Chemistry:Hyalophane

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Short description: Barium-rich feldspar mineral
Hyalophane
Hyalophane NHMLA.png
Hyalophane crystal (Busovača, Bosnia and Herzegovina)
General
CategoryTectosilicate
Formula
(repeating unit)
(K,Ba)[Al(Si,Al)Si
2
O
8
]
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupC2/m
Unit cella = 8.52 Å, b = 12.95 Å,
c = 7.14 Å; β = 116°; Z = 4
Identification
Formula mass302.06 g/mol
ColorColorless, yellow, white, red
Crystal habitCrystalline – fine – occurs as well-formed fine sized crystals; massive – uniformly indistinguishable crystals forming large masses
TwinningCommonly simple twins according to the Carlsbad, Manebach, or Baveno laws
Cleavage{001} perfect, {010} imperfect
FractureConchoidal
TenacityBrittle
Mohs scale hardness6 – ​6 12
|re|er}}Vitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.81
Optical propertiesBiaxial (-)
Refractive indexnα = 1.542, nβ = 1.545, nγ = 1.547
Birefringenceδ = 0.005
2V angle48 – 79°
DispersionWeak
References[1][2][3][4]

Hyalophane or jaloallofane is a crystalline mineral, part of the feldspar group of tectosilicates. It is considered a barium-rich potassium feldspar.[5] Its chemical formula is (K,Ba)[Al(Si,Al)Si
2
O
8
]
, and it has a hardness of 6 to ​6 12. The name hyalophane comes from the Greek hyalos, meaning "glass", and phanos meaning "to appear".[4]

An occurrence of hyalophane was discovered in 1855 in Lengenbach Quarry, Imfield, Binn valley, municipality of Binn, Canton of Valais, Switzerland . The mineral is found predominantly in Europe, with occurrences in Switzerland, Australia , Bosnia, Germany , Japan , New Jersey, and the west coast of North America.[4] Hyalophane may be found in manganese deposits in compact metamorphic zones.[6]

Hyalophane has a monoclinic crystallography, with cell properties a = 8.52 Å, b = 12.95 Å, c = 7.14 Å, and β = 116°. Optically, the material exhibits biaxial birefringence, with refractive index values of nα = 1.542, nβ = 1.545, and nγ = 1.547 and a maximum birefringence of δ = 0.005. It has weak dispersion and low surface relief.[1]

Hyalophane has sometimes been used as a gemstone.[7]

References