Chemistry:Sunflower oil
Sunflower oil is the non-volatile oil pressed from the seeds of the sunflower (Helianthus annuus). Sunflower oil is commonly used in food as a frying oil, and in cosmetic formulations as an emollient.
Sunflower oil is primarily composed of linoleic acid, a polyunsaturated fat, and oleic acid, a monounsaturated fat. Through selective breeding and manufacturing processes, oils of differing proportions of the fatty acids are produced.[1] The expressed oil has a neutral taste profile.[2] The oil contains a large amount of vitamin E.[2]
As of 2023, Ukraine was the world's largest producer of sunflower oil. The Russian invasion of Ukraine that began in 2022 caused global prices of sunflower oil to increase by as much as 58% in a single month in 2022.[3][4]
Composition
Sunflower oil is mainly a triglyceride.[5] The British Pharmacopoeia lists the following profile:[6]
- Palmitic acid (saturated): 5%
- Stearic acid (saturated): 6%
- Oleic acid (monounsaturated omega-9): 30%
- Linoleic acid (polyunsaturated omega-6): 59%
Four types of sunflower oils with differing concentrations of fatty acids are produced through plant breeding and industrial processing: high-linoleic, high-oleic, mid-oleic, and high-stearic combined with high-oleic.[1][2]
- High-linoleic, 69% linoleic acid
- High-oleic, 82% oleic acid
- Mid-oleic, 65% oleic acid
- High-stearic with high-oleic, 18% stearic acid and 72% oleic acid[2]
| Sunflower oil production – 2019 | |
|---|---|
| Country | (millions of tonnes) |
 Ukraine |
5.84 |
 Russia |
5.42 |
 Argentina |
1.41 |
 Turkey |
1.10 |
 Hungary |
0.69 |
 Romania |
0.53 |
 France |
0.53 |
 Bulgaria |
0.52 |
 Spain |
0.49 |
 Kazakhstan |
0.32 |
| World | 20.29 |
| Source: FAOSTAT of the United Nations [7] | |
Genome
A 2017 genome analysis provided a basis for development of hybrid sunflowers to increase oil production.[8] Analysis of the sunflower genome duplication – starting about 29 million years ago – revealed two major breeding traits: flowering time and oil metabolism, which can be cultivated to improve commercialization of sunflower oil.[9][10]
In further analysis of the sunflower genome to reveal plant metabolism producing its oil, phytosterols and other phytochemicals, such as polyphenols, squalene, and terpenoids, were identified.[8][11]
Production
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In 2018, world production of sunflower oil was 18 million tonnes, led by Ukraine and Russia , which together account for 53% of the world total.[7]
In 2022, there is a global shortage of sunflower oil due to the 2022 Russian invasion of Ukraine, which has led to an over 50% drop in the availability of sunflower oil. Due to the shortages, many brands are reforming their recipes by switching to rapeseed oil to allow the production of their products to continue.
Nutrition
| Nutritional value per 100 g (3.5 oz) | |
|---|---|
| Energy | 3,699 kJ (884 kcal) |
0 g | |
100 g | |
| Saturated | 9.748 g |
| Monounsaturated | 83.594 g |
| Polyunsaturated | 3.798 g |
0 g | |
| Vitamins | Quantity %DV† |
| Vitamin E | 274% 41.08 mg |
| Vitamin K | 5% 5.4 μg |
| |
| †Percentages are roughly approximated using US recommendations for adults. Source: USDA Nutrient Database | |
| Nutritional value per 100 g (3.5 oz) | |
|---|---|
| Energy | 3,699 kJ (884 kcal) |
0 g | |
100 g | |
| Saturated | 10.3 g |
| Monounsaturated | 19.5 g |
| Polyunsaturated | 65.7 g |
0 g | |
| Vitamins | Quantity %DV† |
| Vitamin E | 274% 41.08 mg |
| Vitamin K | 5% 5.4 μg |
| |
| †Percentages are roughly approximated using US recommendations for adults. Source: USDA Nutrient Database | |
| Nutritional value per 100 g (3.5 oz) | |
|---|---|
| Energy | 3,699 kJ (884 kcal) |
0 g | |
100 g | |
| Saturated | 9.009 g |
| Monounsaturated | 57.344 g |
| Polyunsaturated | 28.962 g |
0 g | |
| Vitamins | Quantity %DV† |
| Vitamin E | 274% 41.08 mg |
| Vitamin K | 5% 5.4 μg |
| |
| †Percentages are roughly approximated using US recommendations for adults. Source: USDA Nutrient Database | |
Several varieties of sunflower oil seeds have been developed by standard plant breeding methods, mainly to vary the amounts of oleic acid and linoleic acid which, respectively, are the predominant monounsaturated and polyunsaturated fats in sunflower oil.[12] Sunflower oil is a rich source of vitamin E (tables).
Physical properties
Sunflower oil is liquid at room temperature. The refined oil is clear and slightly amber-colored with a slightly fatty odour.
| Smoke point (refined) | 232 °C | 450 °F[13] |
| Smoke point (unrefined) | 107 °C | 225 °F[13] |
| Density (25 °C) | 918.8 kg/m3[14] | |
| Refractive index (25 °C) | ≈1.4735[14] | |
| Saponification value | 188-194 | |
| Iodine value | 120-145 | |
| Unsaponifiable matter | 1.5-2.0% | |
| Viscosity (25 °C), unrefined | 0.04914
kg/(m*s)[15] |
Preparation and storage
Because sunflower oil is primarily composed of less-stable polyunsaturated and monounsaturated fatty acids, it can be particularly susceptible to degradation by heat, air, and light, which trigger and accelerate oxidation. Keeping sunflower oil at low temperatures during manufacture and storage can help minimize rancidity and nutrient loss—as can storage in bottles that are made of either darkly-colored glass, or, plastic that has been treated with an ultraviolet light protectant.[citation needed]
Methods of extraction
Sunflower oil can be extracted using chemical solvents (e.g., hexane),[16] or expeller pressing[17] (i.e., squeezed directly from sunflower seeds by crushing them).[18] "Cold-pressing" (or expeller pressing) sunflower seeds under low-temperature conditions is a method that does not use chemical solvents to derive sunflower seed oil.[citation needed]
Refined versus unrefined
Refining sunflower oil through solvent extraction, de-gumming, neutralization, and bleaching can make it more stable and suitable for high-temperature cooking, but doing so will also remove some of the oil's nutrients, flavor, color (resulting in a pale-yellow), free fatty acids, phospholipids, polyphenols, and phytosterols. Also, some of the polyunsaturated fatty acids will be converted into trans fat due to the high temperatures involved in the process.[19][20] Unrefined sunflower oil is less heat-stable (and therefore well-suited to dishes that are raw, or cooked at low temperatures), but it will retain more of its original nutrient content, flavor, and color (light-amber).
Uses
In food preparation
Refined sunflower oil is used for low-to-extremely-high-temperature cooking. As a frying oil, it behaves as a typical vegetable triglyceride. Unrefined sunflower oil is a traditional salad dressing in Eastern European cuisines.[21] Sunflower oil is also an ingredient in sunflower butter.
Methods for cooking snack foods, such as potato chips or French fries, may use sunflower oil.[22][23]
Seed meal
Extraction of sunflower oil leaves behind the crushed seeds, typically referred to as seed meal, which is rich in protein and dietary fiber and used as an animal feed, fertilizer or fuel.[24]
Supplements
Sunflower oil dietary supplements have been marketed for treatment of eczema, but research has shown it is not medically effective.[25]
As fuel
Sunflower oil can be used to run diesel engines when mixed with diesel in the tank. Due to the high levels of unsaturated fats, there is higher viscosity in cold temperatures.[26]
Cosmetics industry
PEG-10 sunflower glycerides, a pale yellow liquid with a "slightly fatty" odor, are the polyethylene glycol derivative of the mono- and diglycerides derived from sunflower seed oil with an average of 10 moles of ethylene oxide.[27] PEG-10 sunflower glycerides are commonly used in cosmetic formulations.
Horticulture
In the European Union sunflower oil can be sprayed onto tomato crops as a fungicide to control powdery mildew from Oidium neolycopersici. For this use, it is classified as a 'basic substance' that can be used on both organic and conventional farms.[28]
Properties
References
- ↑ 1.0 1.1 "Four types of sunflower oil". National Sunflower Association. 2018. https://www.sunflowernsa.com/oil/Four-Types-of-Sunflower-Oil/.
- ↑ 2.0 2.1 2.2 2.3 "Sunflower oil fatty acid profile". National Sunflower Association. 2018. https://www.sunflowernsa.com/uploads/35/sunflower-oil-fact-sheet_062510.pdf.
- ↑ Abby Vesoulis (2022-03-07). "How the Ukraine-Russia Conflict Will Raise the Price of Snack Foods" (in en). Time. https://time.com/6155095/sunflower-oil-russia-ukraine/. Retrieved 2023-11-07.
- ↑ "Sunflower oil prices skyrocket as Ukrainian farmers harvest amid Russian bombings" (in en). NBC News. 2022-05-10. https://www.nbcnews.com/news/world/body-armor-blocked-ports-ukraines-farmers-carry-war-rcna28058.
- ↑ Alfred Thomas (2002). Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a10_173. ISBN 3527306730.
- ↑ British Pharmacopoeia Commission (2005). "Ph Eur monograph 1371". British Pharmacopoeia 2005. Norwich, England: The Stationery Office. ISBN 0-11-322682-9. https://archive.org/details/britishpharmacop00stat.
- ↑ 7.0 7.1 "Sunflower oil production, 2019; Crops/Regions/World list/Production Quantity; unofficial data (pick lists)". UN Food and Agriculture Organization, Corporate Statistical Database (FAOSTAT). 2020. http://www.fao.org/faostat/en/#data/QD.
- ↑ 8.0 8.1 Badouin, H; Gouzy, J; Grassa, C. J et al. (2017). "The sunflower genome provides insights into oil metabolism, flowering and Asterid evolution". Nature 546 (7656): 148–152. doi:10.1038/nature22380. PMID 28538728. Bibcode: 2017Natur.546..148B.
- ↑ "Progress in modification of sunflower oil to expand its industrial value". J Sci Food Agric 97 (7): 1997–2006. 2017. doi:10.1002/jsfa.8214. PMID 28093767.
- ↑ Christov M (2012). "Contribution of interspecific hybridization to sunflower breeding". Helia 35 (57): 37–46. doi:10.2298/hel1257037c. http://www.doiserbia.nb.rs/img/doi/1018-1806/2012/1018-18061257037C.pdf.
- ↑ Alicia Ayerdi Gotor; Larbi Rhazi (2016). "Effects of refining process on sunflower oil minor components: a review". Oilseeds and Fats, Crops and Lipids 23 (2): D207. doi:10.1051/ocl/2016007. https://www.ocl-journal.org/articles/ocl/full_html/2016/02/ocl160007-s/ocl160007-s.html.
- ↑ "Genetic possibilities for altering sunflower oil quality to obtain novel oils". Can J Physiol Pharmacol 86 (4): 215–21. 2008. doi:10.1139/Y08-008. PMID 18418432.
- ↑ 13.0 13.1 Chu, Michael (2004-06-10). "Smoke Points of Various Fats - Kitchen Notes". Cooking For Engineers. http://www.cookingforengineers.com/article/50/Smoke-Points-of-Various-Fats.
- ↑ 14.0 14.1 Irina NITA, Anisoara NEAGU, Sibel GEACAI, Anca DUMITRU and Anca STERPU: "Study of the behavior of some vegetable oils during the thermal treatment," Technology and Chemical Engineering Department, Ovidius University, bd. Mamaia 124, Constanta, 900527, Romania http://www.univ-ovidius.ro/anale-chimie/chemistry/2010-1/full/1_nita.pdf
- ↑ "Temperature dependence of density and viscosity of vegetable oils". Biomass and Bioenergy 42: 164–71. 2012. doi:10.1016/j.biombioe.2012.03.007. http://upcommons.upc.edu/bitstream/handle/2117/16423/temperature_dependence.pdf.
- ↑ "Sunflower Oil Extraction by Solvent Extraction". Goyum Group. https://www.oilexpeller.com/sunflower-seed-solvent-extraction-plant-process/.
- ↑ "Sunflower Oil Extraction by Expeller Pressing". Goyum Group. https://www.oilexpeller.com/sunflower-seed-oil-mill-plant/.
- ↑ Cox, Jeff (April 1979). "The Sunflower Seed Huller and Oil Press". Organic Gardening. Rodale Press. http://journeytoforever.org/biofuel_library/oilpress.html.
- ↑ Kemény, Z.; Recseg, K.; Hénon, G.; Kővári, K.; Zwobada, F. (2001). "Deodorization of vegetable oils: Prediction of trans polyunsaturated fatty acid content". Journal of the American Oil Chemists' Society 78 (9): 973–979. doi:10.1007/s11746-001-0374-0.
- ↑ Liu, W.; Lu, G. H. (2018). "Cis-trans isomerization of unsaturated fatty acids in edible oils to prepare trans fat". Grasas y Aceites 69 (3): 268. doi:10.3989/gya.0225181. https://www.researchgate.net/publication/327256645.
- ↑ Peter Vatrooshkin (2012). Easier Than a Steamed Turnip: Simple and Delicious Meatless Russian Recipes. Plutagora LLC. pp. 21–22, 26–28, 30. ISBN 9781938407017. https://books.google.com/books?id=oYAKx75pAIAC.
- ↑ "How we make Lays Classic potato chips". Frito-Lay North America, Inc.. 2017. http://www.fritolay.com/nutrition/how-we-make-our-snacks/lays-potato-chips.htm.
- ↑ "The best chips you have ever tasted". BBC Food Recipes. 2017. https://www.bbc.co.uk/food/recipes/thebestchipsyouhavee_93121.
- ↑ Lomascolo, A; Uzan-Boukhris, E; Sigoillot, J. C.; Fine, F (2012). "Rapeseed and sunflower meal: A review on biotechnology status and challenges". Applied Microbiology and Biotechnology 95 (5): 1105–14. doi:10.1007/s00253-012-4250-6. PMID 22752367.
- ↑ "Dietary supplements for established atopic eczema". Cochrane Database Syst Rev 2 (2): CD005205. 2012. doi:10.1002/14651858.CD005205.pub3. PMID 22336810.
- ↑ Johnson, JJ. Meyer, RF. Krall, JM. Shroyer, JP. Schlegel, AJ. Falk, JS and Lee, CD. 2005. Agronomic Practices. In High Plains Sunflower Production Handbook. Kansas State University, Manhattan, KS [accessed 2014 October 22].
- ↑ "Material Safety Data Sheet for Florasolvs PEG-10 Sunflower". http://www.essentialingredients.com/PDF/MSDS_FSpeg-10_sunflower.pdf.
- ↑ European Commission. "Finalised in the Standing Committee on Plants, Animals, Food and Feed at its meeting on 7 October 2016 in view of the approval of sunflower oil as basic substance in accordance with Regulation (EC) No 1107/2009 Sunflowerseed oil (sunflower oil) is derived from sunflower seeds (seeds of Helianthus annuus L.)". Archived from the original on 2022-12-23. https://web.archive.org/web/20221223102940/https://mst.dk/media/171102/pt-b-0300-draft-review-report-for-sunflower-oil-2-vdo.pdf.
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