Chemistry:Carbokentbrooksite
| Carbokentbrooksite | |
|---|---|
| General | |
| Category | Silicate mineral, Cyclosilicate |
| Formula (repeating unit) | (Na,□)12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (original form) |
| Strunz classification | 9.CO.10 (10 ed) 8/E.25-32 (8 ed) |
| Dana classification | 64.1.2.3 |
| Crystal system | Trigonal |
| Crystal class | Ditrigonal pyramidal (3m) (same H-M symbol) |
| Space group | R3m |
| Unit cell | a = 14.24, c = 30.04 [Å]; Z = 3 |
| Identification | |
| Color | Yellow, yellow-orange |
| Crystal habit | rhombohedra (cores of zoned crystals) |
| Cleavage | None |
| Fracture | Conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 5 |
| |re|er}} | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Density | 3.14 (measured) |
| Optical properties | Uniaxial (−) |
| Refractive index | nω = 1.65, nε = 1.64 (approximated) |
| Pleochroism | None |
| Ultraviolet fluorescence | No |
| References | [1][2] |
Carbokentbrooksite is a very rare mineral of the eudialyte group,[1] with formula (Na,□)12(Na,Ce)3Ca6Mn3Zr3NbSiO(Si9O27)2(Si3O9)2(OH)3(CO3).H2O.[2] The original formula was extended to show the presence of cyclic silicate groups and silicon at the M4 site, according to the nomenclature of eudialyte group.[4] Carbokenbrooksite characterizes in being carbonate-rich (the other eudialyte-group species with essential carbonate are zirsilite-(Ce), golyshevite, and mogovidite). It is also sodium rich, being sodium equivalent of zirsilite-(Ce),[1] with which it is intimately associated.[2]
Occurrence and association
Carbokentbrooksite and zirsilite-(Ce) are found as replacements of grains and crystals of eudialyte.[1] They occur in pegmatites of Darai-Pioz alkaline massif, Tajikistan – a locality known for many rare minerals.[5] The minerals are associated with aegirine, ekanite, microcline, polylithionite, quartz, stillwellite-(Ce) (silicates), pyrochlore-group mineral, fluorite, calcite, and galena.[2]
Notes on chemistry
Beside the elements given in the formula, carbokentbrooksite contains admixtures of lanthanum, strontium, neodymium, iron, yttrium, titanium, potassium, chlorine, and praseodymium. Carbokentbrooksite and zirsilite-(Ce) are chemically similar.[2]
Notes on structure
Carbokentbrooksite is isostructural with kentbrooksite.[2]
References
- ↑ 1.0 1.1 1.2 1.3 Mindat, Carbokentbrooksite, http://www.mindat.org/min-25674.html
- ↑ 2.0 2.1 2.2 2.3 2.4 2.5 Khomyakov, A.P., Dusmatov, V.D., Ferraris, G., Gula, A., Ivaldi, G., and Nechelyustov, G.N., 2003: Zirsilite-(Ce), (Na,[])12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)•H2O, and carbokentbrooksite (Na,[])12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)•H2O – two new eudialyte-group minerals from the Dara-i-Pioz alkaline massif, Tajikistan. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 132(5), 40–51 (in Russian, with English abstract); in: Jambor, J.I, and Roberts, A.C., 2004: New mineral names. American Mineralogist 89(11–12), 1826–1834
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794
- ↑ "Darai-Pioz Glacier (Dara-i-Pioz; Dara-Pioz), Alai Range (Alayskiy), Tien Shan Mtn, Region of Republican Subordination, Tajikistan - Mindat.org". http://www.mindat.org/loc-3241.html. Retrieved 2016-03-11.
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