Chemistry:Dumortierite

From HandWiki
Dumortierite
Dumortiérite.JPG
Dumortierite from Tuléar Province (Toliara), Madagascar
General
CategoryNesosilicate
Formula
(repeating unit)
Al7BO3(SiO4)3O3 or Al6.5-7BO3(SiO4)3(O,OH)3[1]
Strunz classification9.AJ.10
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPmcn (no. 62)
Unit cella = 11.77 Å, b = 20.21 Å
c = 4.71 Å; Z = 4
Identification
ColorBlue, greenish-blue, violet-blue, pale blue, red
Crystal habitAs fibrous or columnar crystals; coarsely crystalline to intimate parallel aggregates of needles; massive
TwinningCommon on {110}, may produce trillings
CleavageDistinct on {100}, poor on {110}; parting on {001}
FractureFibrous
Mohs scale hardness7–8.5
|re|er}}Vitreous to dull
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.3–3.4
Optical propertiesBiaxial (−)
Refractive indexnα = 1.659 – 1.678 nβ = 1.684 – 1.691 nγ = 1.686 – 1.692
Birefringenceδ = 0.027
PleochroismStrong; X = deep blue or violet; Y = yellow to red-violet or nearly colorless; Z = colorless or very pale blue
2V angleMeasured: 20° to 52°, Calculated: 30°
Dispersionr > v; strong
References[1][2][3]

Dumortierite is a fibrous variably colored aluminium boro-silicate mineral, Al7BO3(SiO4)3O3. Dumortierite crystallizes in the orthorhombic system typically forming fibrous aggregates of slender prismatic crystals. The crystals are vitreous and vary in color from brown, blue, and green to more rare violet and pink. Substitution of iron and other tri-valent elements for aluminium result in the color variations. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.4. Crystals show pleochroism from red to blue to violet. Dumortierite quartz is blue colored quartz containing abundant dumortierite inclusions.

Dumortierite was first described in 1881 for an occurrence in Chaponost, in the Rhône-Alps of France and named for the French paleontologist Eugène Dumortier (1803–1873).[5] It typically occurs in high temperature aluminium rich regional metamorphic rocks, those resulting from contact metamorphism and also in boron rich pegmatites. The most extensive investigation on dumortierite was done on samples from the high grade metamorphic Gfohl unit in Austria by Fuchs et al. (2005).

It is used in the manufacture of high grade porcelain. It is sometimes mistaken for sodalite and has been used as imitation lapis lazuli.

Sources of Dumortierite include Austria, Brazil , Canada , France , Italy, Madagascar , Namibia, Nevada, Norway , Peru, Poland , Russia , Indonesia, and Sri Lanka.

See also

References

  1. 1.0 1.1 http://webmineral.com/data/Dumortierite.shtml Webmineral data
  2. http://rruff.geo.arizona.edu/doclib/hom/dumortierite.pdf Handbook of Mineralogy
  3. http://www.mindat.org/min-1329.html Mindat.org
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. "Dumortierite". Encyclopædia Britannica. 8 (11th ed.). 1911. p. 667.