Chemistry:Loveringite

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Loveringite
General
CategoryOxide minerals
Formula
(repeating unit)
(Ca,Ce)(Ti,Fe,Cr,Mg)
21
O
38
Strunz classification4.CC.40
Crystal systemTrigonal
Crystal classRhombohedral (3)
(same H-M symbol)
Space groupR3
Unit cella = 10.33, c = 20.67 [Å]; Z = 3
Identification
ColorBlack
Crystal habitAnhedral, can be acicular - occurs as needle-like crystals
Fractureconchoidal
Mohs scale hardness7.5
|re|er}}Metallic
StreakGrayish black
DiaphaneityOpaque
Specific gravity4.41
Optical propertiesUniaxial
Other characteristicsmetamict due to trace to minor uranium substitution
References[1][2][3]

Loveringite is a rare metallic oxide mineral of the crichtonite group with the chemical formula (Ca,Ce)(Ti,Fe,Cr,Mg)
21
O
38
. It is a late-stage magmatic mineral, formed in the residual melt of mafic layered intrusions in either the olivine-chromite, pyroxene, or plagioclase-rich layers.[3]

Discovery and occurrence

Loveringite was discovered in 1978 in the Jimberlana Intrusion, Dundas Shire, Western Australia,[2] and was named for Australian geochemist and University of Melbourne professor John Francis Lovering, in recognition of his work on fission-track methods in geochemistry.[1][3]

Loveringite has also been generally found in areas of medium-grade metamorphism, reported from the Hoggar Mountains of Algeria; the Hohe Tauern Mountains, Salzburg, Austria; the Koitelainen intrusion of Lappland, Finland ; Bourg d’Oisans, Isere, France ; Bracco, Liguria, Italy; the Kerguelen Islands; the Khibiny Massif in the Kola Peninsula of Russia ;[2][3] and at Makwiro on the Great Dyke in Zimbabwe.[4]

Crystallography

Loveringite is trigonal (crystal system), rhombohedral (crystal class), meaning it contains three equal axes each related by 120° and one axis perpendicular to these. It has a three-fold rotation axis as well as a center of symmetry and belongs to the space group R3.[5] Loveringite is found to be grayish white to gray in plane polarized light and does not display pleochroism. Additionally, when viewed in plane polarized light, Loveringite is found to have high relief and has sharp grain boundaries, shows fractures and cleavages well, and sticks out above other minerals in the thin section. Reflectance data indicates that loveringite is anisotropic, showing properties of different values when measured in different directions.

References

  1. 1.0 1.1 Webmineral data
  2. 2.0 2.1 2.2 Mindat with locations
  3. 3.0 3.1 3.2 3.3 Handbook of Mineralogy
  4. Stribrny, B., Wellmer, F. W., Burgath, K. P., Oberthür, T., Tarkian, M., Pfeiffer, T. (2000). "Unconventional PGE occurrences and PGE mineralization in the Great Dyke: metallogenic and economic aspects". Mineralium Deposita 35 (2–3): 260–280. doi:10.1007/s001260050019. 
  5. Gatehouse, B. M., I. E. Grey, I. H. Campbell and P. Kelly (1978). The crystal structure of loveringite-a new member of the crichtonite group. American Mineralogist, 63, 28-36