Chemistry:Stannocene
From HandWiki
Stannocene is an organometallic compound with the formula Sn(C
5H
5)
2. It appears yellow-brown, and melts around 105 °C.[1]
Chemically, stannocene is a metallocene that can be produced efficiently from cyclopentadienyl sodium and tin(II) chloride.[2] Unlike in ferrocene the two cyclopentadienyl rings are not parallel.[3]
Stannocene reacts with strong Lewis acids to give the cyclopentadienyltin(II) cation, SnC5H+5.[4]
References
- ↑ Fischer, E. O.; Grubert, H. (1956). "Di-cyclopentadienyl-zinn". Zeitung Für Naturforschung B 11 (7): 423–424. doi:10.1515/znb-1956-0714. (Links go to multiple-article compendium.)
- ↑ Janiak, Christpher (2010), "Stannocene as cyclopentadienyl transfer agent in transmetallation reactions with lanthanide metals for the synthesis of tris(cyclopentadienyl)lanthanides", Zeitschrift für anorganische und allgemeine Chemie 636 (13–14): 2387–2390, doi:10.1002/zaac.201000239, Bibcode: 2010ZAACh.636.2387J, https://hal.archives-ouvertes.fr/hal-00569390/document
- ↑ Smith, P. J. (2012). Chemistry of Tin. Springer Science & Business Media. ISBN 9789401149389. https://books.google.com/books?id=LTTyCAAAQBAJ.
- ↑ Schleep, Mario; Hettich, Clarissa; Velázquez Rojas, Jennifer; Kratzert, Daniel; Ludwig, Thilo; Lieberth, Katharina; Krossing, Ingo (2017-03-06). "The Parent Cyclopentadienyltin Cation, Its Toluene Adduct, and the Quadruple‐Decker [Sn 3 Cp 4 2+"] (in en). Angewandte Chemie International Edition 56 (11): 2880–2884. doi:10.1002/anie.201611351. ISSN 1433-7851. https://onlinelibrary.wiley.com/doi/10.1002/anie.201611351.
Template:Cyclopentadienide complexes
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