Chemistry:Yttrium

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Short description: Chemical element, symbol Y and atomic number 39

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Yttrium, 39Y
Yttrium sublimed dendritic and 1cm3 cube.jpg
Yttrium
Pronunciation/ˈɪtriəm/ ​(IT-ree-əm)
Appearancesilvery white
Standard atomic weight Ar, std(Y)88.90584(1)[1]
Yttrium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Sc
↑
Y
↓
La[lower-alpha 1]
strontium ← yttrium → zirconium
Atomic number (Z)39
Groupgroup 3
Periodperiod 5
Block  d-block
Element category  d-block
Electron configuration[Kr] 4d1 5s2
Electrons per shell2, 8, 18, 9, 2
Physical properties
Phase at STPsolid
Melting point1799 K ​(1526 °C, ​2779 °F)
Boiling point3203 K ​(2930 °C, ​5306 °F)
Density (near r.t.)4.472 g/cm3
when liquid (at m.p.)4.24 g/cm3
Heat of fusion11.42 kJ/mol
Heat of vaporization363 kJ/mol
Molar heat capacity26.53 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1883 2075 (2320) (2627) (3036) (3607)
Atomic properties
Oxidation states0,[2] +1, +2, +3 (a weakly basic oxide)
ElectronegativityPauling scale: 1.22
Ionization energies
  • 1st: 600 kJ/mol
  • 2nd: 1180 kJ/mol
  • 3rd: 1980 kJ/mol
Atomic radiusempirical: 180 pm
Covalent radius190±7 pm
Color lines in a spectral range
Spectral lines of yttrium
Other properties
Natural occurrenceprimordial
Crystal structure ​hexagonal close-packed (hcp)
Hexagonal close packed crystal structure for yttrium
Speed of sound thin rod3300 m/s (at 20 °C)
Thermal expansionα, poly: 10.6 µm/(m·K) (at r.t.)
Thermal conductivity17.2 W/(m·K)
Electrical resistivityα, poly: 596 nΩ·m (at r.t.)
Magnetic orderingparamagnetic[3]
Magnetic susceptibility+2.15·10−6 cm3/mol (2928 K)[4]
Young's modulus63.5 GPa
Shear modulus25.6 GPa
Bulk modulus41.2 GPa
Poisson ratio0.243
Brinell hardness200–589 MPa
CAS Number7440-65-5
History
Namingafter Ytterby (Sweden) and its mineral ytterbite (gadolinite)
DiscoveryJohan Gadolin (1794)
First isolationFriedrich Wöhler (1838)
Main isotopes of yttrium
Iso­tope Abun­dance Physics:Half-life (t1/2) Decay mode Pro­duct
87Y syn 3.4 d ε 87Sr
γ –
88Y syn 106.6 d ε 88Sr
γ –
89Y 100% stable
90Y syn 2.7 d β− 90Zr
γ –
91Y syn 58.5 d β− 91Zr
γ –
Category Category: Yttrium
view · talk · edit | references
Y
data m.p. cat
in calc from C diff report ref
C 1526 — —
K 1799 1799 0
F 2779 2779 0
max precision 0
WD


input C: 1526, K: 1799, F: 2779
comment
Y
data b.p. cat
in calc from C diff report ref
C 2930 — —
K 3203 3200 3 delta
F 5306 5310 -4 delta
max precision 0
WD


input C: 2930, K: 3203, F: 5306
comment

Yttrium is a chemical element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element".[5] Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.

The most important present-day use of yttrium is as a component of phosphors, especially those used in LEDs. Historically, it was once widely used in the red phosphors in television set cathode ray tube displays.[6] Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and tracing various materials to enhance their properties.

Yttrium has no known biological role. Exposure to yttrium compounds can cause lung disease in humans.[7]

Etymology

The element is named after ytterbite, a mineral first identified in 1787 by the chemist Carl Axel Arrhenius. He named the mineral after the village of Ytterby, in Sweden, where it had been discovered. When one of the chemicals in ytterbite was later found to be a previously unidentified element, the element was then named yttrium after the mineral.

Characteristics

Properties

Yttrium is a soft, silver-metallic, lustrous and highly crystalline transition metal in group 3. As expected by periodic trends, it is less electronegative than its predecessor in the group, scandium, and less electronegative than the next member of period 5, zirconium. However, due to the lanthanide contraction, it is also less electronegative than its successor in the group, lutetium.[8][9][10] Yttrium is the first d-block element in the fifth period.

The pure element is relatively stable in air in bulk form, due to passivation of a protective oxide (Y2O3) film that forms on the surface. This film can reach a thickness of 10 µm when yttrium is heated to 750 °C in water vapor.[11] When finely divided, however, yttrium is very unstable in air; shavings or turnings of the metal can ignite in air at temperatures exceeding 400 °C.[12] Yttrium nitride (YN) is formed when the metal is heated to 1000 °C in nitrogen.[11]

Similarity to the lanthanides

Further information: Chemistry:Rare-earth element

The similarities of yttrium to the lanthanides are so strong that the element has been grouped with them as a rare-earth element,[5] and is always found in nature together with them in rare-earth minerals.[13] Chemically, yttrium resembles those elements more closely than its neighbor in the periodic table, scandium,[14] and if physical properties were plotted against atomic number, it would have an apparent number of 64.5 to 67.5, placing it between the lanthanides gadolinium and erbium.[15]

It often also falls in the same range for reaction order,[11] resembling terbium and dysprosium in its chemical reactivity.[6] Yttrium is so close in size to the so-called 'yttrium group' of heavy lanthanide ions that in solution, it behaves as if it were one of them.[11][16] Even though the lanthanides are one row farther down the periodic table than yttrium, the similarity in atomic radius may be attributed to the lanthanide contraction.[17]

One of the few notable differences between the chemistry of yttrium and that of the lanthanides is that yttrium is almost exclusively trivalent, whereas about half the lanthanides can have valences other than three; nevertheless, only for four of the fifteen lanthanides are these other valences important in aqueous solution (CeIV, SmII, EuII, and YbII).[11]

Compounds and reactions

See also: Category:Yttrium compounds
Left: Soluble yttrium salts reacts with carbonate, forming white precipitate yttrium carbonate. Right: Yttrium carbonate is soluble in excess alkali metal carbonate solution.

As a trivalent transition metal, yttrium forms various inorganic compounds, generally in the oxidation state of +3, by giving up all three of its valence electrons.[18] A good example is yttrium(III) oxide (Y2O3), also known as yttria, a six-coordinate white solid.[19]

Yttrium forms a water-insoluble fluoride, hydroxide, and oxalate, but its bromide, chloride, iodide, nitrate and sulfate are all soluble in water.[11] The Y3+ ion is colorless in solution because of the absence of electrons in the d and f electron shells.[11]

Water readily reacts with yttrium and its compounds to form Y2O3.[13] Concentrated nitric and hydrofluoric acids do not rapidly attack yttrium, but other strong acids do.[11]

With halogens, yttrium forms trihalides such as yttrium(III) fluoride (YF3), yttrium(III) chloride (YCl3), and yttrium(III) bromide (YBr3) at temperatures above roughly 200 °C.[7] Similarly, carbon, phosphorus, selenium, silicon and sulfur all form binary compounds with yttrium at elevated temperatures.[11]

Organoyttrium chemistry is the study of compounds containing carbon–yttrium bonds. A few of these are known to have yttrium in the oxidation state 0.[2][20] (The +2 state has been observed in chloride melts,[21] and +1 in oxide clusters in the gas phase.[22]) Some trimerization reactions were generated with organoyttrium compounds as catalysts.[20] These syntheses use YCl3 as a starting material, obtained from Y2O3 and concentrated hydrochloric acid and ammonium chloride.[23][24]

Hapticity is a term to describe the coordination of a group of contiguous atoms of a ligand bound to the central atom; it is indicated by the Greek character eta, η. Yttrium complexes were the first examples of complexes where carboranyl ligands were bound to a d0-metal center through a η7-hapticity.[20] Vaporization of the graphite intercalation compounds graphite–Y or graphite–Y2O3 leads to the formation of endohedral fullerenes such as Y@C82.[6] Electron spin resonance studies indicated the formation of Y3+ and (C82)3− ion pairs.[6] The carbides Y3C, Y2C, and YC2 can be hydrolyzed to form hydrocarbons.[11]

Isotopes and nucleosynthesis

Main page: Physics:Isotopes of yttrium

Yttrium in the Solar System was created through stellar nucleosynthesis, mostly by the s-process (≈72%), but also by the r-process (≈28%).[25] The r-process consists of rapid neutron capture by lighter elements during supernova explosions. The s-process is a slow neutron capture of lighter elements inside pulsating red giant stars.[26]

Grainy irregular shaped yellow spot with red rim on a black background
Mira is an example of the type of red giant star in which most of the yttrium in the solar system was created.

Yttrium isotopes are among the most common products of the nuclear fission of uranium in nuclear explosions and nuclear reactors. In the context of nuclear waste management, the most important isotopes of yttrium are 91Y and 90Y, with half-lives of 58.51 days and 64 hours, respectively.[27] Though 90Y has a short half-life, it exists in secular equilibrium with its long-lived parent isotope, strontium-90 (90Sr) with a half-life of 29 years.[12]

All group 3 elements have an odd atomic number, and therefore few stable isotopes.[8] Scandium has one stable isotope, and yttrium itself has only one stable isotope, 89Y, which is also the only isotope that occurs naturally. However, the lanthanide rare earths contain elements of even atomic number and many stable isotopes. Yttrium-89 is thought to be more abundant than it otherwise would be, due in part to the s-process, which allows enough time for isotopes created by other processes to decay by electron emission (neutron → proton).[26][lower-alpha 2] Such a slow process tends to favor isotopes with atomic mass numbers (A = protons + neutrons) around 90, 138 and 208, which have unusually stable atomic nuclei with 50, 82, and 126 neutrons, respectively.[26][lower-alpha 3] This stability is thought to result from their very low neutron-capture cross-section.[26] Electron emission of isotopes with those mass numbers is simply less prevalent due to this stability, resulting in them having a higher abundance.[12] 89Y has a mass number close to 90 and has 50 neutrons in its nucleus.

At least 32 synthetic isotopes of yttrium have been observed, and these range in atomic mass number from 76 to 108.[27] The least stable of these is 106Y with a half-life of >150 ns (76Y has a half-life of >200 ns) and the most stable is 88Y with a half-life of 106.626 days.[27] Apart from the isotopes 91Y, 87Y, and 90Y, with half-lives of 58.51 days, 79.8 hours, and 64 hours, respectively, all the other isotopes have half-lives of less than a day and most of less than an hour.[27]

Yttrium isotopes with mass numbers at or below 88 decay primarily by positron emission (proton → neutron) to form strontium (Z = 38) isotopes.[27] Yttrium isotopes with mass numbers at or above 90 decay primarily by electron emission (neutron → proton) to form zirconium (Z = 40) isotopes.[27] Isotopes with mass numbers at or above 97 are also known to have minor decay paths of β− delayed neutron emission.[28]

Yttrium has at least 20 metastable ("excited") isomers ranging in mass number from 78 to 102.[27][lower-alpha 4] Multiple excitation states have been observed for 80Y and 97Y.[27] While most of yttrium's isomers are expected to be less stable than their ground state, 78mY, 84mY, 85mY, 96mY, 98m1Y, 100mY, and 102mY have longer half-lives than their ground states, as these isomers decay by beta decay rather than isomeric transition.[28]

History

In 1787, part-time chemist Carl Axel Arrhenius found a heavy black rock in an old quarry near the Swedish village of Ytterby (now part of the Stockholm Archipelago).[29] Thinking it was an unknown mineral containing the newly discovered element tungsten,[30] he named it ytterbite[lower-alpha 5] and sent samples to various chemists for analysis.[29]

Black and white bust painting of a young man with neckerchief in a coat. The hair is only faintly painted and looks grey.
Johan Gadolin discovered yttrium oxide.

Johan Gadolin at the University of Åbo identified a new oxide (or "earth") in Arrhenius' sample in 1789, and published his completed analysis in 1794.[31][lower-alpha 6] Anders Gustaf Ekeberg confirmed the identification in 1797 and named the new oxide yttria.[32] In the decades after Antoine Lavoisier developed the first modern definition of chemical elements, it was believed that earths could be reduced to their elements, meaning that the discovery of a new earth was equivalent to the discovery of the element within, which in this case would have been yttrium.[lower-alpha 7][33][34][35]

Friedrich Wöhler is credited with first isolating the metal in 1828 by reacting a volatile chloride that he believed to be yttrium chloride with potassium.[36][37][38]

In 1843, Carl Gustaf Mosander found that samples of yttria contained three oxides: white yttrium oxide (yttria), yellow terbium oxide (confusingly, this was called 'erbia' at the time) and rose-colored erbium oxide (called 'terbia' at the time).[39][40] A fourth oxide, ytterbium oxide, was isolated in 1878 by Jean Charles Galissard de Marignac.[41] New elements were later isolated from each of those oxides, and each element was named, in some fashion, after Ytterby, the village near the quarry where they were found (see ytterbium, terbium, and erbium).[42] In the following decades, seven other new metals were discovered in "Gadolin's yttria".[29] Since yttria was found to be a mineral and not an oxide, Martin Heinrich Klaproth renamed it gadolinite in honor of Gadolin.[29]

Until the early 1920s, the chemical symbol Yt was used for the element, after which Y came into common use.[43][44]

In 1987, yttrium barium copper oxide was found to achieve high-temperature superconductivity.[45] It was only the second material known to exhibit this property,[45] and it was the first-known material to achieve superconductivity above the (economically important) boiling point of nitrogen.[lower-alpha 8]

Occurrence

Three column shaped brown crystals on a white background
Xenotime crystals contain yttrium.

Abundance

Yttrium is found in most rare-earth minerals,[9] it is found in some uranium ores, but is never found in the Earth's crust as a free element.[46] About 31 ppm of the Earth's crust is yttrium,[6] making it the 28th most abundant element, 400 times more common than silver.[47] Yttrium is found in soil in concentrations between 10 and 150 ppm (dry weight average of 23 ppm) and in sea water at 9 ppt.[47] Lunar rock samples collected during the United States Apollo Project have a relatively high content of yttrium.[42]

Yttrium has no known biological role, though it is found in most, if not all, organisms and tends to concentrate in the liver, kidney, spleen, lungs, and bones of humans.[48] Normally, as little as 0.5 milligrams (0.0077 gr) is found in the entire human body; human breast milk contains 4 ppm.[49] Yttrium can be found in edible plants in concentrations between 20 ppm and 100 ppm (fresh weight), with cabbage having the largest amount.[49] With as much as 700 ppm, the seeds of woody plants have the highest known concentrations.[49]

(As of April 2018) there are reports of the discovery of very large reserves of rare-earth elements in the deep seabed several hundred kilometers from the tiny Japanese island of Minami-Torishima Island, also known as Marcus Island. This location is described as having "tremendous potential" for rare-earth elements and yttrium (REY), according to a study published in Scientific Reports.[50] "This REY-rich mud has great potential as a rare-earth metal resource because of the enormous amount available and its advantageous mineralogical features," the study reads. The study shows that more than 16 million short tons (15 billion kilograms) of rare-earth elements could be "exploited in the near future." As well as yttrium (Y), which is used in products like camera lenses and mobile phone screens, the rare-earth elements found are europium (Eu), terbium (Tb), and dysprosium (Dy).[51]

Production

As yttrium is chemically similar to lanthanides, it occurs in the same ores (rare-earth minerals) and is extracted by the same refinement processes. A slight distinction is recognized between the light (LREE) and the heavy rare-earth elements (HREE), but the distinction is not perfect. Yttrium is concentrated in the HREE group because of its ion size, though it has a lower atomic mass.[52][53]

Roughly cube shaped piece of dirty grey metal with an uneven superficial structure.
A piece of yttrium. Yttrium is difficult to separate from other rare-earth elements.

Rare-earth elements (REEs) come mainly from four sources:[54]

  • Carbonate and fluoride containing ores such as the LREE bastnäsite ([(Ce, La, etc.)(CO3)F]) contain an average of 0.1%[12][52] of yttrium compared to the 99.9% for the 16 other REEs.[52] The main source for bastnäsite from the 1960s to the 1990s was the Mountain Pass rare earth mine in California, making the United States the largest producer of REEs during that period.[52][54] The name "bastnäsite" is actually a group name, and the Levinson suffix is used in the correct mineral names, e.g., bästnasite-(Y) has Y as a prevailing element.[55][56][57]
  • Monazite ([(Ce, La, etc.)PO4]), which is mostly phosphate, is a placer deposit of sand created by the transportation and gravitational separation of eroded granite. Monazite as an LREE ore contains 2%[52] (or 3%)[58] yttrium. The largest deposits were found in India and Brazil in the early 20th century, making those two countries the largest producers of yttrium in the first half of that century.[52][54] Of the monazite group, the Ce-dominant member, monazite-(Ce), is the most common one.[59]
  • Xenotime, a REE phosphate, is the main HREE ore containing as much as 60% yttrium as yttrium phosphate (YPO4).[52] This applies to xenotime-(Y).[57][60][56] The largest mine is the Bayan Obo deposit in China, making China the largest exporter for HREE since the closure of the Mountain Pass mine in the 1990s.[52][54]
  • Ion absorption clays or Lognan clays are the weathering products of granite and contain only 1% of REEs.[52] The final ore concentrate can contain as much as 8% yttrium. Ion absorption clays are mostly in southern China.[52][54][61] Yttrium is also found in samarskite and fergusonite (which also stand for group names).[47]

One method for obtaining pure yttrium from the mixed oxide ores is to dissolve the oxide in sulfuric acid and fractionate it by ion exchange chromatography. With the addition of oxalic acid, the yttrium oxalate precipitates. The oxalate is converted into the oxide by heating under oxygen. By reacting the resulting yttrium oxide with hydrogen fluoride, yttrium fluoride is obtained.[62] When quaternary ammonium salts are used as extractants, most yttrium will remain in the aqueous phase. When the counter-ion is nitrate, the light lanthanides are removed, and when the counter-ion is thiocyanate, the heavy lanthanides are removed. In this way, yttrium salts of 99.999% purity are obtained. In the usual situation, where yttrium is in a mixture that is two-thirds heavy-lanthanide, yttrium should be removed as soon as possible to facilitate the separation of the remaining elements.

Annual world production of yttrium oxide had reached 600 tonnes (660 short tons) by 2001; by 2014 it had increased to 6,400 tonnes (7,000 short tons).[47][63] Global reserves of yttrium oxide were estimated in 2014 to be more than 450,000 tonnes (500,000 short tons). The leading countries for these reserves included Australia, Brazil, China, India, and the United States.[63] Only a few tonnes of yttrium metal are produced each year by reducing yttrium fluoride to a metal sponge with calcium magnesium alloy. The temperature of an arc furnace of greater than 1,600 °C is sufficient to melt the yttrium.[47][62]

Applications

Consumer

Forty columns of oval dots, 30 dots high. First red then green then blue. The columns of red starts with only four dots in red from the bottom becoming more with every column to the right
Yttrium is one of the elements that was used to make the red color in CRT televisions.

The red component of color television cathode ray tubes is typically emitted from an yttria (Y2O3) or yttrium oxide sulfide (Y2O2S) host lattice doped with europium (III) cation (Eu3+) phosphors.[12][6][lower-alpha 9] The red color itself is emitted from the europium while the yttrium collects energy from the electron gun and passes it to the phosphor.[64] Yttrium compounds can serve as host lattices for doping with different lanthanide cations. Tb3+ can be used as a doping agent to produce green luminescence. As such yttrium compounds such as yttrium aluminium garnet (YAG) are useful for phosphors and are an important component of white LEDs.

Yttria is used as a sintering additive in the production of porous silicon nitride.[65]

Yttrium compounds are used as a catalyst for ethylene polymerization.[12] As a metal, yttrium is used on the electrodes of some high-performance spark plugs.[66] Yttrium is used in gas mantles for propane lanterns as a replacement for thorium, which is radioactive.[67]

Garnets

Nd:YAG laser rod 0.5 cm (0.20 in) in diameter

Yttrium is used in the production of a large variety of synthetic garnets,[68] and yttria is used to make yttrium iron garnets (Y3Fe5O12, also "YIG"), which are very effective microwave filters[12] which were recently shown to have magnetic interactions more complex and longer-ranged than understood over the previous four decades.[69] Yttrium, iron, aluminium, and gadolinium garnets (e.g. Y
3(Fe,Al)
5O
12 and Y
3(Fe,Gd)
5O
12) have important magnetic properties.[12] YIG is also very efficient as an acoustic energy transmitter and transducer.[70] Yttrium aluminium garnet (Y3Al5O12 or YAG) has a hardness of 8.5 and is also used as a gemstone in jewelry (simulated diamond).[12] Cerium-doped yttrium aluminium garnet (YAG:Ce) crystals are used as phosphors to make white LEDs.[71][72][73]

YAG, yttria, yttrium lithium fluoride (LiYF4), and yttrium orthovanadate (YVO4) are used in combination with dopants such as neodymium, erbium, ytterbium in near-infrared lasers.[74][75] YAG lasers can operate at high power and are used for drilling and cutting metal.[58] The single crystals of doped YAG are normally produced by the Czochralski process.[76]

Material enhancer

Small amounts of yttrium (0.1 to 0.2%) have been used to reduce the grain sizes of chromium, molybdenum, titanium, and zirconium.[77] Yttrium is used to increase the strength of aluminium and magnesium alloys.[12] The addition of yttrium to alloys generally improves workability, adds resistance to high-temperature recrystallization, and significantly enhances resistance to high-temperature oxidation (see graphite nodule discussion below).[64]

Yttrium can be used to deoxidize vanadium and other non-ferrous metals.[12] Yttria stabilizes the cubic form of zirconia in jewelry.[78]

Yttrium has been studied as a nodulizer in ductile cast iron, forming the graphite into compact nodules instead of flakes to increase ductility and fatigue resistance.[12] Having a high melting point, yttrium oxide is used in some ceramic and glass to impart shock resistance and low thermal expansion properties.[12] Those same properties make such glass useful in camera lenses.[47]

Medical

The radioactive isotope yttrium-90 is used in drugs such as Yttrium Y 90-DOTA-tyr3-octreotide and Yttrium Y 90 ibritumomab tiuxetan for the treatment of various cancers, including lymphoma, leukemia, liver, ovarian, colorectal, pancreatic and bone cancers.[49] It works by adhering to monoclonal antibodies, which in turn bind to cancer cells and kill them via intense β-radiation from the yttrium-90 (see monoclonal antibody therapy).[79]

A technique called radioembolization is used to treat hepatocellular carcinoma and liver metastasis. Radioembolization is a low toxicity, targeted liver cancer therapy that uses millions of tiny beads made of glass or resin containing radioactive yttrium-90. The radioactive microspheres are delivered directly to the blood vessels feeding specific liver tumors/segments or lobes. It is minimally invasive and patients can usually be discharged after a few hours. This procedure may not eliminate all tumors throughout the entire liver, but works on one segment or one lobe at a time and may require multiple procedures.[80]

Also see radioembolization in the case of combined cirrhosis and hepatocellular carcinoma.

Needles made of yttrium-90, which can cut more precisely than scalpels, have been used to sever pain-transmitting nerves in the spinal cord,[30] and yttrium-90 is also used to carry out radionuclide synovectomy in the treatment of inflamed joints, especially knees, in people with conditions such as rheumatoid arthritis.[81]

A neodymium-doped yttrium–aluminium–garnet laser has been used in an experimental, robot-assisted radical prostatectomy in canines in an attempt to reduce collateral nerve and tissue damage,[82] and erbium-doped lasers are coming into use for cosmetic skin resurfacing.[6]

Superconductors

Main page: Physics:High-temperature superconductor
Dark grey pills on a watchglass. One cubic piece of the same material on top of the pills.
YBCO superconductor

Yttrium is a key ingredient in the yttrium barium copper oxide (YBa2Cu3O7, aka 'YBCO' or '1-2-3') superconductor developed at the University of Alabama in Huntsville and the University of Houston in 1987.[45] This superconductor is notable because the operating superconductivity temperature is above liquid nitrogen's boiling point (77.1 K).[45] Since liquid nitrogen is less expensive than the liquid helium required for metallic superconductors, the operating costs for applications would be less.

The actual superconducting material is often written as YBa2Cu3O7–d, where d must be less than 0.7 for superconductivity. The reason for this is still not clear, but it is known that the vacancies occur only in certain places in the crystal, the copper oxide planes, and chains, giving rise to a peculiar oxidation state of the copper atoms, which somehow leads to the superconducting behavior.

The theory of low temperature superconductivity has been well understood since the BCS theory of 1957. It is based on a peculiarity of the interaction between two electrons in a crystal lattice. However, the BCS theory does not explain high temperature superconductivity, and its precise mechanism is still a mystery. What is known is that the composition of the copper-oxide materials must be precisely controlled for superconductivity to occur.[83]

This superconductor is a black and green, multi-crystal, multi-phase mineral. Researchers are studying a class of materials known as perovskites that are alternative combinations of these elements, hoping to develop a practical high-temperature superconductor.[58]

Lithium batteries

Yttrium is used in small quantities in the cathodes of some Lithium iron phosphate battery (LFP), which are then commonly called LiFeYPO4 chemistry, or LYP. Similar to LFP, LYP batteries offer high energy density, good safety and long life. But LYP offers higher cathode stability, and prolongs the life of the battery, by protecting the physical structure of the cathode, especially at higher temperatures and higher charging / discharge current. LYP batteries find use in stationary applications (off-grid solar systems), electric vehicles (some cars), as well other applications (submarines, ships), similar to LFP batteries, but often at improved safety and cycle life time. LYP cells have essentially the same nominal voltage as LFP, 3.25 V, but the maximum charging voltage is 4.0 V,[84] and the charging and discharge characteristics are very similar.[85]

Other applications

In 2009, Professor Mas Subramanian and associates at Oregon State University discovered that yttrium can be combined with indium and manganese to form an intensely blue, non-toxic, inert, fade-resistant pigment, YInMn blue, the first new blue pigment discovered in 200 years.

Precautions

Yttrium currently has no known biological role, and it can be highly toxic to humans, animals and plants.[7]

Water-soluble compounds of yttrium are considered mildly toxic, while its insoluble compounds are non-toxic.[49] In experiments on animals, yttrium and its compounds caused lung and liver damage, though toxicity varies with different yttrium compounds. In rats, inhalation of yttrium citrate caused pulmonary edema and dyspnea, while inhalation of yttrium chloride caused liver edema, pleural effusions, and pulmonary hyperemia.[7]

Exposure to yttrium compounds in humans may cause lung disease.[7] Workers exposed to airborne yttrium europium vanadate dust experienced mild eye, skin, and upper respiratory tract irritation—though this may be caused by the vanadium content rather than the yttrium.[7] Acute exposure to yttrium compounds can cause shortness of breath, coughing, chest pain, and cyanosis.[7] The Occupational Safety and Health Administration (OSHA) limits exposure to yttrium in the workplace to 1 mg/m3 (5.8×10−10 oz/cu in) over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit (REL) is 1 mg/m3 (5.8×10−10 oz/cu in) over an 8-hour workday. At levels of 500 mg/m3 (2.9×10−7 oz/cu in), yttrium is immediately dangerous to life and health.[86] Yttrium dust is highly flammable.[7]

See also

Notes

  1. ↑ There is disagreement in the literature whether lanthanum (La) or lutetium (Lu) should be the next element in group 3 below yttrium. A IUPAC project was started on 18 December 2015 to recommend which it should be.
  2. ↑ Essentially, a neutron becomes a proton while an electron and antineutrino are emitted.
  3. ↑ See: magic number
  4. ↑ Metastable isomers have higher-than-normal energy states than the corresponding non-excited nucleus and these states last until a gamma ray or conversion electron is emitted from the isomer. They are designated by an 'm' being placed next to the isotope's mass number.
  5. ↑ Ytterbite was named after the village it was discovered near, plus the -ite ending to indicate it was a mineral.
  6. ↑ Stwertka 1998, p. 115 says that the identification occurred in 1789 but is silent on when the announcement was made. Van der Krogt 2005 cites the original publication, with the year 1794, by Gadolin.
  7. ↑ Earths were given an -a ending and new elements are normally given an -ium ending.
  8. ↑ Tc for YBCO is 93 K and the boiling point of nitrogen is 77 K.
  9. ↑ Emsley 2001, p. 497 says that "Yttrium oxysulfide, doped with europium (III), was used as the standard red component in colour televisions", and Jackson and Christiansen (1993) state that 5–10 g yttrium oxide and 0.5–1 g europium oxide were required to produce a single TV screen, as quoted in Gupta and Krishnamurthy.

References

  1. ↑ Meija, Juris; Coplen, Tyler B.; Berglund, Michael; Brand, Willi A.; De Bièvre, Paul; Gröning, Manfred; Holden, Norman E.; Irrgeher, Johanna et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry 88 (3): 265–91. doi:10.1515/pac-2015-0305. 
  2. ↑ 2.0 2.1 Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see Cloke, F. Geoffrey N. (1993). "Zero Oxidation State Compounds of Scandium, Yttrium, and the Lanthanides". Chem. Soc. Rev. 22: 17–24. doi:10.1039/CS9932200017.  and Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E.; Shabatina, Tatyana I.; Zagorskii, Vyacheslav V.; Cloke (2003-12-15). "Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation". Journal of Organometallic Chemistry 688 (1–2): 49–55. doi:10.1016/j.jorganchem.2003.08.028. 
  3. ↑ Lide, D. R., ed (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5. https://web.archive.org/web/20110303222309/http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf. 
  4. ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4. 
  5. ↑ 5.0 5.1 Connelly N G, ed (2005). Nomenclature of Inorganic Chemistry: IUPAC Recommendations 2005. RSC Publishing. p. 51. ISBN 978-0-85404-438-2. http://publications.iupac.org/books/rbook/Red_Book_2005.pdf. Retrieved 2007-12-17. 
  6. ↑ 6.0 6.1 6.2 6.3 6.4 6.5 6.6 Cotton, Simon A. (2006-03-15). "Scandium, Yttrium & the Lanthanides: Inorganic & Coordination Chemistry". Encyclopedia of Inorganic Chemistry. doi:10.1002/0470862106.ia211. ISBN 978-0-470-86078-6. 
  7. ↑ 7.0 7.1 7.2 7.3 7.4 7.5 7.6 7.7 "Occupational Safety and Health Guideline for Yttrium and Compounds". United States Occupational Safety and Health Administration. 2007-01-11. https://www.osha.gov/SLTC/healthguidelines/yttriumandcompounds/recognition.html.  (public domain text)
  8. ↑ 8.0 8.1 Greenwood 1997, p. 946
  9. ↑ 9.0 9.1 Hammond, C. R. (1985). "Yttrium". The Elements. Fermi National Accelerator Laboratory. pp. 4–33. ISBN 978-0-04-910081-7. http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elements.pdf. Retrieved 2008-08-26. 
  10. ↑ The electronegativity of both scandium and yttrium are between europium and gadolinium.
  11. ↑ 11.0 11.1 11.2 11.3 11.4 11.5 11.6 11.7 11.8 11.9 Daane 1968, p. 817
  12. ↑ 12.00 12.01 12.02 12.03 12.04 12.05 12.06 12.07 12.08 12.09 12.10 12.11 12.12 Lide, David R., ed (2007–2008). "Yttrium". CRC Handbook of Chemistry and Physics. 4. New York: CRC Press. p. 41. ISBN 978-0-8493-0488-0. 
  13. ↑ 13.0 13.1 Emsley 2001, p. 498
  14. ↑ Daane 1968, p. 810.
  15. ↑ Daane 1968, p. 815.
  16. ↑ Greenwood 1997, p. 945
  17. ↑ Greenwood 1997, p. 1234
  18. ↑ Greenwood 1997, p. 948
  19. ↑ Greenwood 1997, p. 947
  20. ↑ 20.0 20.1 20.2 Schumann, Herbert; Fedushkin, Igor L. (2006). "Scandium, Yttrium & The Lanthanides: Organometallic Chemistry". Encyclopedia of Inorganic Chemistry. doi:10.1002/0470862106.ia212. ISBN 978-0-470-86078-6. 
  21. ↑ Nikolai B., Mikheev; Auerman, L. N.; Rumer, Igor A.; Kamenskaya, Alla N.; Kazakevich, M. Z. (1992). "The anomalous stabilisation of the oxidation state 2+ of lanthanides and actinides". Russian Chemical Reviews 61 (10): 990–998. doi:10.1070/RC1992v061n10ABEH001011. Bibcode: 1992RuCRv..61..990M. 
  22. ↑ Kang, Weekyung; E. R. Bernstein (2005). "Formation of Yttrium Oxide Clusters Using Pulsed Laser Vaporization". Bull. Korean Chem. Soc. 26 (2): 345–348. doi:10.5012/bkcs.2005.26.2.345. 
  23. ↑ Turner, Francis M. Jr.; Berolzheimer, Daniel D.; Cutter, William P.; Helfrich, John (1920). The Condensed Chemical Dictionary. New York: Chemical Catalog Company. pp. 492. https://archive.org/details/condchemdiction00chemrich. Retrieved 2008-08-12. "Yttrium chloride." 
  24. ↑ Spencer, James F. (1919). The Metals of the Rare Earths. New York: Longmans, Green, and Co.. pp. 135. https://archive.org/details/metalsrareearth00spengoog. Retrieved 2008-08-12. "Yttrium chloride." 
  25. ↑ Pack, Andreas; Sara S. Russell; J. Michael G. Shelley; Mark van Zuilen (2007). "Geo- and cosmochemistry of the twin elements yttrium and holmium". Geochimica et Cosmochimica Acta 71 (18): 4592–4608. doi:10.1016/j.gca.2007.07.010. Bibcode: 2007GeCoA..71.4592P. 
  26. ↑ 26.0 26.1 26.2 26.3 Greenwood 1997, pp. 12–13
  27. ↑ 27.0 27.1 27.2 27.3 27.4 27.5 27.6 27.7 Alejandro A. Sonzogni (Database Manager), ed (2008). "Chart of Nuclides". Upton, New York: National Nuclear Data Center, Brookhaven National Laboratory. http://www.nndc.bnl.gov/chart/. 
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  30. ↑ 30.0 30.1 Emsley 2001, p. 496
  31. ↑ Gadolin 1794
  32. ↑ Greenwood 1997, p. 944
  33. ↑ Marshall, James L. Marshall; Marshall, Virginia R. Marshall (2015). "Rediscovery of the elements: The Rare Earths–The Beginnings". The Hexagon: 41–45. http://www.chem.unt.edu/~jimm/REDISCOVERY%207-09-2018/Hexagon%20Articles/rare%20earths%20I.pdf. Retrieved 30 December 2019. 
  34. ↑ Marshall, James L. Marshall; Marshall, Virginia R. Marshall (2015). "Rediscovery of the elements: The Rare Earths–The Confusing Years". The Hexagon: 72–77. http://www.chem.unt.edu/~jimm/REDISCOVERY%207-09-2018/Hexagon%20Articles/rare%20earths%20II.pdf. Retrieved 30 December 2019. 
  35. ↑ Weeks, Mary Elvira (1956). The discovery of the elements (6th ed.). Easton, PA: Journal of Chemical Education. https://archive.org/details/discoveryoftheel002045mbp. 
  36. ↑ "Yttrium". 2020. https://www.rsc.org/periodic-table/element/39/yttrium. 
  37. ↑ Wöhler, Friedrich (1828). "Ueber das Beryllium und Yttrium". Annalen der Physik 89 (8): 577–582. doi:10.1002/andp.18280890805. Bibcode: 1828AnP....89..577W. https://zenodo.org/record/1423522. 
  38. ↑ Heiserman, David L. (1992). "Element 39: Yttrium". Exploring Chemical Elements and their Compounds. New York: TAB Books. pp. 150–152. ISBN:0-8306-3018-X.
  39. ↑ Heiserman, David L. (1992). "Carl Gustaf Mosander and his Research on rare Earths". Exploring Chemical Elements and their Compounds. New York: TAB Books. p. 41. ISBN 978-0-8306-3018-9. https://archive.org/details/exploringchemica01heis. 
  40. ↑ "Ueber die das Cerium begleitenden neuen Metalle Lathanium und Didymium, so wie über die mit der Yttererde vorkommen-den neuen Metalle Erbium und Terbium" (in de). Annalen der Physik und Chemie 60 (2): 297–315. 1843. doi:10.1002/andp.18431361008. Bibcode: 1843AnP...136..297M. https://zenodo.org/record/1423592. 
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  42. ↑ 42.0 42.1 Stwertka 1998, p. 115.
  43. ↑ Coplen, Tyler B.; Peiser, H. S. (1998). "History of the Recommended Atomic-Weight Values from 1882 to 1997: A Comparison of Differences from Current Values to the Estimated Uncertainties of Earlier Values (Technical Report)". Pure Appl. Chem. 70 (1): 237–257. doi:10.1351/pac199870010237. https://zenodo.org/record/1236255. 
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  45. ↑ 45.0 45.1 45.2 45.3 Wu, M. K. et al. (1987). "Superconductivity at 93 K in a New Mixed-Phase Y-Ba-Cu-O Compound System at Ambient Pressure". Physical Review Letters 58 (9): 908–910. doi:10.1103/PhysRevLett.58.908. PMID 10035069. Bibcode: 1987PhRvL..58..908W. 
  46. ↑ "yttrium". Lenntech. http://www.lenntech.com/periodic-chart-elements/y-en.htm. 
  47. ↑ 47.0 47.1 47.2 47.3 47.4 47.5 Emsley 2001, p. 497
  48. ↑ MacDonald, N. S.; Nusbaum, R. E.; Alexander, G. V. (1952). "The Skeletal Deposition of Yttrium". Journal of Biological Chemistry 195 (2): 837–841. doi:10.1016/S0021-9258(18)55794-X. PMID 14946195. 
  49. ↑ 49.0 49.1 49.2 49.3 49.4 Emsley 2001, p. 495
  50. ↑ Takaya et a., Yutaro (10 April 2018). "The tremendous potential of deep-sea mud as a source of rare-earth elements". Scientific Reports 8 (5763): 5763. doi:10.1038/s41598-018-23948-5. PMID 29636486. Bibcode: 2018NatSR...8.5763T. 
  51. ↑ "Treasure island: Rare metals discovery on remote Pacific atoll is worth billions of dollars". 2018-04-19. http://www.foxnews.com/science/2018/04/19/treasure-island-rare-metals-discovery-on-remote-pacific-atoll-is-worth-billions-dollars.html. 
  52. ↑ 52.0 52.1 52.2 52.3 52.4 52.5 52.6 52.7 52.8 52.9 Morteani, Giulio (1991). "The rare earths; their minerals, production and technical use". European Journal of Mineralogy 3 (4): 641–650. doi:10.1127/ejm/3/4/0641. Bibcode: 1991EJMin...3..641M. http://eurjmin.geoscienceworld.org/cgi/content/abstract/3/4/641. 
  53. ↑ Kanazawa, Yasuo; Kamitani, Masaharu (2006). "Rare earth minerals and resources in the world". Journal of Alloys and Compounds 408–412: 1339–1343. doi:10.1016/j.jallcom.2005.04.033. 
  54. ↑ 54.0 54.1 54.2 54.3 54.4 Naumov, A. V. (2008). "Review of the World Market of Rare-Earth Metals". Russian Journal of Non-Ferrous Metals 49 (1): 14–22. doi:10.1007/s11981-008-1004-6. https://link.springer.com/article/10.1007/s11981-008-1004-6. 
  55. ↑ "Mindat.org - Mines, Minerals and More". https://www.mindat.org/. 
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  58. ↑ 58.0 58.1 58.2 Stwertka 1998, p. 116
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  60. ↑ "Xenotime-(Y): Mineral information, data and localities.". https://www.mindat.org/min-4333.html. 
  61. ↑ Zheng, Zuoping; Lin Chuanxian (1996). "The behaviour of rare-earth elements (REE) during weathering of granites in southern Guangxi, China". Chinese Journal of Geochemistry 15 (4): 344–352. doi:10.1007/BF02867008. 
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  75. ↑ Tokurakawa, M.; Takaichi, K.; Shirakawa, A.; Ueda, K.; Yagi, H.; Yanagitani, T.; Kaminskii, A. A. (2007). "Diode-pumped 188 fs mode-locked Yb3+:Y2O3 ceramic laser". Applied Physics Letters 90 (7): 071101. doi:10.1063/1.2476385. Bibcode: 2007ApPhL..90g1101T. 
  76. ↑ Golubović, Aleksandar V.; Nikolić, Slobodanka N.; Gajić, Radoš; Đurić, Stevan; Valčić, Andreja (2002). "The growth of Nd: YAG single crystals". Journal of the Serbian Chemical Society 67 (4): 91–300. doi:10.2298/JSC0204291G. 
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  78. ↑ Berg, Jessica. "Cubic Zirconia". Emporia State University. http://www.emporia.edu/earthsci/amber/go340/students/berg/cz.html. 
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  86. ↑ "CDC – NIOSH Pocket Guide to Chemical Hazards – Yttrium". https://www.cdc.gov/niosh/npg/npgd0673.html. 

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Yttrium

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