Chemistry:Tetrakis(trimethylsilyl)methane
From HandWiki
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| Preferred IUPAC name
trimethyl[tris(trimethylsilyl)methyl]silane | |
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C13H36Si4 | |
| Molar mass | 304.771 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Tetrakis(trimethylsilyl)methane (TTMSM) is an organic compound with formula C13H36Si4, consisting of four trimethylsilyl (Si(CH3)3) groups bonded to a central carbon atom. It is extremely sterically crowded but unlike with the all-carbon equivalent tetra-tert-butylmethane which is only known as a theoretical compound, the longer silicon-carbon bonds allow this compound to be synthesised.[1][2][3][4]
See also
- Neopentane
- Tetraethylmethane
- Tetravinylmethane
- Tetraethynylmethane
- Tetracyclopropylmethane
- Tetraphenylmethane
- Methanetetracarboxylate
- Tetramethoxymethane
- Tetrafluoromethane
- Tetrachloromethane
- Tetrabromomethane
- Tetraiodomethane
- Tetraazidomethane
- Tetracyanomethane
- Tetranitromethane
References
- ↑ "Molecular movements and phase transitions in solids. Tetrakis(trimethylsilyl)methane.". Journal of Physical Chemistry 76 (26): 4037–4039. December 1972. doi:10.1021/j100670a028.
- ↑ "The molecular structure of tetrakis (trimethylsilyl) methane studied by gas-phase electron diffraction and molecular mechanics.". Journal of Molecular Structure 176 (1–2): 81–77. May 1988. doi:10.1016/0022-2860(88)80233-3. Bibcode: 1988JMoSt.176...81B.
- ↑ "Solid state dynamic properties of tetrakis (trimethylsilyl) methane: high-resolution solid state 13C and 29Si NMR investigations.". Journal of Solid State Chemistry 110 (2): 314–320. June 1994. doi:10.1006/jssc.1994.1174. Bibcode: 1994JSSCh.110..314A.
- ↑ "Order-disorder phenomena determined by high-resolution powder diffraction: the structures of tetrakis(trimethylsilyl)methane C". Acta Crystallographica Section B: Structural Science 55 (Pt 6): 1014–1029. December 1999. doi:10.1107/s0108768199006126. PMID 10927444.
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