Chemistry:Isopropyl formate
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Short description: Organic chemical compound
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| Properties | |
| C4H8O2 | |
| Molar mass | 88.106 g·mol−1 |
| Density | 0.88 |
| Boiling point | 68 °C (154 °F; 341 K) |
Refractive index (nD)
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1.37 |
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| GHS Signal word | Danger |
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| PP210Script error: No such module "Preview warning".Category:GHS errors, PP233Script error: No such module "Preview warning".Category:GHS errors, PP240Script error: No such module "Preview warning".Category:GHS errors, PP241Script error: No such module "Preview warning".Category:GHS errors, PP242Script error: No such module "Preview warning".Category:GHS errors, PP243Script error: No such module "Preview warning".Category:GHS errors, PP261Script error: No such module "Preview warning".Category:GHS errors, PP264+P265Script error: No such module "Preview warning".Category:GHS errors, PP271Script error: No such module "Preview warning".Category:GHS errors, PP280Script error: No such module "Preview warning".Category:GHS errors, PP303+P361+P353Script error: No such module "Preview warning".Category:GHS errors, PP304+P340Script error: No such module "Preview warning".Category:GHS errors, PP305+P351+P338Script error: No such module "Preview warning".Category:GHS errors, PP319Script error: No such module "Preview warning".Category:GHS errors, PP337+P317Script error: No such module "Preview warning".Category:GHS errors, PP370+P378Script error: No such module "Preview warning".Category:GHS errors, PP403+P233Script error: No such module "Preview warning".Category:GHS errors, PP403+P235Script error: No such module "Preview warning".Category:GHS errors, PP405Script error: No such module "Preview warning".Category:GHS errors, PP501Script error: No such module "Preview warning".Category:GHS errors | |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Isopropyl formate is an organic chemical compound. Like many other aliphatic carboxylic acid esters, it has an odor. It is described as pleasant and fruit-like, similar to plums or pears.[1] In fact, many fruits contain isopropyl formate, but their smell is determined by a combination of esters, not by isopropyl formate alone.[2]
Production
Isopropyl formate can be produced by a typical Fischer Esterification, of isopropyl alcohol and formic acid, catalyzed by sulfuric acid[3]:
- HCOOH + (CH3)2CHOH → C4H8O2 + H2O
Use
Isopropyl formate can be used as a flavour.[1]
Fate
When released in the atmosphere, isopropyl formate is mostly degraded by reaction with hydroxyl radicals and secondarily by chlorine atoms.[4]
References
- ↑ 1.0 1.1 Burdock, George A. (29 July 2014) (in en). Encyclopedia of Food & Color Additives. CRC Press. ISBN 978-1-4987-1108-1. https://books.google.com/books?id=z-ZhDwAAQBAJ&pg=PA1489.
- ↑ "CAS 625-55-8: Isopropyl formate | CymitQuimica" (in en). https://cymitquimica.com/cas/625-55-8/.
- ↑ PubChem. "Isopropyl formate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/12257.
- ↑ Zhang, Y.J.; Liang, P.; Jiang, Z.H.; Cazaunau, M.; Daële, V.; Mu, Y.J.; Mellouki, A. (May 2014). "Reactions of OH and Cl with isopropyl formate, isobutyl formate, n-propyl isobutyrate and isopropyl isobutyrate". Chemical Physics Letters 602: 68–74. doi:10.1016/j.cplett.2014.04.020. Bibcode: 2014CPL...602...68Z. https://insu.hal.science/insu-00989673.
