Chemistry:Plutonium oxyiodide
From HandWiki
| Names | |
|---|---|
| Other names
Plutonium oxide iodide
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| PuOI | |
| Molar mass | 387 g/mol |
| Appearance | bright green crystals |
| Density | 8.46 g/cm3[1] |
| insoluble | |
| Structure | |
| tetragonal | |
| P4/nmm | |
| Related compounds | |
Other anions
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Plutonium oxyfluoride Plutonium oxychloride Plutonium oxybromide |
Other cations
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Lanthanum oxyiodide Neodymium oxyiodide Californium(III) oxyiodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Plutonium oxyiodide or plutonium oxide iodide is an inorganic compound of plutonium, oxygen, and iodine with the chemical formula PuOI.[2][3]
Synthesis
Plutonium oxyiodide is produced in a reaction of plutonium dioxide with hydrogen iodide:[4]
- PuO
2 + ½H
2 + HI → PuOI + H
2O
- PuO
It can also be made by passing hydrogen iodide through heated plutonium(IV) oxide:[5]
- 2PuO
2 + 4HI → 2PuOI + 2H
2O + I
2
- 2PuO
Physical properties
Plutonium oxyiodide forms bright green crystals of the tetragonal crystal system, space group P4/nmm.[6]
References
- ↑ Satya, Prakash (2013) (in en). Advanced Chemistry of Rare Elements. S. Chand Publishing. p. 690. ISBN 978-81-219-4254-6. https://books.google.com/books?id=WB_4DwAAQBAJ&dq=Plutonium+oxyiodide+PuOI&pg=PA690. Retrieved 14 July 2025.
- ↑ Morss, L. R.; Edelstein, Norman M.; Fuger, Jean (31 December 2007) (in en). The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5). Springer Science & Business Media. p. 1101. ISBN 978-1-4020-3598-2. https://books.google.com/books?id=KyHyM0ObXrAC&dq=Plutonium+oxyiodide+PuOI&pg=PA1101. Retrieved 14 July 2025.
- ↑ Alburger, D. E.; Perlman, I.; Rasmussen, J. O.; Hyde, Earl K.; Seaborg, Glenn T.; Bishop, George R.; Wilson, Richard; Devons, S. et al. (6 December 2012) (in en). Kernreaktionen III / Nuclear Reactions III. Springer Science & Business Media. p. 247. ISBN 978-3-642-45878-1. https://books.google.com/books?id=FqT1CAAAQBAJ&dq=Plutonium+oxyiodide+PuOI&pg=PA247.
- ↑ (in de) Long-range Charge Transfer in DNA. Springer. 1951. p. 500. ISBN 978-3-540-65301-1. https://books.google.com/books?id=Mv81AQAAIAAJ&q=Plutonium+oxybromide+PuOBr. Retrieved 13 July 2025.
- ↑ (in en) Abstracts of Declassified Documents. U. S. Atomic Energy Commission Technical Information Division, Oak Ridge Directed Operations. 1947. p. 747. https://books.google.com/books?id=L7s57GR7nj8C&dq=Plutonium+oxyiodide+PuOI&pg=PA747. Retrieved 14 July 2025.
- ↑ Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 154. https://books.google.com/books?id=5lVCBwmZsLYC&dq=Plutonium+oxyiodide+PuOI&pg=RA4-PA156. Retrieved 14 July 2025.
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