Chemistry:Tistarite

From HandWiki
Short description: Titanium oxide mineral
Tistarite
General
CategoryOxide minerals
Formula
(repeating unit)
Ti2O3
Strunz classification4.CB.05
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space groupR3c
Identification
References[1]

Tistarite is an exceedingly rare mineral with the formula Ti2O3, thus being the natural analogue of titanium(III) oxide.[3][1] In terms of chemistry it is the titanium-analogue of hematite, corundum, eskolaite, and karelianite. Other minerals with the general formula A2O3 are arsenolite, avicennite, claudetite, bismite, bixbyite, kangite, sphaerobismoite, yttriaite-(Y) and valentinite. Tistarite and grossmanite – both found in the famous Allende meteorite (so is kangite) – are the only currently known minerals with trivalent titanium. Titanium in minerals is almost exclusively tetravalent.[1][4][5] The only known terrestrial occurrence of tistarite was found during minerals exploration by Shefa Yamim Ltd. in the upper mantle beneath Mount Carmel, Israel.[6][7]

References

  1. 1.0 1.1 1.2 Mindat, Tistarite, http://www.mindat.org/min-38695.html
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  3. Ma, C., and Rossmann, G.R., 2009: Tistarite, Ti2O3, a new refractory mineral from the Allende meteorite. American Mineralogist 94(5–6), 841–844
  4. Mindat, Kangite, http://www.mindat.org/min-42879.html
  5. Mindat, Yttriaite-(Y), http://www.mindat.org/min-40471.html
  6. W.L. Griffin; S.E.M. Gain; D.T. Adams; J-X. Huang; M. Saunders; V. Toledo; N.J. pearson; S.Y. O'Reilly (2016), "First terrestrial occurrence of tistarite (Ti2O3): Ultra-low oxygen fugacity in the upper mantle beneath Mount Carmel, Israel", Geology (Geological Society of America) 44 (10): 815–818, 2016-08-17, doi:10.1130/G37910.1, Bibcode2016Geo....44..815G, http://www.shefayamim.com/ufksa7390/Geology-2016-Griffin-G37910_1.pdf, retrieved 2016-09-12 
  7. "Australian university confirms Israeli rare mineral discovery". 2016-02-21. http://www.jwire.com.au/60546-2/.