Chemistry:Rubicline

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Rubicline
Rubicline.jpg
General
CategoryFeldspar group
Formula
(repeating unit)
(Rb, K)[AlSi3O8]
Strunz classification9.FA.30
Crystal systemTriclinic
Crystal classPinacoidal (1)
(same H-M symbol)
Space groupP1
Identification
Formula mass313.11 g/mol
ColorColorless
Cleavage{001}
|re|er}}Vitreous
DiaphaneityTransparent
Density2.8 g/cm3
Optical propertiesbiaxial
Refractive indexnα = 1.520 nβ = 1.524 nγ = 1.527
Birefringenceδ = 0.007
DispersionStrong
Other characteristicsRadioactive
References[1][2]

Rubicline, also referred to as Rb-microcline, is the rubidium analogue of microcline, an important tectosilicate mineral. Its chemical formula is (Rb, K)[AlSi3O8] with an ideal composition of RbAlSi3O8. Chemical analysis by electron microprobe indicated the average weight of the crystal is 56.66% SiO2, 16.95% Al2O3, and 23.77% Rb2O,[4] along with trace amounts of caesium oxide (Cs2O) and iron(III) oxide (Fe2O3).[5]

Rubicline was first discovered in 1998 in Elba, Italy, by a team from the University of Manitoba. It was the first mineral to have been discovered with rubidium as an essential constituent.[5] It has also been found in Mozambique[6] and the Kola Peninsula in Russia .[7] Rubicline occurs as small, abundant, rounded grains found within veins of rubidian microcline. Pure rubicline with an ideal potassium-free composition has never been found in nature.[4] Rubicline was synthesized in 2001 by placing powdered albite in a solvent of RbCl. This mixture was then placed in a silver tube containing H2O, heated to 400 °C and pressurized to 60 MPa.[4]

Unlike microcline, which can be yellow, red, or green, rubicline is colorless. It is also transparent, brittle,[5] and has a vitreous luster.[8] Rubicline has been classified as both triclinic and monoclinic.[4][8] The crystal does not show twinning. Other minerals in this group include adularia, anorthoclase, buddingtonite, celsian, hyalophane, microcline, monalbite, orthoclase, and sanidine.[8]

Like all rubidium compounds, rubicline is mildly radioactive. Activity and dose rate of various amounts of rubicline are listed in the table below.[1]

Specimen weight/size Calculated
activity (Bq)
Calculated
activity (Ci)
Estimated
activity GR(api)
Estimated
exposure (mRem)/hr*
1000 g / 8.79 cm 183,355 4.96×10−6 8,449.31 2.78
100 g / 4.08 cm 18,336 4.96×10−7 844.93 0.28
10 g / 1.89 cm 1,834 4.96×10−8 84.49 0.03
1 g / 8.79 mm 183 4.96×10−9 8.45 0.00
0.1 g / 4.08 mm 18 4.96×10−10 0.84 0.00
0.01 g / 1.89 mm 2 4.96×10−11 0.08 0.00
0.001 g / 0.88 mm 0 4.96×10−12 0.01 0.00
  • If held in hand for one hour.
  • Government estimate of average annual exposure (360 mRem)
  • Max permissible adult dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
  • Lethal exposure 400,000 to 500,000 mRem

References

  1. 1.0 1.1 Rubicline at Webminerals
  2. Rubicline at Mindat
  3. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  4. 4.0 4.1 4.2 4.3 Kyono, A.; Kimata, M. (August 2001). "Refinement of the crystal structure of a synthetic non-stoichiometric Rb-feldspar". Mineralogical Magazine 65 (4): 523–531. doi:10.1180/002646101750377542. Bibcode2001MinM...65..523K. http://rruff.info/uploads/MM65_523.pdf. 
  5. 5.0 5.1 5.2 Teertstra, David K. (December 2008). "Rubicline, a new feldspar from San Piero in Campo, Elba, Italy". American Mineralogist 83 (11–12): 1335–1339. doi:10.2138/am-1998-11-1223. http://ammin.geoscienceworld.org/cgi/content/abstract/83/11-12_Part_1/1335. 
  6. Teertstra, D. K.; Cerny, P.; Hawthorne, F. C. (1999). "Subsolidus rubidium-dominant feldspar from the Morrua pegmatite, Mozambique: paragenesis and composition". Mineralogical Magazine 63 (3): 313–320. doi:10.1180/002646199548538. ISSN 0026-461X. Bibcode1999MinM...63..313T. 
  7. "Rubicline R070044". RRUFF. http://rruff.info/rubicline/names/asc/. Retrieved 15 February 2010. 
  8. 8.0 8.1 8.2 "Rubicline". Mindat.org. 2010. http://www.mindat.org/min-7276.html. Retrieved 15 February 2010.