Chemistry:Tlapallite
| Tlapallite | |
|---|---|
 Tlapallite on matrix from Bambollita mine (La Oriental), Moctezuma, Municipio de Moctezuma, Sonora, Mexico. Picture width: 29 mm | |
| General | |
| Category | Tellurate minerals |
| Formula (repeating unit) | (Ca,Pb) 3CaCu 6[Te4+ 3Te6+O 12] 2(Te4+O 3) 2(SO 4) 2 · 3H2O |
| Strunz classification | 4.JL.25 |
| Dana classification | 34.8.2.1 |
| Crystal system | Monoclinic P3 2 1 |
| Unit cell | a = 11.97 Å , b = 9.11 Å c = 15.66 Å; Z = 4 |
| Identification | |
| Color | Green |
| Crystal habit | Thin crusts or botryoidal aggregates |
| Cleavage | None |
| Mohs scale hardness | 3 |
| |re|er}} | Vitreous, Waxy |
| Streak | Pale green |
| Diaphaneity | Translucent |
| Specific gravity | 5.38 (measured) 5.05–5.465 (calculated) |
| Optical properties | Biaxial (−) |
| Refractive index | nα = 1.815 – 1.915 nβ = 1.960 – 2.115 nγ = 1.960 – 2.115 |
| Birefringence | δ = 0.1450–0.2000 |
| Pleochroism | Moderate, different shades of green |
| 2V angle | 0 |
| Ultraviolet fluorescence | None |
| Fusibility | Fuses readily |
| Diagnostic features | Thin green paint-like crusts |
| Solubility | Soluble in cold HCl Slightly soluble in HNO3 unless heated |
| References | [1][2][3][4] |
Tlapallite is a rare and complex tellurate mineral with the chemical formula (Ca,Pb)
3CaCu
6[Te4+
3Te6+O
12]
2(Te4+O
3)
2(SO
4)
2 · 3H2O. It has a Moh's hardness of 3 and it is green in colour. It was named after the Nahua word "Tlalpalli", which translates to paint, referring to the paint-like habit of the mineral.[2] Its formula and crystal structure were redefined in 2019, showing it contained a mixed-valence phyllotellurate layer [Te4+
3Te6+O
12]12−.[3]
Occurrence
It was discovered in 1972 the Bambollita mine (La Oriental), Moctezuma, Municipio de Moctezuma, Sonora, Mexico, a mine known for its tellurium deposits, and it was approved by the IMA in 1977. Here, it is found as thin paint-like crusts on rock fractures and next to thin veins running through rhyolite. It is often found as a thin film on quartz, sericite, calcite or baryte, but it also forms botryoidal aggregates. It is often found alone, but may be associated with other minerals, especially carlfriesite.[4] It has also been found in the emerald mine in Tombstone District, Cochise County, Arizona in the United States .[2][5][6]
The habit of the mineral suggests it precipitates from rapidly drying acid solutions. It seems to form in the transitory phase when other tellurium minerals, like tlalocite, cesbronite, xocomecatlite, quetzalcoatlite, teineite and carlfriesite, start to break down.[4]
See also
References
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ 2.0 2.1 "Tlapallite: Tlapallite mineral information and data.". http://www.mindat.org/min-3983.html.
- ↑ Missen, Owen P.; Kampf, Anthony R.; Mills, Stuart J.; Housley, Robert M.; Spratt, John; Welch, Mark D.; Coolbaugh, Mark F.; Marty, Joe et al. (2019). The crystal structures of the mixed-valence tellurium oxysalts tlapallite., (Ca,Pb)
3CaCu
6[Te4+
3Te6+O
12]
2(Te4+O
3)
2(SO
4)
2·
3H
2O, and carlfriesite, CaTe4+
2Te6+O
8Missen, Owen P.; Kampf, Anthony R.; Mills, Stuart J.; Housley, Robert M.; Spratt, John; Welch, Mark D.; Coolbaugh, Mark F.; Marty, Joe et al. (2019). "The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb)3CaCu6[Te4+3Te6+O12]2(Te4+O3)2(SO4)2·3H2O, and carlfriesite, CaTe4+2Te6+O8" (in en). Mineralogical Magazine 83 (4): 539–549. doi:10.1180/mgm.2019.9. ISSN 0026-461X. Bibcode: 2019MinM...83..539M. https://www.cambridge.org/core/journals/mineralogical-magazine/article/abs/crystal-structures-of-the-mixedvalence-tellurium-oxysalts-tlapallite-capb3cacu6te43te6o122te4o32so423h2o-and-carlfriesite-cate42te6o8/52763FBB654B9FD2C7AC19D0F3DDC833. - ↑ 4.0 4.1 S.A. Williams and Marjorie Duggan (June 1978). "Tlapallite, a new mineral from Moctezuma, Sonora, Mexico". Mineralogical Magazine 42 (322): 183–186. doi:10.1180/minmag.1978.042.322.03. Bibcode: 1978MinM...42..183W. http://www.minersoc.org/pages/Archive-MM/Volume_42/42-322-183.pdf.
- ↑ Barthelmy, Dave. "Tlapallite Mineral Data". http://www.webmineral.com/data/Tlapallite.shtml#.V9o0Gyh97tQ.
- ↑ "Handbook of Mineralogy". http://www.handbookofmineralogy.org/pdfs/tlapallite.pdf.
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