Chemistry:Coesite
| Coesite | |
|---|---|
 | |
| General | |
| Category | Tectosilicate, quartz group |
| Formula (repeating unit) | SiO 2 |
| Strunz classification | 4.DA.35 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H–M symbol) |
| Space group | C2/c |
| Unit cell | a = 7.143 b = 12.383 c = 7.143 [Å] β = 120.00° Z = 16 |
| Identification | |
| Formula mass | 60.0843 g/mol |
| Color | Colorless |
| Crystal habit | Inclusions in UHP metamorphic minerals up to 3 mm in size |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 7.5 |
| |re|er}} | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Density | 2.92 (calculated) |
| Optical properties | Biaxial |
| Refractive index | nx = 1.594 ny = 1.595 nz = 1.599 |
| Birefringence | +0.006 |
| 2V angle | 60–70 |
| References | [1] |
Coesite (/ˈkoʊsaɪt/)[3] is a form (polymorph) of silicon dioxide (SiO2) that is formed when very high pressure (2–3 gigapascals), and moderately high temperature (700 °C, 1,300 °F), are applied to quartz. Coesite was first synthesized by Loring Coes, Jr., a chemist at the Norton Company, in 1953.[4][5]
Occurrences
In 1960, a natural occurrence of coesite was reported by Edward C. T. Chao,[6] in collaboration with Eugene Shoemaker, from Barringer Crater, in Arizona, US, which was evidence that the crater must have been formed by an impact. After this report, the presence of coesite in unmetamorphosed rocks was taken as evidence of a meteorite impact event or of an atomic bomb explosion. It was not expected that coesite would survive in high pressure metamorphic rocks.
In metamorphic rocks, coesite was initially described in eclogite xenoliths from the mantle of the Earth that were carried up by ascending magmas; kimberlite is the most common host of such xenoliths.[7] In metamorphic rocks, coesite is now recognized as one of the best mineral indicators of metamorphism at very high pressures (UHP, or ultrahigh-pressure metamorphism).[8] Such UHP metamorphic rocks record subduction or continental collisions in which crustal rocks are carried to depths of 70 km (43 mi) or more. Coesite is formed at pressures above about 2.5 GPa (25 kbar) and temperature above about 700 °C. This corresponds to a depth of about 70 km in the Earth. It can be preserved as mineral inclusions in other phases because as it partially reverts to quartz, the quartz rim exerts pressure on the core of the grain, preserving the metastable grain as tectonic forces uplift and expose these rock at the surface. As a result, the grains have a characteristic texture of a polycrystalline quartz rim (see infobox figure).
Coesite has been identified in UHP metamorphic rocks around the world, including the western Alps of Italy at Dora Maira,[8] the Ore Mountains of Germany,[9] the Lanterman Range of Antarctica,[10] in the Kokchetav Massif of Kazakhstan,[11] in the Western Gneiss region of Norway,[12] the Dabie-Shan Range in Eastern China,[13][14] the Himalayas of Eastern Pakistan,[15] and in the Appalachian Mountains of Vermont.[16][17]
Crystal structure
Coesite is a tectosilicate with each silicon atom surrounded by four oxygen atoms in a tetrahedron. Each oxygen atom is then bonded to two Si atoms to form a framework. There are two crystallographically distinct Si atoms and five different oxygen positions in the unit cell. Although the unit cell is close to being hexagonal in shape ("a" and "c" are nearly equal and β nearly 120°), it is inherently monoclinic and cannot be hexagonal. The crystal structure of coesite is similar to that of feldspar and consists of four silicon dioxide tetrahedra arranged in Si4O8 and Si8O16 rings. The rings are further arranged into chains. This structure is metastable within the stability field of quartz: coesite will eventually decay back into quartz with a consequent volume increase, although the metamorphic reaction is very slow at the low temperatures of the Earth's surface. The crystal symmetry is monoclinic C2/c, No.15, Pearson symbol mS48.[18]
See also
- Seifertite, forming at higher pressure than stishovite
- Stishovite, a higher-pressure polymorph
References
- ↑ "Coesite". Handbook of Mineralogy. 2 (Silica, Silicates). Chantilly, Virginia: Mineralogical Society of America. ISBN 0962209716. https://handbookofmineralogy.org/pdfs/coesite.pdf. Retrieved December 5, 2011.
- ↑ Warr, L. N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ "coesite". Dictionary.com Unabridged. Random House. https://www.dictionary.com/browse/coesite.
- ↑ Coes, Jr., L. (31 July 1953). "A New Dense Crystalline Silica". Science 118 (3057): 131–132. doi:10.1126/science.118.3057.131. PMID 17835139. Bibcode: 1953Sci...118..131C. The word coesite is pronounced as "Coze-ite", after chemist Loring Coes, Jr.
- ↑ Hazen, Robert M. (22 July 1999). The Diamond Makers. Cambridge University Press. p. 91. ISBN 978-0-521-65474-6. https://books.google.com/books?id=fNJQok6N9_MC&pg=PA91. Retrieved 2012-06-06.
- ↑ Chao, E. C. T.; Shoemaker, E. M.; Madsen, B. M. (1960). "First Natural Occurrence of Coesite". Science 132 (3421): 220–2. doi:10.1126/science.132.3421.220. PMID 17748937. Bibcode: 1960Sci...132..220C.
- ↑ Smyth, Joseph R.; Hatton, C.J. (1977). "A coesite-sanidine grospydite from the Roberts Victor kimberlite". Earth and Planetary Science Letters 34 (2): 284. doi:10.1016/0012-821X(77)90012-7. Bibcode: 1977E&PSL..34..284S.
- ↑ 8.0 8.1 Chopin, Christian (1984). "Coesite and pure pyrope in high-grade blueschists of the Western Alps: a first record and some consequences". Contributions to Mineralogy and Petrology 86 (2): 107–118. doi:10.1007/BF00381838. Bibcode: 1984CoMP...86..107C.
- ↑ Massonne, H.-J. (2001). "First find of coesite in the ultrahigh-pressure metamorphic area of the central Erzgebirge, Germany". European Journal of Mineralogy 13 (3): 565–570. doi:10.1127/0935-1221/2001/0013-0565. Bibcode: 2001EJMin..13..565M.
- ↑ Ghiribelli, B.; Frezzotti, M.L.; Palmeri, R. (2002). "Coesite in eclogites of the Lanterman Range (Antarctica): Evidence from textural and Raman studies". European Journal of Mineralogy 14 (2): 355–360. doi:10.1127/0935-1221/2002/0014-0355. Bibcode: 2002EJMin..14..355G.
- ↑ Korsakov, A.V.; Shatskiy, V. S.; Sobolev N.V. (1998). "Первая находка коэсита в эклогитах Кокчетавского массива (First occurrence of coesite in eclogites from the Kokchetav Massif)". Doklady Earth Sciences 359: 77–81.
- ↑ Smith, D.C. (1984). "Coesite in clinopyroxene in the Caledonides and its implications for geodynamics". Nature 310 (5979): 641–644. doi:10.1038/310641a0. Bibcode: 1984Natur.310..641S.
- ↑ Schertl, H.-P.; Okay, A.I. (1994). "A coesite inclusion in dolomite in Dabie Shan, China: petrological and rheological significance". Eur. J. Mineral. 6 (6): 995–1000. doi:10.1127/ejm/6/6/0995. Bibcode: 1994EJMin...6..995S. http://eurjmin.geoscienceworld.org/content/6/6/995.short.
- ↑ Wang, Xiaomin; Liou, J. G.; Mao, H. K. (1989-12-01). "Coesite-bearing eclogite from the Dabie Mountains in central China". Geology 17 (12): 1085–1088. doi:10.1130/0091-7613(1989)017<1085:CBEFTD>2.3.CO;2. ISSN 0091-7613. Bibcode: 1989Geo....17.1085W. https://doi.org/10.1130/0091-7613(1989)0172.3.CO;2.
- ↑ O'Brien, P.J.; N. Zotov; R. Law; M.A. Khan; M.Q. Jan (2001). "Coesite in Himalayan eclogite and implications for models of India-Asia collision". Geology 29 (5): 435–438. doi:10.1130/0091-7613(2001)029<0435:CIHEAI>2.0.CO;2. Bibcode: 2001Geo....29..435O.
- ↑ Joseph Gonzalez; Suzanne Baldwin; Jay B Thomas; William O Nachlas; Paul G Fitzgerald (2019). "First Discovery of Coesite in the Appalachians: Characterization of Prograde Metamorphism in a Taconic Metapelite". AGU Fall Meeting 2019: V51B–03. Bibcode: 2019AGUFM.V51B..03G. https://agu.confex.com/agu/fm19/meetingapp.cgi/Paper/552005.
- ↑ Joseph Gonzalez; Suzanne Baldwin; Jay B Thomas; William O Nachlas; Paul G Fitzgerald (2020). "Evidence for ultrahigh-pressure metamorphism discovered in the Appalachian orogen". Geology 48 (10): 947–951. doi:10.1130/G47507.1. Bibcode: 2020Geo....48..947G.
- ↑ Levien L.; Prewitt C.T. (1981). "High-pressure crystal structure and compressibility of coesite". American Mineralogist 66: 324–333. http://www.minsocam.org/ammin/AM66/AM66_324.pdf. Retrieved 2009-12-15.
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