Chemistry:Stillwellite-(Ce)

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Stillwellite-(Ce)
Stillwellite-(Ce)-33971.jpg
1.3 cm stillwellite-(Ce) crystal in matrix
General
CategorySilicate mineral
Formula
(repeating unit)
(Ce,La,Ca)BSiO
5
Strunz classification9.AJ.25
Dana classification54.02.03.02
Crystal systemTrigonal
Crystal classPyramidal (3)
H-M symbol: (3)
Space groupP31
Identification
ColorRed-brown to pale pink
Crystal habitFlat rhombohedral crystals, massive
TwinningObserved on {100}
CleavageImperfect
FractureConchoidal
Mohs scale hardness6.5
|re|er}}Resinous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity4.57–4.6
Optical propertiesUniaxial (+)
Refractive indexnω = 1.765, nε = 1.780
Birefringenceδ = 0.015
Other characteristicsRadioactive.svg Radioactive
References[1][2][3]

Stillwellite-(Ce) is a rare-earth boro-silicate mineral with chemical formula (Ce,La,Ca)BSiO
5
.

Location

It occurs as a metasomatic replacement of metamorphosed limestones in the Mary Kathleen mine, Australia and in alkalic pegmatites associated with syenite in an alkaline massif in Tajikistan.[1] It occurs in association with allanite, garnet, uraninite in the Australian deposit; with calcite, monazite, bastnasite, thorite, uranothorite and thorianite in the Desmont mine, Wilberforce, Ontario, Canada ; and with pyrochlore, tienshanite, sogdianite, thorite, caesium kupletskite, reedmergnerite, steacyite, pectolite and quartz in the Tajikistan deposit.[1] It has also been reported from Mont Saint-Hilaire, Quebec, Canada and from Mineville, Essex County, New York. Other occurrences include the Inagli massif, Yakutia, Russia , around Langesundsfjord, Norway , in the Ilimaussaq intrusive complex, southern Greenland and the Vico volcano, Lazio, Italy.[1]

Discovery

It was first described in 1955 for an occurrence at the type locality is the Mary Kathleen Mine, 55 km (34 mi) east of Mount Isa, Queensland, Australia . It was named for Austrian mineralogist Frank Leslie Stillwell (1888–1963).[2][3]

Chemistry Breakdown

(1) (2) (1) (2)

SiO2

22.40 22.06 La2O3 27.95 19.12
UO2 0.22 Ce2O3 33.15 30.82
ThO2 5.41 Pr2O3 1.82
B2O3 12.23 [13.46] Nd2O3 5.36
Al2O3 0.42 Sm2O3 0.34
Y2O3 0.74 0.28 Fe2O3 0.18

References

  1. 1.0 1.1 1.2 1.3 http://rruff.geo.arizona.edu/doclib/hom/stillwellitece.pdf Handbook of Mineralogy
  2. 2.0 2.1 http://webmineral.com/data/Stillwellite-(Ce).shtml Webmineral data
  3. 3.0 3.1 http://www.mindat.org/min-3788.html Mindat.org
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W.