Chemistry:Hydrogen ozonide

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Hydrogen ozonide
Hydrogen-ozonide-3D-balls.png
Hydrogen-ozonide-3D-vdW.png
Names
IUPAC name
Hydrogen ozonide
Other names
  • Trioxidanyl
  • Hydridotrioxygen
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
Properties
HO3
Molar mass 49.005 g·mol−1
Related compounds
Related hydrogen polyoxides
    • Hydrogen trioxide
    • Hydrogen superoxide
Related compounds
Protonated ozone
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Hydrogen ozonide (HO
3
) is a radical molecule consisting of a hydrogen atom covalently bonded to an ozonide unit.[1]

It is possibly produced in the reaction of the hydroxyl radical with dioxygen: OH + O2 → HO3.[2][3]

It has been detected in a mass spectrometer experiment using HO+3 (protonated ozone) as precursor.[4]

References

  1. Möller, D. (2022). Chemistry for Environmental Scientists. De Gruyter Textbook. De Gruyter. p. 165. ISBN 978-3-11-073517-8. https://books.google.com/books?id=BfqjEAAAQBAJ&pg=PA165. Retrieved 2022-12-28. 
  2. Wabner, Dietrich; Grambow, Clemens (November 1985). "Reactive intermediates during oxindation of water lead dioxide and platinum electrodes". Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 195 (1): 95–108. doi:10.1016/0022-0728(85)80008-5. 
  3. Chernik, A.; Drozdovich, V. B.; Zharskii, I. (1997). "Ozone evolution at the lead dioxide electrode in highly acid and neutral electrolytes : The influence of polarization and fluoride ions on the process kinetics" (in en). Russian Journal of Electrochemistry 33 (3): 259–263. 
  4. Cacace, Fulvio; de Petris, Guilia; Pepi, F.; Troiani, Anna (2 July 1999). "Experimental Detection of Hydrogen Trioxide". Science 285 (5424): 81–82. doi:10.1126/science.285.5424.81. 

Extra reading

  • Kalemos, Apostolos (1 February 2021). "Some ab initio thoughts on the bonding in O3H". Molecular Physics 119 (3): e1804082. doi:10.1080/00268976.2020.1804082. 
  • Fabian, W. M. F.; Kalcher, J.; Janoschek, R. (September 2005). "Stationary points on the energy hypersurface of the reaction O3 + H•→ [•O3H]* ⇆ O2 + •OH and thermodynamic functions of •O3H at G3MP2B3, CCSD(T)–CBS (W1U) and MR–ACPF–CBS levels of theory". Theoretical Chemistry Accounts 114 (1–3): 182–188. doi:10.1007/s00214-005-0659-7.