-structures-of-shlykovite-and. Retrieved 2020-04-29. 
  13. ↑ Pekov, I. V.; Zubkova, N. V.; Filinchuk, Ya. E.; Chukanov, N. V.; Zadov, A. E.; Pushcharovsky, D. Yu.; Gobechiya, E. R. (2010-12-01). "Shlykovite KCa[Si4O9(OH)] · 3 H2O and cryptophyllite K2Ca[Si4O10] · 5 H2O, new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia". Geology of Ore Deposits 52 (8): 767–777. doi:10.1134/S1075701510080088. ISSN 1555-6476. Bibcode: 2010GeoOD..52..767P. 
  14. ↑ De Ceukelaire, L. (1991-05-01). "The determination of the most common crystalline alkali-silica reaction product". Materials and Structures 24 (3): 169–171. doi:10.1007/BF02472981. ISSN 1871-6873. 
  15. ↑ Dähn, R.; Arakcheeva, A.; Schaub, Ph.; Pattison, P.; Chapuis, G.; Grolimund, D.; Wieland, E.; Leemann, A. (2016-01-01). "Application of micro X-ray diffraction to investigate the reaction products formed by the alkali–silica reaction in concrete structures". Cement and Concrete Research 79: 49–56. doi:10.1016/j.cemconres.2015.07.012. ISSN 0008-8846. 
  16. ↑ Shi, Zhenguo; Leemann, Andreas; Rentsch, Daniel; Lothenbach, Barbara (2020-05-01). "Synthesis of alkali-silica reaction product structurally identical to that formed in field concrete". Materials & Design 190: 108562. doi:10.1016/j.matdes.2020.108562. ISSN 0264-1275. 
  17. ↑ Geng, Guoqing; Shi, Zhenguo; Leemann, Andreas; Borca, Camelia; Huthwelker, Thomas; Glazyrin, Konstantin; Pekov, Igor V.; Churakov, Sergey et al. (2020-03-01). "Atomistic structure of alkali-silica reaction products refined from X-ray diffraction and micro X-ray absorption data". Cement and Concrete Research 129: 105958. doi:10.1016/j.cemconres.2019.105958. ISSN 0008-8846. http://www.sciencedirect.com/science/article/pii/S0008884619309020. Retrieved 2020-04-29. 

Further reading

  • Anderson Thomas (1851) Description and analysis of gyrolite, a new mineral species. In: The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 1, 111–113. (PDF 239,5 kB)
  • Mackay, A. L.; Taylor, H. F. W. (March 1953). "Gyrolite". Mineralogical Magazine and Journal of the Mineralogical Society 30 (220): 80–92. doi:10.1180/minmag.1953.030.220.10. ISSN 0369-0148. Bibcode: 1953MinM...30...80M. 
  • Fleischer M. (1959) New mineral names. In: American Mineralogist, Vol. 44, 464–470 (PDF 444 kB; p. 7: Centrallasite = Gyrolite).




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