Chemistry:Hydrofluoric acid

From HandWiki
Revision as of 04:13, 6 February 2024 by Corlink (talk | contribs) (change)
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)
Short description: Solution of hydrogen fluoride in water
Hydrofluoric acid
Hydrogen-fluoride-3D-vdW.png
Water-3D-vdW.png
Fluoride ion2.svg
Oxonium-ion-3D-vdW.png
Hydrogen fluoride.JPG
Names
IUPAC name
Fluorane[1]
Other names
Fluorhydric acid
Hydronium fluoride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
EC Number
  • 231-634-8
RTECS number
  • MW7875000
UNII
Properties
HF (aq)
Appearance Colorless liquid
Density 1.15 g/mL (for 48% soln.)
Acidity (pKa) 3.17[2]
Hazards[3]
GHS pictograms CorrosiveAcute Toxicity
GHS Signal word DANGER
H280, H300, H310, H314, H330
P260, P262, P264, P270, P271, P280, P284, P301+310, P301+330+331, P302+350, P303+361+353, P304+340, P305+351+338, P310, P320, P321, P322, P330, P361, P363, P403+233, P405, P410+403, P501
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☑Y verify (what is ☑Y☒N ?)
Infobox references
Tracking categories (test):

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

Uses

Production of organofluorine compounds

The principal use of hydrofluoric acid is in organofluorine chemistry. Many organofluorine compounds are prepared using HF as the fluorine source, including Teflon, fluoropolymers, fluorocarbons, and refrigerants such as freon. Many pharmaceuticals contain fluorine.[4]

Production of inorganic fluorides

Most high-volume inorganic fluoride compounds are prepared from hydrofluoric acid. Foremost are Na3AlF6, cryolite, and AlF3, aluminium trifluoride. A molten mixture of these solids serves as a high-temperature solvent for the production of metallic aluminium. Other inorganic fluorides prepared from hydrofluoric acid include sodium fluoride and uranium hexafluoride.[4]

Etchant, cleaner

Wet etching tanks

It is used in the semiconductor industry as a major component of Wright etch and buffered oxide etch, which are used to clean silicon wafers. In a similar manner it is also used to etch glass by treatment with silicon dioxide to form gaseous or water-soluble silicon fluorides. It can also be used to polish and frost glass.[5]

SiO2 + 4 HF → SiF4(g) + 2 H2O
SiO2 + 6 HF → H2SiF6 + 2 H2O

A 5% to 9% hydrofluoric acid gel is also commonly used to etch all ceramic dental restorations to improve bonding.[6] For similar reasons, dilute hydrofluoric acid is a component of household rust stain remover, in car washes in "wheel cleaner" compounds, in ceramic and fabric rust inhibitors, and in water spot removers.[5][7] Because of its ability to dissolve iron oxides as well as silica-based contaminants, hydrofluoric acid is used in pre-commissioning boilers that produce high-pressure steam. Hydrofluoric acid is also useful for dissolving rock samples (usually powdered) prior to analysis. In similar manner, this acid is used in acid macerations to extract organic fossils from silicate rocks. Fossiliferous rock may be immersed directly into the acid, or a cellulose nitrate film may be applied (dissolved in amyl acetate), which adheres to the organic component and allows the rock to be dissolved around it.[8]

Oil refining

In a standard oil refinery process known as alkylation, isobutane is alkylated with low-molecular-weight alkenes (primarily a mixture of propylene and butylene) in the presence of an acid catalyst derived from hydrofluoric acid. The catalyst protonates the alkenes (propylene, butylene) to produce reactive carbocations, which alkylate isobutane. The reaction is carried out at mild temperatures (0 and 30 °C) in a two-phase reaction.

Production

Hydrofluoric acid was first prepared in 1771, by Carl Wilhelm Scheele.[9] It is now mainly produced by treatment of the mineral fluorite, CaF2, with concentrated sulfuric acid at approximately 265 °C.

CaF2 + H2SO4 → 2 HF + CaSO4

The acid is also a by-product of the production of phosphoric acid from apatite and fluoroapatite. Digestion of the mineral with sulfuric acid at elevated temperatures releases a mixture of gases, including hydrogen fluoride, which may be recovered.[4]

Because of its high reactivity toward glass, hydrofluoric acid is stored in fluorinated plastic (often PTFE) containers.[4][5]

Properties

In dilute aqueous solution hydrogen fluoride behaves as a weak acid,[10] Infrared spectroscopy has been used to show that, in solution, dissociation is accompanied by formation of the ion pair H
3O+
·F−.[11] [12]

H
2O + HF ⇌ H
3O+
⋅F− pKa = 3.17

This ion pair has been characterized in the crystalline state at very low temperature.[13] Further association has been characterized both in solution and in the solid state.[citation needed]

HF + F− ⇌ HF−2 log K = 0.6

It is assumed that polymerization occurs as the concentration increases. This assumption is supported by the isolation of a salt of a tetrameric anion H3F−4[14] and by low-temperature X-ray crystallography.[13] The species that are present in concentrated aqueous solutions of hydrogen fluoride have not all been characterized; in addition to HF−2 which is known[11] the formation of other polymeric species, Hn−1F−n, is highly likely.

The Hammett acidity function, H0, for 100% HF was first reported as -10.2,[15] while later compilations show -11, comparable to values near -12 for pure sulfuric acid.[16][17]

Acidity

Unlike other hydrohalic acids, such as hydrochloric acid, hydrogen fluoride is only a weak acid in dilute aqueous solution.[18] This is in part a result of the strength of the hydrogen–fluorine bond, but also of other factors such as the tendency of HF, H2O, and F− anions to form clusters.[19] At high concentrations, HF molecules undergo homoassociation to form polyatomic ions (such as bifluoride, HF−2) and protons, thus greatly increasing the acidity.[20] This leads to protonation of very strong acids like hydrochloric, sulfuric, or nitric when using concentrated hydrofluoric acid solutions.[21] Although hydrofluoric acid is regarded as a weak acid, it is very corrosive, even attacking glass when hydrated.[20]

The acidity of hydrofluoric acid solutions varies with concentration owing to homoassociation, which refers to the effect of F− on HF. Dilute solutions are weakly acidic with an acid ionization constant Ka = 6.6×10−4 (or pKa = 3.18),[10] in contrast to corresponding solutions of the other hydrogen halides, which are strong acids (pKa < 0). However concentrated solutions of hydrogen fluoride are much more strongly acidic than implied by this value, as shown by measurements of the Hammett acidity function H0(or "effective pH"). During self ionization of 100% liquid HF the H0 was first measured as −10.2[15] and later compiled as −11, comparable to values near −12 for sulfuric acid.[16][17]

In thermodynamic terms, HF solutions are highly non-ideal, with the activity of HF increasing much more rapidly than its concentration. The weak acidity in dilute solution is sometimes attributed to the high H—F bond strength, which combines with the high dissolution enthalpy of HF to outweigh the more negative enthalpy of hydration of the fluoride ion.[22] Paul Giguère and Sylvia Turrell[11][12] have shown by infrared spectroscopy that the predominant solute species in dilute solution is the hydrogen-bonded ion pair H
3O+
·F−.[23]

H
2O + HF ⇌ H
3O+
⋅F−

With increasing concentration of HF the concentration of the hydrogen difluoride ion also increases.[11] The reaction

3 HF ⇌ HF−2 + H2F+

is an example of homoconjugation.

Health and safety

A hydrofluoric acid burn of the hand
Main page: Medicine:Hydrofluoric acid burn

In addition to being a highly corrosive liquid, hydrofluoric acid is also a powerful contact poison. Because of the ability of hydrofluoric acid to penetrate tissue, poisoning can occur readily through exposure of skin or eyes, or when inhaled or swallowed. Symptoms of exposure to hydrofluoric acid may not be immediately evident, and this can provide false reassurance to victims, causing them to delay medical treatment.[24] Despite having an irritating odor, HF may reach dangerous levels without an obvious odor.[5] HF interferes with nerve function, meaning that burns may not initially be painful. Accidental exposures can go unnoticed, delaying treatment and increasing the extent and seriousness of the injury.[24] Symptoms of HF exposure include irritation of the eyes, skin, nose, and throat, eye and skin burns, rhinitis, bronchitis, pulmonary edema (fluid buildup in the lungs), and bone damage.[25]

Hydrofluoric burns are treated with a calcium gluconate gel.

In popular culture

In the episodes "Cat's in the Bag..." and "Box Cutter" of the crime drama television series Breaking Bad, Walter White and Jesse Pinkman use hydrofluoric acid to chemically disincorporate bodies of gangsters.[26][27]

HF is also used as one of John "Jigsaw" Kramers traps in Saw VI, as at the end of the movie an acid trap flies from the ceiling and pumps Bobby full of acid.

See also

References

  1. ↑ Favre, Henri A.; Powell, Warren H., eds (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. Cambridge: The Royal Society of Chemistry. p. 131. ISBN 9781849733069. 
  2. ↑ Harris, Daniel C. (2010). Quantitative Chemical Analysis (8th international ed.). New York: W. H. Freeman. pp. AP14. ISBN 978-1429263092. 
  3. ↑ "Hydrofluoric Acid". National Institute of Health. https://pubchem.ncbi.nlm.nih.gov/compound/hydrofluoric_acid. 
  4. ↑ 4.0 4.1 4.2 4.3 Aigueperse, Jean; Mollard, Paul; Devilliers, Didier; Chemla, Marius; Faron, Robert; Romano, René; Cuer, Jean Pierre (2000). "Ullmann's Encyclopedia of Industrial Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a11_307. 
  5. ↑ 5.0 5.1 5.2 5.3 "Hydrogen Fluoride/Hydrofluoric Acid: Systemic Agent". Emergency Response Safety and Health Database. NIOSH - CDC. May 12, 2011. https://www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750030.html. 
  6. ↑ Craig, Robert (2006). Craig's restorative dental materials. St. Louis, Mo: Mosby Elsevier. ISBN 0-323-03606-6. OCLC 68207297. 
  7. ↑ Strachan, John (January 1999). "A deadly rinse: The dangers of hydrofluoric acid". Professional Carwashing & Detailing 23 (1). http://secure.gvmg.com/carwash/articleprint.asp?print=1&IndexID=4230101. 
  8. ↑ Edwards, D. (1982). "Fragmentary non-vascular plant microfossils from the late Silurian of Wales". Botanical Journal of the Linnean Society 84 (3): 223–256. doi:10.1111/j.1095-8339.1982.tb00536.x. 
  9. ↑ Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 921. ISBN 978-0-08-022057-4. https://books.google.com/books?id=OezvAAAAMAAJ&q=0-08-022057-6&dq=0-08-022057-6&source=bl&ots=m4tIRxdwSk&sig=XQTTjw5EN9n5z62JB3d0vaUEn0Y&hl=en&sa=X&ei=UoAWUN7-EM6ziQfyxIDoCQ&ved=0CD8Q6AEwBA. 
  10. ↑ 10.0 10.1 Ralph H. Petrucci; William S. Harwood; Jeffry D. Madura (2007). General chemistry: principles and modern applications. Pearson/Prentice Hall. p. 691. ISBN 978-0-13-149330-8. https://books.google.com/books?id=5z0vAQAAIAAJ. Retrieved 22 August 2011. 
  11. ↑ 11.0 11.1 11.2 11.3 Giguère, Paul A.; Turrell, Sylvia (1980). "The nature of hydrofluoric acid. A spectroscopic study of the proton-transfer complex H3O+...F−". J. Am. Chem. Soc. 102: 5473. doi:10.1021/ja00537a008. 
  12. ↑ 12.0 12.1 Radu Iftimie; Vibin Thomas; Sylvain Plessis; Patrick Marchand; Patrick Ayotte (2008). "Spectral Signatures and Molecular Origin of Acid Dissociation Intermediates". J. Am. Chem. Soc. 130 (18): 5901–7. doi:10.1021/ja077846o. PMID 18386892. 
  13. ↑ 13.0 13.1 Mootz, D. (1981). "Crystallochemical Correlate to the Anomaly of Hydrofluoric Acid.". Angew. Chem. Int. Ed. Engl. 20 (123): 791. doi:10.1002/anie.198107911. 
  14. ↑ Bunič, Tina; Tramšek, Melita; Goreshnik, Evgeny; Žemva, Boris (2006). "Barium trihydrogen tetrafluoride of the composition Ba(H3F4)2: The first example of homoleptic HF metal environment". Solid State Sciences 8 (8): 927–931. doi:10.1016/j.solidstatesciences.2006.02.045. Bibcode: 2006SSSci...8..927B. 
  15. ↑ 15.0 15.1 Hyman, Herbert H.; Kilpatrick, Martin; Katz, Joseph J. (1957). "The Hammett Acidity Function H0 for Hydrofluoric Acid Solutions". Journal of the American Chemical Society (American Chemical Society (ACS)) 79 (14): 3668–3671. doi:10.1021/ja01571a016. ISSN 0002-7863. 
  16. ↑ 16.0 16.1 Jolly, William L. (1984). Modern Inorganic Chemistry. McGraw-Hill. p. 203. ISBN 0-07-032768-8. OCLC 22861992. 
  17. ↑ 17.0 17.1 Cotton, F. A.; Wilkinson, G. (1988). Advanced Inorganic Chemistry (5th ed.). New York: Wiley. p. 109. ISBN 0-471-84997-9. OCLC 16580057. 
  18. ↑ Wiberg, Egon; Wiberg, Nils; Holleman, Arnold Frederick (2001). Inorganic Chemistry. San Diego: Academic Press. p. 425. ISBN 978-0-12-352651-9. 
  19. ↑ Clark, Jim (2002). "The acidity of the hydrogen halides". http://www.chemguide.co.uk/inorganic/group7/acidityhx.html. 
  20. ↑ 20.0 20.1 Chambers, C.; Holliday, A. K. (1975). Modern inorganic chemistry (An intermediate text). The Butterworth Group. pp. 328–329. http://files.rushim.ru/books/neorganika/Chambers.pdf. 
  21. ↑ Hannan, Henry J. (2010). Course in chemistry for IIT-JEE 2011. Tata McGraw Hill Education Private Limited. pp. 15–22. ISBN 9780070703360. https://books.google.com/books?id=wNYMUeCcaSEC&pg=SA15-PA22. 
  22. ↑ C. E. Housecroft and A. G. Sharpe "Inorganic Chemistry" (Pearson Prentice Hall, 2nd ed. 2005), p. 170.
  23. ↑ Cotton & Wilkinson (1988), p. 104
  24. ↑ 24.0 24.1 "Ionophoretic delivery of calcium for experimental hydrofluoric acid burns". Crit. Care Med. 29 (8): 1575–8. 2001. doi:10.1097/00003246-200108000-00013. PMID 11505130. 
  25. ↑ "NIOSH Pocket Guide to Chemical Hazards – Hydrogen fluoride". https://www.cdc.gov/niosh/npg/npgd0334.html. 
  26. ↑ "How much of the science in Breaking Bad is real?". 16 August 2013. https://www.bbc.com/news/magazine-23710654. 
  27. ↑ Hare, Jonathan (1 May 2011). "Breaking Bad II – acid bath disposal of bodies". Royal Society of Chemistry. https://edu.rsc.org/analysis/breaking-bad-ii-acid-bath-disposal-of-bodies/3007374.article. 

External links



Retrieved from "https://handwiki.org/wiki/index.php?title=Chemistry:Hydrofluoric_acid&oldid=3336022"