Chemistry:Nickel azide
From HandWiki
| Names | |
|---|---|
| IUPAC name
Nickel(II) diazide
| |
| Other names
Nickel diazide
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
PubChem CID
|
|
| |
| |
| Properties | |
| Ni(N 3) 2 | |
| Molar mass | 142.73 g/mol |
| Hazards | |
| GHS pictograms | 
|
| GHS Signal word | Danger |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Nickel azide is an inorganic chemical compound with the formula Ni(N
3)
2. It can be formed through the reaction between nickel tetracarbonyl and iodine azide.[1]
- 2Ni(CO)
4 + 2IN
3 → Ni(N
3)
2 + NiI
2 + 8CO
Properties
Nickel azide water solution has high absorbance in the ultraviolet with a peak at 292 nm. The solution also contains hexaaquanickel cations with visible light absorption peaks at 394, 656, and 720 nm.[2] A related mixed anion compound with nicotinic acid and nicotinate exhibits EO bridging coordination (μ-1,1) on the azide, and possesses an unusual angle between the nickel and nitrogen present within the complex.[3] Like most azides, it is explosive.
References
- ↑ Dehnicke, K.; Dübgen, R. (1 September 1978). "Die Reaktionen des Jodazids mit Metallcarbonylen" (in de). Zeitschrift für anorganische und allgemeine Chemie 444 (1): 61–70. doi:10.1002/zaac.19784440106. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19784440106. Retrieved 2023-10-30.
- ↑ Egghart, H. C. (26 August 1968). "A study of nickel-azido complex formation in aqueous solution". J. Inorg. Nucl. Chem. 31 (5): 1538–1541. doi:10.1016/0022-1902(69)80278-2. https://dx.doi.org/10.1016/0022-1902%2869%2980278-2. Retrieved 30 October 2023.
- ↑ Liu, Fu-Chen; Zeng, Yong-Fei; Li, Jian-Rong; Bu, Xian-He; Zhang, Hong-Jie; Ribas, Joan (15 September 2005). "Novel 3-D Framework Nickel(II) Complex with Azide, Nicotinic Acid, and Nicotinate(1−) as Coligands: Hydrothermal Synthesis, Structure, and Magnetic Properties". Inorganic Chemistry 44 (21): 7298–7300. doi:10.1021/ic051030b. PMID 16212349. https://pubs.acs.org/doi/10.1021/ic051030b. Retrieved 30 October 2023.
Salts and covalent derivatives of the azide ion
| |||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| HN3 | He | ||||||||||||||||||
| LiN3 | Be(N3)2 | B(N3)3 | CH3N3, C(N3)4 |
N(N3)3,H2N—N3 | O | FN3 | Ne | ||||||||||||
| NaN3 | Mg(N3)2 | Al(N3)3 | Si(N3)4 | P | SO2(N3)2 | ClN3 | Ar | ||||||||||||
| KN3 | Ca(N3)2 | Sc(N3)3 | Ti(N3)4 | VO(N3)3 | Cr(N3)3, CrO2(N3)2 |
Mn(N3)2 | Fe(N3)3 | Co(N3)2, Co(N3)3 |
Ni(N3)2 | CuN3, Cu(N3)2 |
Zn(N3)2 | Ga(N3)3 | Ge | As | Se(N3)4 | BrN3 | Kr | ||
| RbN3 | Sr(N3)2 | Y | Zr(N3)4 | Nb | Mo | Tc | Ru(N3)63− | Rh(N3)63− | Pd(N3)2 | AgN3 | Cd(N3)2 | In | Sn | Sb | Te | IN3 | Xe(N3)2 | ||
| CsN3 | Ba(N3)2 | Hf | Ta | W | Re | Os | Ir(N3)63− | Pt(N3)62− | Au(N3)4− | Hg2(N3)2, Hg(N3)2 |
TlN3 | Pb(N3)2 | Bi(N3)3 |
Po | At | Rn | |||
| Fr | Ra(N3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La | Ce(N3)3, Ce(N3)4 |
Pr | Nd | Pm | Sm | Eu | Gd(N3)3 | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
| Ac | Th | Pa | UO2(N3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
 |  |
