Chemistry:Hydrotrioxide
From HandWiki
Hydrotrioxides are a class of highly reactive unstable chemical compounds.[1] They have been confirmed to appear inside the atmosphere of Earth.[2][3][4]
They are generated when peroxyl radicals (non-ionic superoxides, not to be confused with the hydroperoxyl radical) in the atmosphere react with the hydroxyl radical.[1]
The simplest example of a hydrotrioxide is trioxidane.[5] One may also say hydrogen ozonide is actually the simplest hydrotrioxide.
Triethylsilyl hydrotrioxide is, in theory, capable of being used to generate either singlet oxygen or 1,9-nonanediol.[6][7]
References
- ↑ 1.0 1.1 "New type of extremely reactive substance in the atmosphere" (in en). https://www.eurekalert.org/news-releases/953806.
- ↑ Berndt, Torsten; Chen, Jing; Kjærgaard, Eva R.; Møller, Kristian H.; Tilgner, Andreas; Hoffmann, Erik H.; Herrmann, Hartmut; Crounse, John D. et al. (2022-05-27). "Hydrotrioxide (ROOOH) formation in the atmosphere" (in en). Science 376 (6596): 979–982. doi:10.1126/science.abn6012. ISSN 0036-8075. https://www.science.org/doi/10.1126/science.abn6012.
- ↑ "New class of substances detected in atmospheric chemistry" (in en). https://www.eurekalert.org/news-releases/953731.
- ↑ "Hydrotrioxides are in the air" (in en). https://www.chemistryworld.com/news/hydrotrioxides-are-in-the-air/4015751.article.
- ↑ Chemistry (IUPAC), The International Union of Pure and Applied. "IUPAC - trioxides (T06501)" (in en). https://goldbook.iupac.org/terms/view/T06501.
- ↑ Fuchs, Philip L. (2011). Reagents for silicon-mediated organic synthesis. Handbook of reagents for organic synthesis. Chichester: Wiley. ISBN 978-0-470-71023-4.
- ↑ Corey, E. J.; Mehrotra, Mukund M.; Khan, Ahsan U. (1986-04-01). "Generation of 1Δg oxygen from triethylsilane and ozone". Journal of the American Chemical Society 108 (9): 2472–2473. doi:10.1021/ja00269a070. ISSN 0002-7863. https://doi.org/10.1021/ja00269a070.
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