Chemistry:Vinyldiphenylphosphine
From HandWiki
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| Preferred IUPAC name
Ethenyldi(phenyl)phosphane | |
| Other names
Diphenylvinylphosphine
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3D model (JSmol)
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| Properties | |
| C14H13P | |
| Molar mass | 212.232 g·mol−1 |
| Appearance | colorless solid |
| Melting point | 70.5–71.5 °C (158.9–160.7 °F; 343.6–344.6 K) |
| Boiling point | 104 °C (219 °F; 377 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Vinyldiphenylphosphine is the organophosphorus compound with the formula (C6H5)2PCH=CH2. This colorless, air-sensitive solid is used as a precursor to ligands used in coordination chemistry and homogeneous catalysis.[1] It is prepared by treating chlorodiphenylphosphine with vinyl Grignard reagents.[2]
References
- ↑ King, R. Bruce (1972). "Poly(tertiary Phosphines) and Their Metal Complexes". Accounts of Chemical Research 5 (5): 177–185. doi:10.1021/ar50053a003.
- ↑ Rabinowitz, Robert; Pellon, Joseph (1961). "Phosphorus-containing monomers. I. Synthesis of Vinyl Phosphines, Oxides, Sulfides, and Phosphonium Compounds". Journal of Organic Chemistry 26 (11): 4623–6. doi:10.1021/jo01069a101.
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