Chemistry:Olivine

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Short description: Magnesium iron silicate solid solution series mineral
Olivine
Olivine-gem7-10a.jpg
General
CategoryNesosilicate
Olivine group
Olivine series
Formula
(repeating unit)		(Mg,Fe)
2SiO
4
Strunz classification9.AC.05
Crystal systemOrthorhombic
Space groupPbnm (no. 62)
Identification
ColorYellow to yellow-green
Crystal habitMassive to granular
CleavagePoor
FractureConchoidal
Tenacitybrittle
Mohs scale hardness6.5–7.0
|re|er}}Vitreous
Streakcolorless or white
DiaphaneityTransparent to translucent
Specific gravity3.2–4.5[1][2][3][4]
Optical propertiesBiaxial (+)
Refractive indexnα = 1.630–1.650
nβ = 1.650–1.670
nγ = 1.670–1.690
Birefringenceδ = 0.040
References[5][6][7]

The mineral olivine (/ˈɒl.ɪˌviːn/) is a magnesium iron silicate with the chemical formula (Mg,Fe)
2SiO
4. It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle,[9] it is a common mineral in Earth's subsurface, but weathers quickly on the surface. For this reason, olivine has been proposed as a good candidate for accelerated weathering to sequester carbon dioxide from the Earth's oceans and atmosphere, as part of climate change mitigation. Olivine also has many other historical uses, such as the gemstone peridot (or chrysolite), as well as industrial applications like metalworking processes.

Olivine in cross-polarized light

The ratio of magnesium to iron varies between the two endmembers of the solid solution series: forsterite (Mg-endmember: Mg2SiO4) and fayalite (Fe-endmember: Fe2SiO4). Compositions of olivine are commonly expressed as molar percentages of forsterite (Fo) and/or fayalite (Fa) (e.g., Fo70Fa30, or just Fo70 with Fa30 implied). Forsterite's melting temperature is unusually high at atmospheric pressure, almost 1,900 °C (3,450 °F), while fayalite's is much lower – about 1,200 °C (2,190 °F). Melting temperature varies smoothly between the two endmembers, as do other properties. Olivine incorporates only minor amounts of elements other than oxygen (O), silicon (Si), magnesium (Mg) and iron (Fe). Manganese (Mn) and nickel (Ni) commonly are the additional elements present in highest concentrations.

Olivine gives its name to the group of minerals with a related structure (the olivine group) – which includes tephroite (Mn2SiO4), monticellite (CaMgSiO4), larnite (Ca2SiO4) and kirschsteinite (CaFeSiO4) (commonly also spelled kirschteinite[10]).

Olivine's crystal structure incorporates aspects of the orthorhombic P Bravais lattice, which arise from each silica (SiO4) unit being joined by metal divalent cations with each oxygen in SiO4 bound to three metal ions. It has a spinel-like structure similar to magnetite but uses one quadrivalent and two divalent cations M22+ M4+O4 instead of two trivalent and one divalent cations.[11]

Identification and paragenesis

Olivine is named for its typically olive-green color, thought to be a result of traces of nickel,[citation needed] though it may alter to a reddish color from the oxidation of iron.

Translucent olivine is sometimes used as a gemstone called peridot (péridot, the French word for olivine). It is also called chrysolite (or chrysolithe, from the Greek words for gold and stone), though this name is now rarely used in the English language. Some of the finest gem-quality olivine has been obtained from a body of mantle rocks on Zabargad Island in the Red Sea.[12][13]

Olivine occurs in both mafic and ultramafic igneous rocks and as a primary mineral in certain metamorphic rocks. Mg-rich olivine crystallizes from magma that is rich in magnesium and low in silica. That magma crystallizes to mafic rocks such as gabbro and basalt.[14] Ultramafic rocks usually contain substantial olivine, and those with an olivine content of over 40% are described as peridotites. Dunite has an olivine content of over 90% and is likely a cumulate formed by olivine crystallizing and settling out of magma or a vein mineral lining magma conduits.[15] Olivine and high pressure structural variants constitute over 50% of the Earth's upper mantle, and olivine is one of the Earth's most common minerals by volume.[16] The metamorphism of impure dolomite or other sedimentary rocks with high magnesium and low silica content also produces Mg-rich olivine, or forsterite.

Fe-rich olivine fayalite is relatively much less common, but it occurs in igneous rocks in small amounts in rare granites and rhyolites, and extremely Fe-rich olivine can exist stably with quartz and tridymite. In contrast, Mg-rich olivine does not occur stably with silica minerals, as it would react with them to form orthopyroxene ((Mg,Fe)
2Si
2O
6).

Mg-rich olivine is stable to pressures equivalent to a depth of about 410 km (250 mi) within Earth. Because it is thought to be the most abundant mineral in Earth's mantle at shallower depths, the properties of olivine have a dominant influence upon the rheology of that part of Earth and hence upon the solid flow that drives plate tectonics. Experiments have documented that olivine at high pressures (12 GPa, the pressure at depths of about 360 km (220 mi)) can contain at least as much as about 8900 parts per million (weight) of water, and that such water content drastically reduces the resistance of olivine to solid flow. Moreover, because olivine is so abundant, more water may be dissolved in olivine of the mantle than is contained in Earth's oceans.[17]

Olivine pine forest (a plant community) is unique to Norway. It is rare and found on dry olivine ridges in the fjord districts of Sunnmøre and Nordfjord.[18]

  • Olivine grains that eroded from lava on Papakolea Beach, Hawaii

  • Light green olivine crystals in peridotite xenoliths in basalt from Arizona

  • Olivine basalt from the Moon, collected in 1971 by the crew of Apollo 15

  • Bright green olivine from Pakistan, showing chisel termination and silky luster

  • Olivine in lava from the Azores

Extraterrestrial occurrences

Crystals of olivine embedded in iron, in a slice of Esquel, a pallasite meteorite

Mg-rich olivine has also been discovered in meteorites,[19] on the Moon[20] and Mars,[21][22] falling into infant stars,[23] as well as on asteroid 25143 Itokawa.[24] Such meteorites include chondrites, collections of debris from the early Solar System; and pallasites, mixes of iron-nickel and olivine. The rare A-type asteroids are suspected to have a surface dominated by olivine.[25]

The spectral signature of olivine has been seen in the dust disks around young stars. The tails of comets (which formed from the dust disk around the young Sun) often have the spectral signature of olivine, and the presence of olivine was verified in samples of a comet from the Stardust spacecraft in 2006.[26] Comet-like (magnesium-rich) olivine has also been detected in the planetesimal belt around the star Beta Pictoris.[27]

Crystal structure

Figure 1: The atomic scale structure of olivine looking along the a axis. Oxygen is shown in red, silicon in pink, and magnesium/iron in blue. A projection of the unit cell is shown by the black rectangle.

Minerals in the olivine group crystallize in the orthorhombic system (space group Pbnm) with isolated silicate tetrahedra, meaning that olivine is a nesosilicate. The structure can be described as a hexagonal, close-packed array of oxygen ions with half of the octahedral sites occupied with magnesium or iron ions and one-eighth of the tetrahedral sites occupied by silicon ions.

There are three distinct oxygen sites (marked O1, O2 and O3 in figure 1), two distinct metal sites (M1 and M2) and only one distinct silicon site. O1, O2, M2 and Si all lie on mirror planes, while M1 exists on an inversion center. O3 lies in a general position.

High-pressure polymorphs

At the high temperatures and pressures found at depth within the Earth the olivine structure is no longer stable. Below depths of about 410 km (250 mi) olivine undergoes an exothermic phase transition to the sorosilicate, wadsleyite and, at about 520 km (320 mi) depth, wadsleyite transforms exothermically into ringwoodite, which has the spinel structure. At a depth of about 660 km (410 mi), ringwoodite decomposes into silicate perovskite ((Mg,Fe)SiO
3) and ferropericlase ((Mg,Fe)O) in an endothermic reaction. These phase transitions lead to a discontinuous increase in the density of the Earth's mantle that can be observed by seismic methods. They are also thought to influence the dynamics of mantle convection in that the exothermic transitions reinforce flow across the phase boundary, whereas the endothermic reaction hampers it.[28]

The pressure at which these phase transitions occur depends on temperature and iron content.[29] At 800 °C (1,070 K; 1,470 °F), the pure magnesium end member, forsterite, transforms to wadsleyite at 11.8 gigapascals (116,000 atm) and to ringwoodite at pressures above 14 GPa (138,000 atm). Increasing the iron content decreases the pressure of the phase transition and narrows the wadsleyite stability field. At about 0.8 mole fraction fayalite, olivine transforms directly to ringwoodite over the pressure range 10.0 to 11.5 GPa (99,000–113,000 atm). Fayalite transforms to Fe2SiO4 spinel at pressures below 5 GPa (49,000 atm). Increasing the temperature increases the pressure of these phase transitions.

Weathering

Olivine altered to iddingsite within a mantle xenolith.

Olivine is one of the less stable common minerals on the surface according to the Goldich dissolution series. It alters into iddingsite (a combination of clay minerals, iron oxides and ferrihydrite) readily in the presence of water.[30] Artificially increasing the weathering rate of olivine, e.g. by dispersing fine-grained olivine on beaches, has been proposed as a cheap way to sequester CO2.[31][32] The presence of iddingsite on Mars would suggest that liquid water once existed there, and might enable scientists to determine when there was last liquid water on the planet.[33]

Because of its rapid weathering, olivine is rarely found in sedimentary rock.[34]

Mining

Norway

Open-pit mining at Sunnylvsfjorden, Hurtigruten ship passing.

Norway is the main source of olivine in Europe, particularly in an area stretching from Åheim to Tafjord, and from Hornindal to Flemsøy in the Sunnmøre district. There is also olivine in Eid municipality. About 50% of the world's olivine for industrial use is produced in Norway. At Svarthammaren in Norddal olivine was mined from around 1920 to 1979, with a daily output up to 600 metric tons. Olivine was also obtained from the construction site of the hydro power stations in Tafjord. At Robbervika in Norddal municipality an open-pit mine has been in operation since 1984. The characteristic red color is reflected in several local names with "red" such as Raudbergvik (Red rock bay) or Raudnakken (Red ridge).[35][36][37][38]

Hans Strøm in 1766 described the olivine's typical red color on the surface and the blue color within. Strøm wrote that in Norddal district large quantities of olivine were broken from the bedrock and used as sharpening stones.[39]

Kallskaret near Tafjord is a nature reserve with olivine.[40]

Uses

A worldwide search is on for cheap processes to sequester CO2 by mineral reactions, called enhanced weathering. Removal by reactions with olivine is an attractive option, because it is widely available and reacts easily with the (acid) CO2 from the atmosphere. When olivine is crushed, it weathers completely within a few years, depending on the grain size. All the CO2 that is produced by burning one liter of oil can be sequestered by less than one liter of olivine. The reaction is exothermic but slow. To recover the heat produced by the reaction to produce electricity, a large volume of olivine must be thermally well-isolated. The end-products of the reaction are silicon dioxide, magnesium carbonate, and small amounts of iron oxide.[41][42] A nonprofit, Project Vesta, is investigating this approach on beaches which increase the agitation and surface area of crushed olivine through wave action.[43]

Olivine is used as a substitute for dolomite in steel works.[44]

The aluminium foundry industry uses olivine sand to cast objects in aluminium. Olivine sand requires less water than silica sands while still holding the mold together during handling and pouring of the metal. Less water means less gas (steam) to vent from the mold as metal is poured into the mold.[45]

In Finland, olivine is marketed as an ideal rock for sauna stoves because of its comparatively high density and resistance to weathering under repeated heating and cooling.[46]

Gem-quality olivine is used as a gemstone called peridot.

See also

References

  1. ↑ Mick R. Smith (1999). Stone: Building Stone, Rock Fill and Armourstone in Construction. Geological Society of London. pp. 62–. ISBN 978-1-86239-029-4. https://books.google.com/books?id=Xcuoyxo33nsC&pg=PA62. "Specific Gravity 3.5–4.5" 
  2. ↑ Jessica Elzea Kogel (2006). Industrial Minerals & Rocks: Commodities, Markets, and Uses. SME. pp. 679–. ISBN 978-0-87335-233-8. https://books.google.com/books?id=zNicdkuulE4C&pg=PA679. "The specific gravity is approximately 3.2 when pure rises with increasing iron content." 
  3. ↑ "Olivine". Science.smith.edu. http://www.science.smith.edu/geosciences/petrology/Petrography/Olivine/Olivine.html. "G = 3.22 to 4.39. Specific gravity increases and hardness decreases with increasing Fe." 
  4. ↑ "University of Minnesota's Mineral Pages: Olivine". Geo.umn.edu. http://www.geo.umn.edu/courses/1001/minerals/olivine.shtml. "Specific Gravity: 3.2 (Mg-rich variety) to 4.3 (Iron-rich variety) (average weight)" 
  5. ↑ Olivine . Webmineral.com Retrieved on 2012-06-16.
  6. ↑ Olivine . Mindat.org Retrieved on 2012-06-16.
  7. ↑ Klein, Cornelis; C. S. Hurlburt (1985). Manual of Mineralogy (20th ed.). New York: John Wiley & Sons. ISBN 978-0-471-80580-9. https://archive.org/details/manualofmineralo00klei. 
  8. ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. 
  9. ↑ Garlick, Sarah (2014). Pocket Guide to the Rocks & Minerals of North America. National Geographic Society. p. 23. ISBN 9781426212826. 
  10. ↑ Klein & Hurlbut 1985, p. 373.
  11. ↑ Ernst, W. G. Earth Materials. Englewood Cliffs, NJ: Prentice-Hall, 1969. p. 65
  12. ↑ St. John's Island peridot information and history at Mindat.org
  13. ↑ Gubelin, Edward (Spring 1981). "Zabargad: The ancient peridot island in the Red Sea". Gems & Gemology 17: 2–8. doi:10.5741/GEMS.17.1.2. https://www.gia.edu/doc/Spring-1981-Gems-Gemology-Zabargad-Peridot-Island-Red-Sea.pdf. Retrieved 6 February 2021. 
  14. ↑ Klein & Hurlbut 1985, pp. 374-375.
  15. ↑ Philpotts, Anthony R.; Ague, Jay J. (2009). Principles of igneous and metamorphic petrology (2nd ed.). Cambridge, UK: Cambridge University Press. pp. 44, 138, 142, 385. ISBN 9780521880060. 
  16. ↑ McDonough, W.F.; Rudnick, R.L. (1998). "Mineralogy and composition of the upper mantle". Reviews in Mineralogy 37: 139–164. https://www.researchgate.net/publication/284507003. Retrieved 6 February 2021. 
  17. ↑ Smyth, J. R.; Frost, D. J.; Nestola, F.; Holl, C. M.; Bromiley, G. (2006). "Olivine hydration in the deep upper mantle: Effects of temperature and silica activity". Geophysical Research Letters 33 (15): L15301. doi:10.1029/2006GL026194. Bibcode: 2006GeoRL..3315301S. http://ruby.colorado.edu/~smyth/Research/Papers/Hydrolivine.pdf. Retrieved 2017-10-26. 
  18. ↑ Brandrud, T.E. (2009). "Olivinfuruskog og rødlistearter i Bjørkedalen, Volda: naturverdi og forvaltningsmuligheter" (in norwegian). NINA Rapport 461. https://brage.nina.no/nina-xmlui/handle/11250/2397756. Retrieved 14 February 2021. 
  19. ↑ Fukang and other Pallasites . Farlang.com (2008-04-30). Retrieved on 2012-06-16.
  20. ↑ Meyer, C. (2003). "Mare Basalt Volcanism". NASA Lunar Petrographic Educational Thin Section Set. NASA. https://curator.jsc.nasa.gov/lunar/letss/mare3.pdf. 
  21. ↑ Pretty Green Mineral.... Mission Update 2006... UMD Deep Impact Website, University of Maryland Ball Aerospace & Technology Corp. retrieved June 1, 2010
  22. ↑ Hoefen, T.M., et al. 2003. "Discovery of Olivine in the Nili Fossae Region of Mars". Science 302, 627–30. "Hoefen, T. M. (2003). "Discovery of Olivine in the Nili Fossae Region of Mars". Science 302 (5645): 627–630. doi:10.1126/science.1089647. PMID 14576430. Bibcode: 2003Sci...302..627H. https://zenodo.org/record/1230836. "
  23. ↑ Spitzer Sees Crystal Rain... NASA Website
  24. ↑ Japan says Hayabusa brought back asteroid grains... retrieved November 18, 2010
  25. ↑ Sanchez, Juan A. et al. (January 2014). "Olivine-dominated asteroids: Mineralogy and origin". Icarus 228: 288–300. doi:10.1016/j.icarus.2013.10.006. Bibcode: 2014Icar..228..288S. 
  26. ↑ Press Release 06-091 . Jet Propulsion Laboratory Stardust website, retrieved May 30, 2006.
  27. ↑ De Vries, B. L.; Acke, B.; Blommaert, J. A. D. L.; Waelkens, C.; Waters, L. B. F. M.; Vandenbussche, B.; Min, M.; Olofsson, G. et al. (2012). "Comet-like mineralogy of olivine crystals in an extrasolar proto-Kuiper belt". Nature 490 (7418): 74–76. doi:10.1038/nature11469. PMID 23038467. Bibcode: 2012Natur.490...74D. 
  28. ↑ Christensen, U.R. (1995). "Effects of phase transitions on mantle convection". Annu. Rev. Earth Planet. Sci. 23: 65–87. doi:10.1146/annurev.ea.23.050195.000433. Bibcode: 1995AREPS..23...65C. 
  29. ↑ Deer, W. A.; R. A. Howie; J. Zussman (1992). An Introduction to the Rock-Forming Minerals (2nd ed.). London: Longman. ISBN 978-0-582-30094-1. 
  30. ↑ Kuebler, K.; Wang, A.; Haskin, L. A.; Jolliff, B. L. (2003). "A Study of Olivine Alteration to Iddingsite Using Raman Spectroscopy". Lunar and Planetary Science 34: 1953. Bibcode: 2003LPI....34.1953K. http://www.lpi.usra.edu/meetings/lpsc2003/pdf/1953.pdf. 
  31. ↑ "CO2 Mineral Sequestration Studies in US". 2001. https://www.netl.doe.gov/publications/proceedings/01/carbon_seq/6c1.pdf. 
  32. ↑ "Olivine against climate change and ocean acidification". http://www.innovationconcepts.eu/res/literatuurSchuiling/olivineagainstclimatechange23.pdf. 
  33. ↑ Swindle, T. D.; Treiman, A. H.; Lindstrom, D. J.; Burkland, M. K.; Cohen, B. A.; Grier, J. A.; Li, B.; Olson, E. K. (2000). "Noble Gases in Iddingsite from the Lafayette meteorite: Evidence for Liquid water on Mars in the last few hundred million years". Meteoritics and Planetary Science 35 (1): 107–15. doi:10.1111/j.1945-5100.2000.tb01978.x. Bibcode: 2000M&PS...35..107S. 
  34. ↑ Velbel, Michael A. (October 2009). "Dissolution of olivine during natural weathering". Geochimica et Cosmochimica Acta 73 (20): 6098–6113. doi:10.1016/j.gca.2009.07.024. Bibcode: 2009GeCoA..73.6098V. 
  35. ↑ Furseth, Astor (1987): Norddal i 150 år. Valldal: Norddal kommune.
  36. ↑ Geological Survey of Norway. Kart over mineralressurser . Accessed 9.12.2012.
  37. ↑ "Olivin" (in nb). http://www.ngu.no/fagomrade/olivin. 
  38. ↑ Gjelsvik, T. (1951). Oversikt over bergartene i Sunnmøre og tilgrensende deler av Nordfjord . Norge geologiske undersøkelser, report 179.
  39. ↑ Strøm, Hans: Physisk og Oeconomisk Beskrivelse over Fogderiet Søndmør beliggende i Bergen Stift i Norge. Published in Sorø, Denmark, 1766.
  40. ↑ "Kallskaret". 28 September 2014. http://snl.no/Kallskaret. 
  41. ↑ Goldberg, P.; Chen, Z.-Y.; O'Connor, W.; Walters, R.; Ziock, H. (2000). "CO2 Mineral Sequestration Studies in US". Technology 1 (1): 1–10. http://www.netl.doe.gov/publications/proceedings/01/carbon_seq/6c1.pdf. Retrieved 2008-07-07. 
  42. ↑ Schuiling, R. D.; Krijgsman, P. (2006). "Enhanced Weathering: An Effective and Cheap Tool to Sequester CO2". Climatic Change 74 (1–3): 349–54. doi:10.1007/s10584-005-3485-y. Bibcode: 2006ClCh...74..349S. 
  43. ↑ Delbert, Caroline (2020-06-11). "How This Strange Green Sand Could Reverse Climate Change" (in en-US). https://www.popularmechanics.com/science/environment/a32799266/green-sand-carbon-dioxide-climate-change/. 
  44. ↑ Mineralressurser i Norge ; Mineralstatistikk og bergverksberetning 2006. Trondheim: Bergvesenet med bergmesteren for Svalbard. 2007.
  45. ↑ Ammen, C. W. (1980). The Metal Caster's Bible. Blue Ridge Summit PA: TAB. p. 331. ISBN 978-0-8306-9970-4. https://archive.org/details/metalcastersbibl00amme/page/331. 
  46. ↑ "The olivine stone". https://suomenkiuaskivi.fi/en/the-olivine-stone/. 

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