Chemistry:Isopropyl mercaptan

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Isopropyl mercaptan
Propane-2-thiol 200.svg
Names
Other names
  • 2-Propanethiol
  • Propane-2-thiol
  • 2-propanthiol
  • 2-propane thiol
  • Isopropyl mercaptan
  • Isopropanethiol
  • Isopropylthiol
  • 2-Mercaptopropane
  • 2-Propylmercaptan
  • 1-Methylethanethiol
Identifiers
3D model (JSmol)
605260
ChEBI
ChEMBL
ChemSpider
EC Number
  • 200-861-4
KEGG
UNII
UN number 2402
Properties
C3H8S
Molar mass 76.16 g·mol−1
Density 0.8143
Melting point −130.7 °C (−203.3 °F; 142.5 K)
Boiling point 52.5 °C (126.5 °F; 325.6 K)
4835 g/L
Vapor pressure 277.3 mm Hg
Hazards
GHS pictograms GHS02: FlammableGHS06: ToxicGHS07: Harmful
GHS Signal word Danger
H225, H302, H315, H319, H331
P210, P233, P240, P241, P242, P243, P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P270, P271, P280, P301+317Script error: No such module "Preview warning".Category:GHS errors, P302+352, P303+361+353, P304+340, P305+351+338, P316Script error: No such module "Preview warning".Category:GHS errors, P321, P330, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P370+378, P403+233
Related compounds
Related compounds
Propanethiol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Isopropyl mercaptan is an organic compound with the formula C3H8S. It has the CAS Registry Number 75-33-2.[2] It is REACH registered with the European number of 200-861-4.[3] It is a water-white liquid with an extremely pungent odor resembling skunk spray or bad eggs. The odor means one use is as an odorizer.[4] Despite this, it has Food and Drug Administration sanction as a food additive to add flavor.[5] Another use is as a rubber additive.[6]

Analysis and detection

The usual method of analysis and detection is by gas chromatography.[7][8]

See also

References

  1. "2-Propanethiol" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/6364#section=Safety-and-Hazards. 
  2. "CAS Common Chemistry". https://commonchemistry.cas.org/detail?cas_rn=75-33-2. 
  3. PubChem. "2-Propanethiol" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/6364. 
  4. Michanowicz, Drew R.; Leventhal, Olivia M.; Domen, Jeremy K.; Williams, Samuel R.; Lebel, Eric D.; Hill, Lee Ann L.; Buonocore, Jonathan J.; Nordgaard, Curtis L. et al. (2023-07-25). "Natural gas odorants: A scoping review of health effects" (in en). Current Environmental Health Reports 10 (3): 337–352. doi:10.1007/s40572-023-00403-w. ISSN 2196-5412. PMID 37491689. 
  5. PubChem. "2-Propanethiol Flavor profile" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/6364. 
  6. Li, Zhiwei; An, Dong; He, Rizheng; Sun, Zhijian; Li, Jiaxiong; Zhang, Zhiyi; Liu, Yaqing; Wong, Chingping (April 2023). "The design of crosslinks in different vulcanized systems to improve crack growth resistance for carbon black/graphene oxide/natural rubber composites" (in en). Advanced Composites and Hybrid Materials 6 (2). doi:10.1007/s42114-023-00662-z. ISSN 2522-0128. https://link.springer.com/10.1007/s42114-023-00662-z. 
  7. Tangerman, Albert (1986-01-01). "Determination of volatile sulphur compounds in air at the parts per trillion level by tenax trapping and gas chromatography". Journal of Chromatography A 366: 205–216. doi:10.1016/S0021-9673(01)93468-5. ISSN 0021-9673. PMID 3782318. https://www.sciencedirect.com/science/article/pii/S0021967301934685. 
  8. Wang, Xinguang; Le, Minh; Stuetz, Richard (January 2022). "Calibration methods for VSCs measured on AS-TD-GC-SCD" (in en). Environmental Monitoring and Assessment 194 (1): 25. doi:10.1007/s10661-021-09690-y. ISSN 0167-6369. PMID 34905118. https://link.springer.com/10.1007/s10661-021-09690-y.