Chemistry:Kentbrooksite
| Kentbrooksite | |
|---|---|
 | |
| General | |
| Category | Silicate mineral, Cyclosilicate |
| Formula (repeating unit) | (Na,REE) 15(Ca,REE) 6Mn 3Zr 3NbSi 25O 74F 2 · 2H2O (original form) |
| Strunz classification | 9.CO.10 (10 ed) 8/E.23-20 (8 ed) |
| Dana classification | 64.1.2.1 |
| Crystal system | Trigonal |
| Crystal class | Ditrigonal pyramidal (3m) H-M symbol: (3m) |
| Space group | R3m |
| Unit cell | a = 14.24, c = 30.03 [Å] (approximated); Z = 3 |
| Identification | |
| Color | Yellow-brown |
| Crystal habit | aggregates (anhedral to subhedral) |
| Cleavage | None |
| Fracture | Uneven |
| Tenacity | Brittle |
| Mohs scale hardness | 5–6 |
| |re|er}} | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Density | 3.10 (measured) |
| Optical properties | Uniaxial (−) |
| Refractive index | nω = 1.63, nε = 1.62 (approximated) |
| Pleochroism | None |
| Other characteristics | Pyroelectric |
| References | [1][2] |
Kentbrooksite is a moderately rare mineral of the eudialyte group,[1] with chemical formula (Na,REE)
15(Ca,REE)
6Mn
3Zr
3NbSi[(Si
9O
27)
2(Si
3O
9)
2O
2]F
2 · 2H2O.[2] This extended formula shows the presence of cyclic silicate groups and dominance of Si at the M4 site, according to the nomenclature of the eudialyte group.[4] The characteristic features of kentbrooksite, that make it different from eudialyte are: (1) dominancy of fluorine (the only currently known example among the whole group[1]), (2) dominancy of manganese, and (3) dominancy of niobium. Trace hafnium and magnesium are also reported.[2] Kentbrooksite is relatively common when compared to most other species of the group.[1]
Occurrence
Kentbrooksite was found in alkaline pegmatites within pulaskites of the Kangerdlugssuaq intrusion in East Greenland.[2]
Notes on chemistry
Rare earth elements (REE) in kentbrooksite are dominated by cerium and yttrium. Potassium, strontium, iron, aluminium, titanium, magnesium are present as other admixtures. An important fraction of fluorine is substituted by chlorine and hydroxyl groups.
References
- ↑ 1.0 1.1 1.2 1.3 Mindat, Kentbrooksite, http://www.mindat.org/min-7132.html
- ↑ 2.0 2.1 2.2 2.3 Johnsen, O., Grice, J.D., and Gault, R.A., 1998. Kentbrooksite from the Kangerdlugssuaq intrusion, East Greenland, a new Mn-REE-Nb-F end-member in a series within the eudialyte group: Description and crystal structure. European Journal of Mineralogy 10(2), 207–220.
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794
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