Chemistry:Monolayer-protected cluster molecules

Short description: Nanoclusters

Monolayer protected clusters (MPCs) are one type of nanoparticles or clusters of atoms. A single MPC contains three main parts: metallic core, protective ligand layer and metal-ligand interface between, each defined by their distinctive chemical and structural environments. The main part of a MPC is a metallic core, which can consist of a single metal or it can be a mixture of metals. Bare metal particles tend to be reactive. They usually react with environment or with other particles making larger structures. Ligand layer is used to protect them, so that the particle size is preserved. Ligands are usually some organic molecules and they are bound to metallic core via some linking atoms such as sulfur or phosphorus forming thiol and phosphine ligands. However, there are alkynyl and carbene protected MPCs, where carbon is directly bound to metal atoms. Ligand layer can consist of a single type of ligands, like in the case of thiolate-protected gold clusters, or it can contain several different molecules. Even though the ligand layer is usually used to passivate a nanoparticle, it is not a passive part of the MPCs. For example, ligands can be functionalized to work in specific applications such as binding to surfaces or acting as a carrier for other molecules. Ligand layer also contributes to the total electronic structure of the particle, which furthermore affects the superatomic nature of the particle.

[Au₂₅(SCH₂Ph)₁₈]⁻ presented here is a thiolate-protected gold cluster and a classic example of the MPC, structure of which is determined by single crystal X-ray diffraction. (white: H, grey: C, dull yellow :S, yellow: Au). Top left: full structure; middle : gold core and Au-S protecting units, bottom right: Au₁₃-core.

In order to fully understand how MPCs work, one has to solve their atomic structures. One of the most common ways is to use X-ray crystallography. There are a large amount of these structures found but they are scattered over different sources. This article is designed to be a list of known structures of MPCs focusing on experimentally determined ones. MPCs are divided to tables according to their cores. Within the tables they are sorted according to the amount of metal atoms from smallest to largest. If there several clusters with similar core sizes, earlier published is listed first. The last table contains some structures which are partially determined experimentally and partially predicted by theoretical calculations. Every table lists the chemical formula of the MPC, the full reference to the publication and a their shortened DOI code with a link to the publication. There are three main ways to access the structure information. The first one is to go to the webpage of the original publication and see if there is supplementary information file containing the data. The second approach is to use the listed DOI and search the structure from the Cambridge Structural Database (CSD) or Crystallography Open Database (COD). There one can easily download the structure, if authors have submitted their crystallographic data. Some crystal structures are published in Protein Data Bank (PDB), in which case corresponding accession code is listed after the DOI. The third option is for the situations, where two first ones don't work and the data is really needed. One can check who is the corresponding author of the publication and ask politely for the data.

Gold

Table of the crystal structures of gold MPCs.

Formula	References
[Au3C27N2H36]1+	Robilotto, Thomas J.; Bacsa, John; Gray, Thomas G.; Sadighi, Joseph P. (2012). "Synthesis of a Trigold Monocation: An Isolobal Analogue of [H3]+". Angewandte Chemie International Edition 51 (48): 12077–12080. doi:10.1002/anie.201206712. PMID 23038641.
{[(tBu)3PAu]4}2+	Zeller, Edgar; Beruda, Holger; Schmidbaur, Hubert (1993). "Tetrahedral gold cluster [Au4]2+: Crystal structure of {[(tert-Bu)3PAu]4}2+(BF4-)2.2CHCl3". Inorganic Chemistry 32 (15): 3203–3204. doi:10.1021/ic00067a002.
[(Au(P(mesityl)3)4]2+	Yang, Yi; Sharp, Paul R. (1994). "New Gold Clusters [Au8L6](BF4)2 and [(AuL)4](BF4)2 (L = P(mesityl)3)". Journal of the American Chemical Society 116 (15): 6983–6984. doi:10.1021/ja00094a082. Bibcode: 1994JAChS.116.6983Y.
[Au6(PPh3)6]2+	Briant, Clive E.; Hall, Kevin P.; Mingos, D. Michael P.; Wheeler, Allison C. (1986). "Synthesis and structural characterisation of hexakis(triphenyl phosphine)hexagold(2+) nitrate, [Au6(PPh3)6][NO3]2, and related clusters with edgesharing bitetrahedral geometries". Journal of the Chemical Society, Dalton Transactions (3): 687. doi:10.1039/DT9860000687.
[Au6P(PhCH3)3]2+	Bellon, Pierluigi; Manassero, Mario; Sansoni, Mirella (1973). "An octahedral gold cluster: Crystal and molecular structure of hexakis[tris-(p-tolyl)phosphine]-octahedro-hexagold bis(tetraphenylborate)". Journal of the Chemical Society, Dalton Transactions (22): 2423. doi:10.1039/DT9730002423.
[Au6(dppp)4]2+	Van Der Velden, J. W. A.; Bour, J. J.; Steggerda, J. J.; Beurskens, P. T.; Roseboom, M.; Noordik, J. H. (1982). "Gold clusters. Tetrakis[1,3-bis(diphenylphosphino)propane]hexagold dinitrate: Preparation, x-ray analysis, and gold-197 Moessbauer and phosphorus-31{proton} NMR spectra". Inorganic Chemistry 21 (12): 4321–4324. doi:10.1021/ic00142a041.
[(ImiPr2·Au)6(μ6-C)]2+	Salorinne, Kirsi; Man, Renee W. Y.; Lummis, Paul A.; Hazer, Maryam Sabooni Asre; Malola, Sami; Yim, Jacky C.-H.; Veinot, Alex J.; Zhou, Wenxia et al. (2020). "Synthesis and properties of an Au6 cluster supported by a mixed N-heterocyclic carbene–thiolate ligand". Chemical Communications 56 (45): 6102–6105. doi:10.1039/D0CC01482F. PMID 32355943.
[Au7(PPh3)7]1+	Van Der Velden, J. W. A.; Beurskens, P. T.; Bour, J. J.; Bosman, W. P.; Noordik, J. H.; Kolenbrander, M.; Buskes, J. A. K. M. (1984). "Intermediates in the formation of gold clusters. Preparation and x-ray analysis of [Au7(PPh3)7]+ and synthesis and characterization of [Au8(PPh3)6I]PF6". Inorganic Chemistry 23 (2): 146–151. doi:10.1021/ic00170a007.
[Au7(dppp)4]3+	Shichibu, Yukatsu; Zhang, Mingzhe; Kamei, Yutaro; Konishi, Katsuaki (2014). "[Au7]3+: A Missing Link in the Four-Electron Gold Cluster Family". Journal of the American Chemical Society 136 (37): 12892–12895. doi:10.1021/ja508005x. PMID 25184446. Bibcode: 2014JAChS.13612892S.
[Au8(PPh3)8]2+	Manassero, Mario; Naldini, Luciana; Sansoni, Mirella (1979). "A new class of gold cluster compounds. Synthesis and X-ray structure of the octakis(triphenylphosphinegold) dializarinsulphonate, [Au8(PPh3)8](aliz)2". Journal of the Chemical Society, Chemical Communications (9): 385. doi:10.1039/C39790000385.
[Au8(PPh3)7]2+	Van Der Velden, Jan W. A.; Bour, Jan J.; Bosman, Wil P.; Noordik, Jan H. (1981). "Synthesis and X-ray crystal structure determination of the cationic gold cluster compound [Au8(PPh3)7](NO3)2". Journal of the Chemical Society, Chemical Communications (23): 1218. doi:10.1039/C39810001218.
[Au8(PPh3)7(SnCl3)]+	Demidowicz, Zenon; Johnston, Roy L.; Machell, Jonathan C.; Mingos, D. Michael P.; Williams, Ian D. (1988). "Synthesis and structural characterisation of a novel high-nuclearity gold–tin cluster compound, [Au8(PPH3)7(SNCL3)]2[SNCL6]". J. Chem. Soc., Dalton Trans. (7): 1751–1756. doi:10.1039/DT9880001751.
[Au8L6]1+	Yang, Yi; Sharp, Paul R. (1994). "New Gold Clusters [Au8L6](BF4)2 and [(AuL)4](BF4)2 (L = P(mesityl)3)". Journal of the American Chemical Society 116 (15): 6983–6984. doi:10.1021/ja00094a082. Bibcode: 1994JAChS.116.6983Y.
[Au8(dppp)4]2+	Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2011). "Generation of Small Gold Clusters with Unique Geometries through Cluster-to-Cluster Transformations: Octanuclear Clusters with Edge-sharing Gold Tetrahedron Motifs". Angewandte Chemie International Edition 50 (32): 7442–7445. doi:10.1002/anie.201102901. PMID 21688379.
[Au8(dppp)4Cl2]2+	Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2011). "Generation of Small Gold Clusters with Unique Geometries through Cluster-to-Cluster Transformations: Octanuclear Clusters with Edge-sharing Gold Tetrahedron Motifs". Angewandte Chemie International Edition 50 (32): 7442–7445. doi:10.1002/anie.201102901. PMID 21688379.
[Au8(dppp)4(CCPh)2]2+	Kobayashi, Naoki; Kamei, Yutaro; Shichibu, Yukatsu; Konishi, Katsuaki (2013). "Protonation-Induced Chromism of Pyridylethynyl-Appended [core+ exo ]-Type Au8 Clusters. Resonance-Coupled Electronic Perturbation through π-Conjugated Group". Journal of the American Chemical Society 135 (43): 16078–16081. doi:10.1021/ja4099092. PMID 24127776. Bibcode: 2013JAChS.13516078K.
[Au8(dppm)4S2]2+	Zhang, Shan-Shan; Feng, Lei; Senanayake, Ravithree D.; Aikens, Christine M.; Wang, Xing-Po; Zhao, Quan-Qin; Tung, Chen-Ho; Sun, Di (2018). "Diphosphine-protected ultrasmall gold nanoclusters: Opened icosahedral Au13and heart-shaped Au8clusters". Chemical Science 9 (5): 1251–1258. doi:10.1039/C7SC03566G. PMID 29675171.
[Au8(dppp)4(C4Ph)2]2+	Iwasaki, Mitsuhiro; Shichibu, Yukatsu; Konishi, Katsuaki (2019). "Unusual Attractive Au–π Interactions in Small Diacetylene-Modified Gold Clusters". Angewandte Chemie International Edition 58 (8): 2443–2447. doi:10.1002/anie.201814359. PMID 30614159.
[Au8(dppp)4(C2(CH2)2CH3)2]2+	Iwasaki, Mitsuhiro; Shichibu, Yukatsu; Konishi, Katsuaki (2019). "Unusual Attractive Au–π Interactions in Small Diacetylene-Modified Gold Clusters". Angewandte Chemie International Edition 58 (8): 2443–2447. doi:10.1002/anie.201814359. PMID 30614159.
Au8(DPPF)4	Li, Shuo Hao; Liu, Xu; Hu, Weigang; Chen, Mingyang; Zhu, Yan (2020). "An Au8 Cluster Fortified by Four Ferrocenes". The Journal of Physical Chemistry A 124 (29): 6061–6067. doi:10.1021/acs.jpca.0c03366. PMID 32639744. Bibcode: 2020JPCA..124.6061L.
[Au9{P(p-C6H4Me)3}8]3+	Bellon, P. L.; Cariati, F.; Manassero, M.; Naldini, L.; Sansoni, M. (1971). "Novel gold clusters. Preparation, properties, and X-ray structure determination of salts of octakis(triarylphosphine)enneagold, [Au9L8]X3". Journal of the Chemical Society D: Chemical Communications (22): 1423. doi:10.1039/C29710001423.
[Au9{P(p-C6H4OMe)3}8]3+	Hall, Kevin P.; Theoblad, Brain R. C.; Gilmour, David I.; Mingos, D. Michael P.; Welch, Alan J. (1982). "Synthesis and structural characterization of [Au9{P(p-C6H4OMe)3}8](BF4)3; a cluster with a centred crown of gold atoms". Journal of the Chemical Society, Chemical Communications (10): 528. doi:10.1039/C39820000528.
[Au9{P(p-C6H4OMe)3}8]3+	Briant, Clive E.; Hall, Kevin P.; Mingos, D. Michael P. (1984). "Structural characterisation of two crystalline modifications of [Au9{P(C6H4OMe-p)3}8](NO3)3: The first example of skeletal isomerism in metal cluster chemistry". Journal of the Chemical Society, Chemical Communications (5): 290. doi:10.1039/C39840000290.
[Au9(PPh3)8]3+	Schulz-Dobrick, Martin; Jansen, Martin (2006). "Supramolecular Intercluster Compounds Consisting of Gold Clusters and Keggin Anions". European Journal of Inorganic Chemistry 2006 (22): 4498–4502. doi:10.1002/ejic.200600790.
[Au9(PPh3)8]3+	Schulz-Dobrick, Martin; Jansen, Martin (2007). "Structure-Directing Effects in the Supramolecular Intercluster Compound [Au9(PPH3)8]2[V10O28H3]2: Long-Range versus Short-Range Bonding Interactions". Inorganic Chemistry 46 (11): 4380–4382. doi:10.1021/ic700434x. PMID 17477525.
[Au9(PPh3)8]3+	Wen, Fei; Englert, Ulli; Gutrath, Benjamin; Simon, Ulrich (2008). "Crystal Structure, Electrochemical and Optical Properties of [Au9(PPH3)8](NO3)3". European Journal of Inorganic Chemistry 2008: 106–111. doi:10.1002/ejic.200700534.
[Au10Cl3(PCy2Ph)6]+	Briant, Clive E.; Hall, Kevin P.; Wheeler, Alison C.; Mingos, D. Michael P. (1984). "Structural characterisation of [Au10Cl3(PCy2Ph)6](NO3)(Cy = cyclohexyl) and the development of a structural principle for high nuclearity gold clusters". Journal of the Chemical Society, Chemical Communications (4): 248. doi:10.1039/C39840000248.
[Au10(μ-cis-dppee)4(μ3-S)4]2+	Yao, Liao-Yuan; Yam, Vivian Wing-Wah (2015). "Photoinduced Isomerization-Driven Structural Transformation Between Decanuclear and Octadecanuclear Gold(I) Sulfido Clusters". Journal of the American Chemical Society 137 (10): 3506–3509. doi:10.1021/jacs.5b01676. PMID 25741572. Bibcode: 2015JAChS.137.3506Y.
[Au10(bisNHC)4Br2]2+	Man, Renee W. Y.; Yi, Hong; Malola, Sami; Takano, Shinjiro; Tsukuda, Tatsuya; Häkkinen, Hannu; Nambo, Masakazu; Crudden, Cathleen M. (2022). "Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape". Journal of the American Chemical Society 144 (5): 2056–2061. doi:10.1021/jacs.1c11857. PMID 35100506. Bibcode: 2022JAChS.144.2056M.
[Au10(MesCH2Bimy)6Br3]+	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L. et al. (2022). "NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters". JACS Au 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMID 35557749.
Au11(S-4-NC5-H4)3(PPh3)7	Nunokawa, Keiko; Onaka, Satoru; Ito, Mitsuhiro; Horibe, Makoto; Yonezawa, Tetsu; Nishihara, Hiroshi; Ozeki, Tomoji; Chiba, Hirokazu et al. (2006). "Synthesis, single crystal X-ray analysis, and TEM for a single-sized Au11 cluster stabilized by SR ligands: The interface between molecules and particles". Journal of Organometallic Chemistry 691 (4): 638–642. doi:10.1016/j.jorganchem.2005.09.043.
[Au11(Ph2P(CH2)2PPh2)6]3+	Shichibu, Yukatsu; Kamei, Yutaro; Konishi, Katsuaki (2012). "Unique [core+two] structure and optical property of a dodeca-ligated undecagold cluster: Critical contribution of the exo gold atoms to the electronic structure". Chemical Communications 48 (61): 7559–7561. doi:10.1039/C2CC30251A. PMID 22430877.
Au11(PPh3)7Cl3	McKenzie, Lallie C.; Zaikova, Tatiana O.; Hutchison, James E. (2014). "Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au11(PPH3)7Cl3 and [Au11(PPH3)8Cl2Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione"]. Journal of the American Chemical Society 136 (38): 13426–13435. doi:10.1021/ja5075689. PMID 25171178. Bibcode: 2014JAChS.13613426M.
[Au11(PPh3)8Cl2]+	McKenzie, Lallie C.; Zaikova, Tatiana O.; Hutchison, James E. (2014). "Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au11(PPH3)7Cl3 and [Au11(PPH3)8Cl2Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione"]. Journal of the American Chemical Society 136 (38): 13426–13435. doi:10.1021/ja5075689. PMID 25171178. Bibcode: 2014JAChS.13613426M.
[Au11(PPh3)7(NHCi-Pr)Cl2]+	Narouz, Mina R.; Osten, Kimberly M.; Unsworth, Phillip J.; Man, Renee W. Y.; Salorinne, Kirsi; Takano, Shinjiro; Tomihara, Ryohei; Kaappa, Sami et al. (2019). "N-heterocyclic carbene-functionalized magic-number gold nanoclusters". Nature Chemistry 11 (5): 419–425. doi:10.1038/s41557-019-0246-5. PMID 30988416. Bibcode: 2019NatCh..11..419N.
[Au12(PPh2)2S4(L2)4]2+	Yu, Wen; Wang, Yingxia; Fuhr, Olaf; Fenske, Dieter; Dehnen, Stefanie (2018). "[Au12(PPH2)2S4(L2)4]2+ (L2 = 3,4-bis(diphenylphosphino)-2,5-bis(trimethylsilyloxy)furan): An Au12 unit protected by modified maleic anhydride phosphine ligands". Dalton Transactions 47 (4): 1032–1035. doi:10.1039/C7DT04263A. PMID 29292447.
[Au13(PMe2Ph)10Cl2]3+	Briant, Clive E.; Theobald, Brian R. C.; White, James W.; Bell, Linda K.; Mingos, D. Michael P.; Welch, Alan J. (1981). "Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction". Journal of the Chemical Society, Chemical Communications (5): 201. doi:10.1039/C39810000201.
[Au13(dppe)5Cl2]3+	Shichibu, Yukatsu; Konishi, Katsuaki (2010). "HCL-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to "Magic-Number" Au13 Clusters". Small 6 (11): 1216–1220. doi:10.1002/smll.200902398. PMID 20486140.
[Au13(dppe)5(CCPh)2]3+	Sugiuchi, Mizuho; Shichibu, Yukatsu; Nakanishi, Takayuki; Hasegawa, Yasuchika; Konishi, Katsuaki (2015). "Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands". Chemical Communications 51 (70): 13519–13522. doi:10.1039/C5CC04312C. PMID 26215256.
[Au13(dppm)6]5+	Zhang, Shan-Shan; Feng, Lei; Senanayake, Ravithree D.; Aikens, Christine M.; Wang, Xing-Po; Zhao, Quan-Qin; Tung, Chen-Ho; Sun, Di (2018). "Diphosphine-protected ultrasmall gold nanoclusters: Opened icosahedral Au13and heart-shaped Au8clusters". Chemical Science 9 (5): 1251–1258. doi:10.1039/C7SC03566G. PMID 29675171.
[Au13(NHCBn)9Cl3]2+	Narouz, Mina R.; Takano, Shinjiro; Lummis, Paul A.; Levchenko, Tetyana I.; Nazemi, Ali; Kaappa, Sami; Malola, Sami; Yousefalizadeh, Goonay et al. (2019). "Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes". Journal of the American Chemical Society 141 (38): 14997–15002. doi:10.1021/jacs.9b07854. PMID 31497943. Bibcode: 2019JAChS.14114997N. http://urn.fi/URN:NBN:fi:jyu-201909174173.
[Au13(NHC-1)6Br6]−	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K. et al. (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au13(NHC-2)5Br2]3+	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K. et al. (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au13(NHC-3)9Cl3]2+	Shen, Hui; Xiang, Sijin; Xu, Zhen; Liu, Chen; Li, Xihua; Sun, Cunfa; Lin, Shuichao; Teo, Boon K. et al. (2020). "Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity". Nano Research 13 (7): 1908–1911. doi:10.1007/s12274-020-2685-0.
[Au13(NHC-4)8(ArC≡C)4]+	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo et al. (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335. Bibcode: 2022JAChS.14410844S.
Au14(PPh3)8(NO3)4	Gutrath, Benjamin S.; Oppel, Iris M.; Presly, Oliver; Beljakov, Igor; Meded, Velimir; Wenzel, Wolfgang; Simon, Ulrich (2013). "[Au14(PPH3)8(NO3)4]: An Example of a New Class of Au(NO3)-Ligated Superatom Complexes". Angewandte Chemie International Edition 52 (12): 3529–3532. doi:10.1002/anie.201208681. PMID 23420716.
[Au16(NHC-1)5(PA)3Br2]3+	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo et al. (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335. Bibcode: 2022JAChS.14410844S.
[Au16(NHC-1)5(PA)2(4-MePhC≡C)Br2]3+	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo et al. (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335. Bibcode: 2022JAChS.14410844S.
[Au17(NHC-1)4(PA)4Br4]+	Shen, Hui; Wu, Qingyuan; Malola, Sami; Han, Ying-Zi; Xu, Zhen; Qin, Ruixuan; Tang, Xiongkai; Chen, Yang-Bo et al. (2022). "N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with Organometallic Motifs for Promoting Catalysis". Journal of the American Chemical Society 144 (24): 10844–10853. doi:10.1021/jacs.2c02669. PMID 35671335. Bibcode: 2022JAChS.14410844S.
[Au18(μ-trans-dppee)6(μ3-S)8]2+	Yao, Liao-Yuan; Yam, Vivian Wing-Wah (2015). "Photoinduced Isomerization-Driven Structural Transformation Between Decanuclear and Octadecanuclear Gold(I) Sulfido Clusters". Journal of the American Chemical Society 137 (10): 3506–3509. doi:10.1021/jacs.5b01676. PMID 25741572. Bibcode: 2015JAChS.137.3506Y.
Au18(SC6H11)14	Das, Anindita; Liu, Chong; Byun, Hee Young; Nobusada, Katsuyuki; Zhao, Shuo; Rosi, Nathaniel; Jin, Rongchao (2015). "Structure Determination of [Au18(SR)14]". Angewandte Chemie International Edition 54 (10): 3140–3144. doi:10.1002/anie.201410161. PMID 25619892.
Au18(SC6H11)14	Chen, Shuang; Wang, Shuxin; Zhong, Juan; Song, Yongbo; Zhang, Jun; Sheng, Hongting; Pei, Yong; Zhu, Manzhou (2015). "The Structure and Optical Properties of the [Au18(SR)14] Nanocluster". Angewandte Chemie International Edition 54 (10): 3145–3149. doi:10.1002/anie.201410295. PMID 25620108.
[Au18S8(dppe)6]2+	Keter, Frankline K.; Guzei, Ilia A.; Nell, Margo; Zyl, Werner E. van; Darkwa, James (2014). "Phosphinogold(I) Dithiocarbamate Complexes: Effect of the Nature of Phosphine Ligand on Anticancer Properties". Inorganic Chemistry 53 (4): 2058–2067. doi:10.1021/ic4025926. PMID 24476103.
[Au18(dppm)6Cl4]4+	Zhang, Shan-Shan; Senanayake, Ravithree D.; Zhao, Quan-Qin; Su, Hai-Feng; Aikens, Christine M.; Wang, Xing-Po; Tung, Chen-Ho; Sun, Di et al. (2019). "[Au18(DPPM)6Cl4]4+: A phosphine-protected gold nanocluster with rich charge states". Dalton Transactions 48 (11): 3635–3640. doi:10.1039/C9DT00042A. PMID 30747941.
[Au19(CCPh)9(Hdppa)3]2+	Wan, Xian-Kai; Tang, Qing; Yuan, Shang-Fu; Jiang, De-en; Wang, Quan-Ming (2015). "Au19 Nanocluster Featuring a V-Shaped Alkynyl–Gold Motif". Journal of the American Chemical Society 137 (2): 652–655. doi:10.1021/ja512133a. PMID 25545109. Bibcode: 2015JAChS.137..652W.
[Au20(PPhpy2)10Cl4]2+	Wan, Xian-Kai; Lin, Zhi-Wei; Wang, Quan-Ming (2012). "Au20 Nanocluster Protected by Hemilabile Phosphines". Journal of the American Chemical Society 134 (36): 14750–14752. doi:10.1021/ja307256b. PMID 22931402. Bibcode: 2012JAChS.13414750W.
Au20(TBBT)16	Zeng, Chenjie; Liu, Chong; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Gold–Thiolate Ring as a Protecting Motif in the Au20(SR)16 Nanocluster and Implications". Journal of the American Chemical Society 136 (34): 11922–11925. doi:10.1021/ja506802n. PMID 25126666. Bibcode: 2014JAChS.13611922Z.
[Au20(PP3)4]4+	Chen, Jing; Zhang, Qian-Fan; Williard, Paul G.; Wang, Lai-Sheng (2014). "Synthesis and Structure Determination of a New Au20 Nanocluster Protected by Tripodal Tetraphosphine Ligands". Inorganic Chemistry 53 (8): 3932–3934. doi:10.1021/ic500562r. PMID 24684605.
Au21(S-tBu)15	Yang, Sha; Chai, Jinsong; Song, Yongbo; Fan, Jiqiang; Chen, Tao; Wang, Shuxin; Yu, Haizhu; Li, Xiaowu et al. (2017). "In Situ Two-Phase Ligand Exchange: A New Method for the Synthesis of Alloy Nanoclusters with Precise Atomic Structures". Journal of the American Chemical Society 139 (16): 5668–5671. doi:10.1021/jacs.7b00668. PMID 28383901. Bibcode: 2017JAChS.139.5668Y.
Au21(S-Adm)15	Chen, Shuang; Xiong, Lin; Wang, Shuxin; Ma, Zhongyun; Jin, Shan; Sheng, Hongting; Pei, Yong; Zhu, Manzhou (2016). "Total Structure Determination of Au21(S-Adm)15 and Geometrical/Electronic Structure Evolution of Thiolated Gold Nanoclusters". Journal of the American Chemical Society 138 (34): 10754–10757. doi:10.1021/jacs.6b06004. PMID 27552520. Bibcode: 2016JAChS.13810754C.
Au22(L8)6	Chen, Jing; Zhang, Qian-Fan; Bonaccorso, Timary A.; Williard, Paul G.; Wang, Lai-Sheng (2014). "Controlling Gold Nanoclusters by Diphospine Ligands". Journal of the American Chemical Society 136 (1): 92–95. doi:10.1021/ja411061e. PMID 24351099. Bibcode: 2014JAChS.136...92C.
Au22(SAdm)16	Li, Yingwei; Cowan, Michael J.; Zhou, Meng; Luo, Tian-Yi; Song, Yongbo; Wang, He; Rosi, Nathaniel L.; Mpourmpakis, Giannis et al. (2020). "Atom-by-Atom Evolution of the Same Ligand-Protected Au21, Au22, Au22Cd1, and Au24 Nanocluster Series". Journal of the American Chemical Society 142 (48): 20426–20433. doi:10.1021/jacs.0c09110. PMID 33170677. Bibcode: 2020JAChS.14220426L.
[Au23(SC6H11)16]−	Das, Anindita; Li, Tao; Nobusada, Katsuyuki; Zeng, Chenjie; Rosi, Nathaniel L.; Jin, Rongchao (2013). "Nonsuperatomic [Au23(SC6H11)16]− Nanocluster Featuring Bipyramidal Au15 Kernel and Trimeric Au3(SR)4 Motif". Journal of the American Chemical Society 135 (49): 18264–18267. doi:10.1021/ja409177s. PMID 24274138.
[Au23(CCPh)9(PPh3)6]2+	Wan, Xian-Kai; Yuan, Shang-Fu; Tang, Qing; Jiang, De-en; Wang, Quan-Ming (2015). "Alkynyl-Protected Au23 Nanocluster: A 12-Electron System". Angewandte Chemie International Edition 54 (20): 5977–5980. doi:10.1002/anie.201500590. PMID 25808199.
Au23(CCBu)15	Guan, Zong-Jie; Hu, Feng; Li, Jiao-Jiao; Wen, Zhao-Rui; Lin, Yu-Mei; Wang, Quan-Ming (2020). "Isomerization in Alkynyl-Protected Gold Nanoclusters". Journal of the American Chemical Society 142 (6): 2995–3001. doi:10.1021/jacs.9b11836. PMID 31958012. Bibcode: 2020JAChS.142.2995G.
[Au23(NHCptol)6(C≡CPh)9]2+	Hirano, Koto; Takano, Shinjiro; Tsukuda, Tatsuya (2021). "Ligand Effects on the Structures of [Au23L6(C≡CPH)9]2+ (L = N-Heterocyclic Carbene vs Phosphine) with Au17 Superatomic Cores". The Journal of Physical Chemistry C 125 (18): 9930–9936. doi:10.1021/acs.jpcc.1c02197.
[Au24(CCPh)14(PPh3)4]2+	Wan, Xian-Kai; Xu, Wen Wu; Yuan, Shang-Fu; Gao, Yi; Zeng, Xiao-Cheng; Wang, Quan-Ming (2015). "A Near-Infrared-Emissive Alkynyl-Protected Au24 Nanocluster". Angewandte Chemie International Edition 54 (33): 9683–9686. doi:10.1002/anie.201503893. PMID 26119538.
Au24(SAdm)16	Crasto, David; Barcaro, Giovanni; Stener, Mauro; Sementa, Luca; Fortunelli, Alessandro; Dass, Amala (2014). "Au24(SAdm)16 Nanomolecules: X-ray Crystal Structure, Theoretical Analysis, Adaptability of Adamantane Ligands to Form Au23(SAdm)16 and Au25(SAdm)16, and Its Relation to Au25(SR)18". Journal of the American Chemical Society 136 (42): 14933–14940. doi:10.1021/ja507738e. PMID 25308728. Bibcode: 2014JAChS.13614933C.
Au24(SCH2Ph-tBu)20	Das, Anindita; Li, Tao; Li, Gao; Nobusada, Katsuyuki; Zeng, Chenjie; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Crystal structure and electronic properties of a thiolate-protected Au24 nanocluster". Nanoscale 6 (12): 6458–6462. doi:10.1039/C4NR01350F. PMID 24817094.
[Au24L6Cl4]2+	Sugiuchi, Mizuho; Shichibu, Yukatsu; Konishi, Katsuaki (2018). "An Inherently Chiral Au24 Framework with Double-Helical Hexagold Strands". Angewandte Chemie International Edition 57 (26): 7855–7859. doi:10.1002/anie.201804087. PMID 29719106.
[Au24(PPh3)10(SC2H4Ph)5Cl2]+	Das, Anindita; Li, Tao; Nobusada, Katsuyuki; Zeng, Qiong; Rosi, Nathaniel L.; Jin, Rongchao (2012). "Total Structure and Optical Properties of a Phosphine/Thiolate-Protected Au24 Nanocluster". Journal of the American Chemical Society 134 (50): 20286–20289. doi:10.1021/ja3101566. PMID 23227995. Bibcode: 2012JAChS.13420286D.
[Au24(NHC)14Cl2H3]3+	Kulkarni, Viveka K.; Khiarak, Behnam Nourmohammadi; Takano, Shinjiro; Malola, Sami; Albright, Emily L.; Levchenko, Tetyana I.; Aloisio, Mark D.; Dinh, Cao-Thang et al. (2022). "N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2". Journal of the American Chemical Society 144 (20): 9000–9006. doi:10.1021/jacs.2c00789. PMID 35549258. Bibcode: 2022JAChS.144.9000K.
[Au25(PPh3)10(SEt)5Cl2]2+	Shichibu, Yukatsu; Konishi, Katsuaki (2010). "HCL-Induced Nuclearity Convergence in Diphosphine-Protected Ultrasmall Gold Clusters: A Novel Synthetic Route to "Magic-Number" Au13 Clusters". Small 6 (11): 1216–1220. doi:10.1002/smll.200902398. PMID 20486140.
[Au25(SC2H4Ph)18]1-	Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J.; Schatz, George C.; Jin, Rongchao (2008). "Correlating the Crystal Structure of a Thiol-Protected Au25 Cluster and Optical Properties". Journal of the American Chemical Society 130 (18): 5883–5885. doi:10.1021/ja801173r. PMID 18407639. Bibcode: 2008JAChS.130.5883Z.
[Au25(SC2H4Ph)18]1-	Heaven, Michael W.; Dass, Amala; White, Peter S.; Holt, Kennedy M.; Murray, Royce W. (2008). "Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]". Journal of the American Chemical Society 130 (12): 3754–3755. doi:10.1021/ja800561b. PMID 18321116. Bibcode: 2008JAChS.130.3754H.
[Au25(SC2H4Ph)18]1-	Zhu, Manzhou; Eckenhoff, William T.; Pintauer, Tomislav; Jin, Rongchao (2008). "Conversion of Anionic [Au25(SCH2CH2Ph)18]− Cluster to Charge Neutral Cluster via Air Oxidation". The Journal of Physical Chemistry C 112 (37): 14221–14224. doi:10.1021/jp805786p.
Au25(SC2H4Ph)18	Zhu, Manzhou; Eckenhoff, William T.; Pintauer, Tomislav; Jin, Rongchao (2008). "Conversion of Anionic [Au25(SCH2CH2Ph)18]− Cluster to Charge Neutral Cluster via Air Oxidation". The Journal of Physical Chemistry C 112 (37): 14221–14224. doi:10.1021/jp805786p.
Au25(SC2H4Ph)18	Antonello, Sabrina; Dainese, Tiziano; Pan, Fangfang; Rissanen, Kari; Maran, Flavio (2017). "Electrocrystallization of Monolayer-Protected Gold Clusters: Opening the Door to Quality, Quantity, and New Structures". Journal of the American Chemical Society 139 (11): 4168–4174. doi:10.1021/jacs.7b00568. PMID 28281762. Bibcode: 2017JAChS.139.4168A.
[Au25(S-nC5H11)18]4	Antonello, Sabrina; Dainese, Tiziano; Pan, Fangfang; Rissanen, Kari; Maran, Flavio (2017). "Electrocrystallization of Monolayer-Protected Gold Clusters: Opening the Door to Quality, Quantity, and New Structures". Journal of the American Chemical Society 139 (11): 4168–4174. doi:10.1021/jacs.7b00568. PMID 28281762. Bibcode: 2017JAChS.139.4168A.
Au25(SC2H4Ph)18	Tofanelli, Marcus A.; Salorinne, Kirsi; Ni, Thomas W.; Malola, Sami; Newell, Brian; Phillips, Billy; Häkkinen, Hannu; Ackerson, Christopher J. (2016). "Jahn–Teller effects in Au25(SR)18". Chemical Science 7 (3): 1882–1890. doi:10.1039/C5SC02134K. PMID 29899911.
[Au25(SC2H4Ph)18]1+	Tofanelli, Marcus A.; Salorinne, Kirsi; Ni, Thomas W.; Malola, Sami; Newell, Brian; Phillips, Billy; Häkkinen, Hannu; Ackerson, Christopher J. (2016). "Jahn–Teller effects in Au25(SR)18". Chemical Science 7 (3): 1882–1890. doi:10.1039/C5SC02134K. PMID 29899911.
Au25(SEt)18	Dainese, Tiziano; Antonello, Sabrina; Gascón, José A.; Pan, Fangfang; Perera, Neranjan V.; Ruzzi, Marco; Venzo, Alfonso; Zoleo, Alfonso et al. (2014). "Au25(SEt)18, a Nearly Naked Thiolate-Protected Au25 Cluster: Structural Analysis by Single Crystal X-ray Crystallography and Electron Nuclear Double Resonance". ACS Nano 8 (4): 3904–3912. doi:10.1021/nn500805n. PMID 24628268.
Au25(SPr)18	Agrachev, Mikhail; Antonello, Sabrina; Dainese, Tiziano; Gascón, José A.; Pan, Fangfang; Rissanen, Kari; Ruzzi, Marco; Venzo, Alfonso et al. (2016). "A magnetic look into the protecting layer of Au25 clusters". Chemical Science 7 (12): 6910–6918. doi:10.1039/C6SC03691K. PMID 28567262.
[Au25(SBu)18]2	De Nardi, Marco; Antonello, Sabrina; Jiang, De-en; Pan, Fangfang; Rissanen, Kari; Ruzzi, Marco; Venzo, Alfonso; Zoleo, Alfonso et al. (2014). "Gold Nanowired: A Linear (Au25) n Polymer from Au25 Molecular Clusters". ACS Nano 8 (8): 8505–8512. doi:10.1021/nn5031143. PMID 25088331.
[Au25(PPh3)10(SePh)5Cl2]1+	Song, Yongbo; Jin, Shan; Kang, Xi; Xiang, Ji; Deng, Huijuan; Yu, Haizhu; Zhu, Manzhou (2016). "How a Single Electron Affects the Properties of the "Non-Superatom" Au25 Nanoclusters". Chemistry of Materials 28 (8): 2609–2617. doi:10.1021/acs.chemmater.5b04655.
[Au25(PPh3)10(SePh)5Cl2]2+	Song, Yongbo; Jin, Shan; Kang, Xi; Xiang, Ji; Deng, Huijuan; Yu, Haizhu; Zhu, Manzhou (2016). "How a Single Electron Affects the Properties of the "Non-Superatom" Au25 Nanoclusters". Chemistry of Materials 28 (8): 2609–2617. doi:10.1021/acs.chemmater.5b04655.
[Au25(PPh3)10(SC2H5)5Cl2]2+	Shichibu, Yukatsu; Negishi, Yuichi; Watanabe, Takahito; Chaki, Nirmalya K.; Kawaguchi, Hiroyuki; Tsukuda, Tatsuya (2007). "Biicosahedral Gold Clusters [Au25(PPH3)10(SC n H2 n +1)5Cl2]2+ ( n = 2−18): A Stepping Stone to Cluster-Assembled Materials". The Journal of Physical Chemistry C 111 (22): 7845–7847. doi:10.1021/jp073101t.
[Au25(iPr2-bimy)10Br7]2+	Shen, Hui; Deng, Guocheng; Kaappa, Sami; Tan, Tongde; Han, Ying-Zi; Malola, Sami; Lin, Shui-Chao; Teo, Boon K. et al. (2019). "Highly Robust but Surface-Active: An N-Heterocyclic Carbene-Stabilized Au25 Nanocluster". Angewandte Chemie International Edition 58 (49): 17731–17735. doi:10.1002/anie.201908983. PMID 31517436. http://urn.fi/URN:NBN:fi:jyu-202001081101.
[Au25(MesCH2Bimy)10Br7]2+	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L. et al. (2022). "NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters". JACS Au 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMID 35557749.
[Au25(MesCH2Bimy)10Br8]+	Lummis, Paul A.; Osten, Kimberly M.; Levchenko, Tetyana I.; Sabooni Asre Hazer, Maryam; Malola, Sami; Owens-Baird, Bryan; Veinot, Alex J.; Albright, Emily L. et al. (2022). "NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters". JACS Au 2 (4): 875–885. doi:10.1021/jacsau.2c00004. PMID 35557749.
Au28(TBBT)20	Zeng, Chenjie; Li, Tao; Das, Anindita; Rosi, Nathaniel L.; Jin, Rongchao (2013). "Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography". Journal of the American Chemical Society 135 (27): 10011–10013. doi:10.1021/ja404058q. PMID 23815445. Bibcode: 2013JAChS.13510011Z.
Au28(S-c-C6H11)20	Chen, Yuxiang; Liu, Chong; Tang, Qing; Zeng, Chenjie; Higaki, Tatsuya; Das, Anindita; Jiang, De-en; Rosi, Nathaniel L. et al. (2016). "Isomerism in Au28(SR)20 Nanocluster and Stable Structures". Journal of the American Chemical Society 138 (5): 1482–1485. doi:10.1021/jacs.5b12094. PMID 26817394. Bibcode: 2016JAChS.138.1482C.
Au28(S-c-C6H11)20	Higaki, Tatsuya; Liu, Chong; Chen, Yuxiang; Zhao, Shuo; Zeng, Chenjie; Jin, Renxi; Wang, Shuxin; Rosi, Nathaniel L. et al. (2017). "Oxidation-Induced Transformation of Eight-Electron Gold Nanoclusters: [Au23(SR)16]− to [Au28(SR)20]0". The Journal of Physical Chemistry Letters 8 (4): 866–870. doi:10.1021/acs.jpclett.6b03061. PMID 28145114.
Au29(S-Adm)19	Li, Yingwei; Zhou, Meng; Song, Yongbo; Higaki, Tatsuya; Wang, He; Jin, Rongchao (2021). "Double-helical assembly of heterodimeric nanoclusters into supercrystals". Nature 594 (7863): 380–384. doi:10.1038/s41586-021-03564-6. PMID 34135522. Bibcode: 2021Natur.594..380L.
Au30S(S-tBu)18	Crasto, David; Malola, Sami; Brosofsky, Grace; Dass, Amala; Häkkinen, Hannu (2014). "Single Crystal XRD Structure and Theoretical Analysis of the Chiral Au30S(S- t -Bu)18 Cluster". Journal of the American Chemical Society 136 (13): 5000–5005. doi:10.1021/ja412141j. PMID 24605935. Bibcode: 2014JAChS.136.5000C.
Au30S(S-tBu)18	Yang, Huayan; Wang, Yu; Edwards, Alison J.; Yan, Juanzhu; Zheng, Nanfeng (2014). "High-yield synthesis and crystal structure of a green Au30cluster co-capped by thiolate and sulfide". Chem. Commun. 50 (92): 14325–14327. doi:10.1039/C4CC01773K. PMID 25285336.
Au30(S-tBu)18	Dass, Amala; Jones, Tanya; Rambukwella, Milan; Crasto, David; Gagnon, Kevin J.; Sementa, Luca; De Vetta, Martina; Baseggio, Oscar et al. (2016). "Crystal Structure and Theoretical Analysis of Green Gold Au30(S- t Bu)18 Nanomolecules and Their Relation to Au30S(S- t Bu)18". The Journal of Physical Chemistry C 120 (11): 6256–6261. doi:10.1021/acs.jpcc.6b00062.
Au30(S-Adm)18	Higaki, Tatsuya; Liu, Chong; Zeng, Chenjie; Jin, Renxi; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2016). "Controlling the Atomic Structure of Au30 Nanoclusters by a Ligand-Based Strategy". Angewandte Chemie International Edition 55 (23): 6694–6697. doi:10.1002/anie.201601947. PMID 27099989.
Au30(S-Adm)18	Li, Yingwei; Zhou, Meng; Song, Yongbo; Higaki, Tatsuya; Wang, He; Jin, Rongchao (2021). "Double-helical assembly of heterodimeric nanoclusters into supercrystals". Nature 594 (7863): 380–384. doi:10.1038/s41586-021-03564-6. PMID 34135522. Bibcode: 2021Natur.594..380L.
Au34(S-c-C6H11)22	Dong, Hongwei; Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Chen, Jishi; Tian, Shubo; Zhu, Min; Liu, Xu et al. (2017). "A novel double-helical-kernel evolution pattern of gold nanoclusters: Alternate single-stranded growth at both ends". Nanoscale 9 (11): 3742–3746. doi:10.1039/C6NR09724C. PMID 28134388.
Au34(SPh-2,4-(CH3)2)22	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan et al. (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
Au36(SC5H9)24	Das, Anindita; Liu, Chong; Zeng, Chenjie; Li, Gao; Li, Tao; Rosi, Nathaniel L.; Jin, Rongchao (2014). "Cyclopentanethiolato-Protected Au36(SC5H9)24 Nanocluster: Crystal Structure and Implications for the Steric and Electronic Effects of Ligand". The Journal of Physical Chemistry A 118 (37): 8264–8269. doi:10.1021/jp501073a. PMID 24617814. Bibcode: 2014JPCA..118.8264D.
Au36(SPh)24	Nimmala, Praneeth Reddy; Knoppe, Stefan; Jupally, Vijay Reddy; Delcamp, Jared H.; Aikens, Christine M.; Dass, Amala (2014). "Au36(SPH)24 Nanomolecules: X-ray Crystal Structure, Optical Spectroscopy, Electrochemistry, and Theoretical Analysis". The Journal of Physical Chemistry B 118 (49): 14157–14167. doi:10.1021/jp506508x. PMID 25315687.
Au36(TBBT)24	Zeng, Chenjie; Qian, Huifeng; Li, Tao; Li, Gao; Rosi, Nathaniel L.; Yoon, Bokwon; Barnett, Robert N.; Whetten, Robert L. et al. (2012). "Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24". Angewandte Chemie International Edition 51 (52): 13114–13118. doi:10.1002/anie.201207098. PMID 23154932.
Au36(SCH2Ph-tBu)8Cl20	Yang, Sha; Chai, Jinsong; Song, Yongbo; Kang, Xi; Sheng, Hongting; Chong, Hanbao; Zhu, Manzhou (2015). "A New Crystal Structure of Au36 with a Au14 Kernel Cocapped by Thiolate and Chloride". Journal of the American Chemical Society 137 (32): 10033–10035. doi:10.1021/jacs.5b06235. PMID 26252023. Bibcode: 2015JAChS.13710033Y.
[Au37(PPh3)10(SC2H4Ph)10X2]+	Jin, Renxi; Liu, Chong; Zhao, Shuo; Das, Anindita; Xing, Hongzhu; Gayathri, Chakicherla; Xing, Yan; Rosi, Nathaniel L. et al. (2015). "Tri-icosahedral Gold Nanocluster [Au37(PPH3)10(SC2H4Ph)10X2]+: Linear Assembly of Icosahedral Building Blocks". ACS Nano 9 (8): 8530–8536. doi:10.1021/acsnano.5b03524. PMID 26214221.
Au38(SC2H4Ph)24	Qian, Huifeng; Eckenhoff, William T.; Zhu, Yan; Pintauer, Tomislav; Jin, Rongchao (2010). "Total Structure Determination of Thiolate-Protected Au38 Nanoparticles". Journal of the American Chemical Society 132 (24): 8280–8281. doi:10.1021/ja103592z. PMID 20515047. Bibcode: 2010JAChS.132.8280Q.
Au38(SC2H4Ph)24	Tian, Shubo; Li, Yi-Zhi; Li, Man-Bo; Yuan, Jinyun; Yang, Jinlong; Wu, Zhikun; Jin, Rongchao (2015). "Structural isomerism in gold nanoparticles revealed by X-ray crystallography". Nature Communications 6: 8667. doi:10.1038/ncomms9667. PMID 26482704. Bibcode: 2015NatCo...6.8667T.
Au38S2(S-Adm)20	Liu, Chao; Li, Tao; Li, Gao; Nobusada, Katsuyuki; Zeng, Chenjie; Pang, Guangsheng; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Observation of Body-Centered Cubic Gold Nanocluster". Angewandte Chemie 127 (34): 9964–9967. doi:10.1002/ange.201502667. Bibcode: 2015AngCh.127.9964L.
Au38(2,4-(CH3)2C6H3S)24	Chai, Jinsong; Lv, Ying; Yang, Sha; Song, Yongbo; Zan, Xiaofeng; Li, Qinzhen; Yu, Haizhu; Wu, Mingzai et al. (2017). "X-ray Crystal Structure and Optical Properties of Au38– x Cu x (2,4-(CH3)2C6H3S)24 ( x = 0–6) Alloy Nanocluster". The Journal of Physical Chemistry C 121 (39): 21665–21669. doi:10.1021/acs.jpcc.7b05074.
Au38(SPh-2,4-(CH3)2)24	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan et al. (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
[Au39(PPh3)14Cl6]2+	Teo, Boon K.; Shi, Xiaobo; Zhang, Hong (1992). "Pure gold cluster of 1:9:9:1:9:9:1 layered structure: A novel 39-metal-atom cluster [(Ph3P)14Au39Cl6]Cl2 with an interstitial gold atom in a hexagonal antiprismatic cage". Journal of the American Chemical Society 114 (7): 2743–2745. doi:10.1021/ja00033a073. Bibcode: 1992JAChS.114.2743T.
Au40(S-2-(CH3)Ph)24	Zeng, Chenjie; Chen, Yuxiang; Liu, Chong; Nobusada, Katsuyuki; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Gold tetrahedra coil up: Kekulé-like and double helical superstructures". Science Advances 1 (9). doi:10.1126/sciadv.1500425. PMID 26601286. Bibcode: 2015SciA....1E0425Z.
Au42(S-c-C6H11)26	Dong, Hongwei; Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Chen, Jishi; Tian, Shubo; Zhu, Min; Liu, Xu et al. (2017). "A novel double-helical-kernel evolution pattern of gold nanoclusters: Alternate single-stranded growth at both ends". Nanoscale 9 (11): 3742–3746. doi:10.1039/C6NR09724C. PMID 28134388.
Au42(TBBT)26	Zhuang, Shengli; Liao, Lingwen; Yuan, Jinyun; Xia, Nan; Zhao, Yan; Wang, Chengming; Gan, Zibao; Yan, Nan et al. (2019). "FCC versus Non-FCC Structural Isomerism of Gold Nanoparticles with Kernel Atom Packing Dependent Photoluminescence". Angewandte Chemie International Edition 58 (14): 4510–4514. doi:10.1002/anie.201813426. PMID 30719808.
Au42(TBBT)26	Zhuang, Shengli; Liao, Lingwen; Zhao, Yan; Yuan, Jinyun; Yao, Chuanhao; Liu, Xu; Li, Jin; Deng, Haiteng et al. (2018). "Is the kernel–staples match a key–lock match?". Chemical Science 9 (9): 2437–2442. doi:10.1039/C7SC05019D. PMID 29732119.
Au42(SCH2>Ph)32	Li, Yingwei; Song, Yongbo; Zhang, Xinwen; Liu, Tongyu; Xu, Tingting; Wang, He; Jiang, De-en; Jin, Rongchao (2022). "Atomically Precise Au42 Nanorods with Longitudinal Excitons for an Intense Photothermal Effect". Journal of the American Chemical Society 144 (27): 12381–12389. doi:10.1021/jacs.2c03948. PMID 35767839. Bibcode: 2022JAChS.14412381L.
Au43(C6H11)25	Dong, Hongwei; Liao, Lingwen; Wu, Zhikun (2017). "Two-Way Transformation between FCC- and Nonfcc-Structured Gold Nanoclusters". The Journal of Physical Chemistry Letters 8 (21): 5338–5343. doi:10.1021/acs.jpclett.7b02459. PMID 29039677.
Au44(SPh-2,4-(CH3)2)26	Liao, Lingwen; Zhuang, Shengli; Yao, Chuanhao; Yan, Nan; Chen, Jishi; Wang, Chengming; Xia, Nan; Liu, Xu et al. (2016). "Structure of Chiral Au44(2,4-DMBT)26 Nanocluster with an 18-Electron Shell Closure". Journal of the American Chemical Society 138 (33): 10425–10428. doi:10.1021/jacs.6b07178. PMID 27490914. Bibcode: 2016JAChS.13810425L.
Au44(TBBT)28	Zeng, Chenjie; Chen, Yuxiang; Iida, Kenji; Nobusada, Katsuyuki; Kirschbaum, Kristin; Lambright, Kelly J.; Jin, Rongchao (2016). "Gold Quantum Boxes: On the Periodicities and the Quantum Confinement in the Au28, Au36, Au44, and Au52 Magic Series". Journal of the American Chemical Society 138 (12): 3950–3953. doi:10.1021/jacs.5b12747. PMID 26934618. Bibcode: 2016JAChS.138.3950Z.
Au44(iPr2-bimy)9(PA)6Br8	Shen, Hui; Xu, Zhen; Hazer, Maryam Sabooni Asre; Wu, Qingyuan; Peng, Jian; Qin, Ruixuan; Malola, Sami; Teo, Boon K. et al. (2021). "Surface Coordination of Multiple Ligands Endows N-Heterocyclic Carbene-Stabilized Gold Nanoclusters with High Robustness and Surface Reactivity". Angewandte Chemie International Edition 60 (7): 3752–3758. doi:10.1002/anie.202013718. PMID 33104265. http://urn.fi/URN:NBN:fi:jyu-202010276414.
Au52(TBBT)32	Zeng, Chenjie; Chen, Yuxiang; Liu, Chong; Nobusada, Katsuyuki; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Gold tetrahedra coil up: Kekulé-like and double helical superstructures". Science Advances 1 (9). doi:10.1126/sciadv.1500425. PMID 26601286. Bibcode: 2015SciA....1E0425Z.
Au52(PET)32	Zhuang, Shengli; Liao, Lingwen; Li, Man-Bo; Yao, Chuanhao; Zhao, Yan; Dong, Hongwei; Li, Jin; Deng, Haiteng et al. (2017). "The FCC structure isomerization in gold nanoclusters". Nanoscale 9 (39): 14809–14813. doi:10.1039/C7NR05239A. PMID 28956580.
Au70S20(PPh3)12	Kenzler, Sebastian; Schrenk, Claudio; Frojd, Andrew R.; Häkkinen, Hannu; Clayborne, Andre Z.; Schnepf, Andreas (2018). "Au70S20(PPH3)12: An intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPH3 groups". Chemical Communications 54 (3): 248–251. doi:10.1039/C7CC08014J. PMID 29220046.
Au92(TBBT)44	Zeng, Chenjie; Liu, Chong; Chen, Yuxiang; Rosi, Nathaniel L.; Jin, Rongchao (2016). "Atomic Structure of Self-Assembled Monolayer of Thiolates on a Tetragonal Au92 Nanocrystal". Journal of the American Chemical Society 138 (28): 8710–8713. doi:10.1021/jacs.6b04835. PMID 27355843. Bibcode: 2016JAChS.138.8710Z.
Au102(p-MBA)44	Jadzinsky, Pablo D.; Calero, Guillermo; Ackerson, Christopher J.; Bushnell, David A.; Kornberg, Roger D. (2007). "Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution". Science 318 (5849): 430–433. doi:10.1126/science.1148624. PMID 17947577. Bibcode: 2007Sci...318..430J.
Au102(p-MBA)40(p-BBT)4	Heinecke, Christine L.; Ni, Thomas W.; Malola, Sami; Mäkinen, Ville; Wong, O. Andrea; Häkkinen, Hannu; Ackerson, Christopher J. (2012). "Structural and Theoretical Basis for Ligand Exchange on Thiolate Monolayer Protected Gold Nanoclusters". Journal of the American Chemical Society 134 (32): 13316–13322. doi:10.1021/ja3032339. PMID 22816317. Bibcode: 2012JAChS.13413316H.
Au103S2(S-Nap)41	Higaki, Tatsuya; Liu, Chong; Zhou, Meng; Luo, Tian-Yi; Rosi, Nathaniel L.; Jin, Rongchao (2017). "Tailoring the Structure of 58-Electron Gold Nanoclusters: Au103S2(S-Nap)41 and Its Implications". Journal of the American Chemical Society 139 (29): 9994–10001. doi:10.1021/jacs.7b04678. PMID 28661158. Bibcode: 2017JAChS.139.9994H.
[Au110(p-CF3C6H4CC)48]2-	Wang, Jia-Qi; Shi, Shuang; He, Rui-Lin; Yuan, Shang-Fu; Yang, Gao-Yuan; Liang, Gui-Jie; Wang, Quan-Ming (2020). "Total Structure Determination of the Largest Alkynyl-Protected FCC Gold Nanocluster Au110 and the Study on Its Ultrafast Excited-State Dynamics". Journal of the American Chemical Society 142 (42): 18086–18092. doi:10.1021/jacs.0c07397. PMID 32985888. Bibcode: 2020JAChS.14218086W.
Au130(p-MBT)50	Chen, Yuxiang; Zeng, Chenjie; Liu, Chong; Kirschbaum, Kristin; Gayathri, Chakicherla; Gil, Roberto R.; Rosi, Nathaniel L.; Jin, Rongchao (2015). "Crystal Structure of Barrel-Shaped Chiral Au130( p -MBT)50 Nanocluster". Journal of the American Chemical Society 137 (32): 10076–10079. doi:10.1021/jacs.5b05378. PMID 26244606. Bibcode: 2015JAChS.13710076C.
Au133(SPhtBu)52	Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin; Appavoo, Kannatassen; Sfeir, Matthew Y.; Jin, Rongchao (2015). "Structural patterns at all scales in a nonmetallic chiral Au 133 (SR) 52 nanoparticle". Science Advances 1 (2). doi:10.1126/sciadv.1500045. PMID 26601152. Bibcode: 2015SciA....1E0045Z.
Au144(SCH2Ph)60	Yan, Nan; Xia, Nan; Liao, Lingwen; Zhu, Min; Jin, Fengming; Jin, Rongchao; Wu, Zhikun (2018). "Unraveling the long-pursued Au 144 structure by x-ray crystallography". Science Advances 4 (10). doi:10.1126/sciadv.aat7259. PMID 30333988. Bibcode: 2018SciA....4.7259Y.
Au144(CCAr)60	Lei, Zhen; Li, Jiao-Jiao; Wan, Xian-Kai; Zhang, Wen-Han; Wang, Quan-Ming (2018). "Isolation and Total Structure Determination of an All-Alkynyl-Protected Gold Nanocluster Au144". Angewandte Chemie International Edition 57 (28): 8639–8643. doi:10.1002/anie.201804481. PMID 29771454.
Au146(p-MBA)57	Vergara, Sandra; Lukes, Dylan A.; Martynowycz, Michael W.; Santiago, Ulises; Plascencia-Villa, Germán; Weiss, Simon C.; de la Cruz, M. Jason; Black, David M. et al. (2017). "MicroED Structure of Au146(p-MBA)57 at Subatomic Resolution Reveals a Twinned FCC Cluster". The Journal of Physical Chemistry Letters 8 (22): 5523–5530. doi:10.1021/acs.jpclett.7b02621. PMID 29072840.
Au191(SPh-tBu)66	Sakthivel, Naga Arjun; Shabaninezhad, Masoud; Sementa, Luca; Yoon, Bokwon; Stener, Mauro; Whetten, Robert L.; Ramakrishna, Guda; Fortunelli, Alessandro et al. (2020). "The Missing Link: Au191(SPH- t Bu)66 Janus Nanoparticle with Molecular and Bulk-Metal-like Properties". Journal of the American Chemical Society 142 (37): 15799–15814. doi:10.1021/jacs.0c05685. PMID 32881489. Bibcode: 2020JAChS.14215799S.
Au246(p-MBT)80	Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin; Lambright, Kelly J.; Jin, Rongchao (2016). "Emergence of hierarchical structural complexities in nanoparticles and their assembly". Science 354 (6319): 1580–1584. doi:10.1126/science.aak9750. PMID 28008066. Bibcode: 2016Sci...354.1580Z.
Au279(SPh-tBu)84	Sakthivel, Naga Arjun; Theivendran, Shevanuja; Ganeshraj, Vigneshraja; Oliver, Allen G.; Dass, Amala (2017). "Crystal Structure of Faradaurate-279: Au279(SPH- t Bu)84 Plasmonic Nanocrystal Molecules". Journal of the American Chemical Society 139 (43): 15450–15459. doi:10.1021/jacs.7b08651. PMID 28991464. Bibcode: 2017JAChS.13915450S.

Silver

Table of the crystal structures of silver MPCs.

Formula	References
[{Ag(Ph2PS2)(dppe)}2]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[{Ag(Ph2PS2)(dppe)}4]+	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Ag8(F){S2P(CH2CH2Ph)2}6]+	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag8(Cl){S2P(CH2CH2Ph)2}6]+	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag8(Br){S2P(CH2CH2Ph)2}6]+	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
[Ag8(pfga)6]6-	Liu, Kuan-Guan; Gao, Xue-Mei; Liu, Tongyu; Hu, Mao-Lin; Jiang, De-en (2020). "All-Carboxylate-Protected Superatomic Silver Nanocluster with an Unprecedented Rhombohedral Ag8 Core". Journal of the American Chemical Society 142 (40): 16905–16909. doi:10.1021/jacs.0c06682. PMID 32941019. Bibcode: 2020JAChS.14216905L.
[{Ag(Ph2PS2)(dppe)}10]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Ag12(μ12-I)(μ3-I)4{S2P(CH2CH2Ph)2}6]+	Liao, Jian-Hong; Latouche, Camille; Li, Bing; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2014). "A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton". Inorganic Chemistry 53 (4): 2260–2267. doi:10.1021/ic402960e. PMID 24476137.
Ag12(SCH2C10H7)6(CF3CO2)6(CH3CN)6	Xu, Qing-Qing; Dong, Xi-Yan; Huang, Ren-Wu; Li, Bo; Zang, Shuang-Quan; Mak, Thomas C. W. (2015). "A thermochromic silver nanocluster exhibiting dual emission character". Nanoscale 7 (5): 1650–1654. doi:10.1039/C4NR05122J. PMID 25556676. Bibcode: 2015Nanos...7.1650X.
Ag14(SC6H3F2)12(PPh3)8	Yang, Huayan; Lei, Jing; Wu, Binghui; Wang, Yu; Zhou, Meng; Xia, Andong; Zheng, Lansun; Zheng, Nanfeng (2013). "Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag64+core". Chem. Commun. 49 (3): 300–302. doi:10.1039/C2CC37347E. PMID 23183545.
Ag16(DPPE)4(SC6H3F2)14	Yang, Huayan; Wang, Yu; Zheng, Nanfeng (2013). "Stabilizing subnanometer Ag(0) nanoclusters by thiolate and diphosphine ligands and their crystal structures". Nanoscale 5 (7): 2674–2677. doi:10.1039/C3NR34328F. PMID 23467729. Bibcode: 2013Nanos...5.2674Y.
DNA-Ag8	Huard, Dustin J. E.; Demissie, Aida; Kim, Dahye; Lewis, David; Dickson, Robert M.; Petty, Jeffrey T.; Lieberman, Raquel L. (2019). "Atomic Structure of a Fluorescent Ag8 Cluster Templated by a Multistranded DNA Scaffold". Journal of the American Chemical Society 141 (29): 11465–11470. doi:10.1021/jacs.8b12203. PMID 30562465. Bibcode: 2019JAChS.14111465H.  (PDB: 6NIZ)
DNA-Ag16-NC	Cerretani, Cecilia; Kanazawa, Hiroki; Vosch, Tom; Kondo, Jiro (2019). "Crystal structure of a NIR-Emitting DNA-Stabilized Ag16 Nanocluster". Angewandte Chemie International Edition 58 (48): 17153–17157. doi:10.1002/anie.201906766. PMID 31411360.  (PDB: 6JR4)
DNA-A10:Ag16	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Removal of the A10 adenosine in a DNA-stabilized Ag16 nanocluster". RSC Advances 10 (40): 23854–23860. doi:10.1039/D0RA02672G. PMID 35517326. Bibcode: 2020RSCAd..1023854C.  (PDB: 6M2P)
DNA(A5)-Ag16	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag16 nanocluster". CrystEngComm 22 (46): 8136–8141. doi:10.1039/D0CE01225D. Bibcode: 2020CEG....22.8136C.  (PDB: 7BSE)
DNA(C5)-Ag16	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag16 nanocluster". CrystEngComm 22 (46): 8136–8141. doi:10.1039/D0CE01225D. Bibcode: 2020CEG....22.8136C.  (PDB: 7BSF)
DNA(G5-NIR)-Ag16	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag16 nanocluster". CrystEngComm 22 (46): 8136–8141. doi:10.1039/D0CE01225D. Bibcode: 2020CEG....22.8136C.  (PDB: 7BSG)
DNA(X5)-Ag16	Cerretani, Cecilia; Kondo, Jiro; Vosch, Tom (2020). "Mutation of position 5 as a crystal engineering tool for a NIR-emitting DNA-stabilized Ag16 nanocluster". CrystEngComm 22 (46): 8136–8141. doi:10.1039/D0CE01225D. Bibcode: 2020CEG....22.8136C.  (PDB: 7BSH)
DNA-Ag16	Cerretani, Cecilia; Liisberg, Mikkel B.; Rück, Vanessa; Kondo, Jiro; Vosch, Tom (2022). "The effect of inosine on the spectroscopic properties and crystal structure of a NIR-emitting DNA-stabilized silver nanocluster". Nanoscale Advances 4 (15): 3212–3217. doi:10.1039/D2NA00325B. PMID 36132821. Bibcode: 2022NanoA...4.3212C.  (PDB: 6JR4)
DNA-Ag16	Cerretani, Cecilia; Liisberg, Mikkel B.; Rück, Vanessa; Kondo, Jiro; Vosch, Tom (2022). "The effect of inosine on the spectroscopic properties and crystal structure of a NIR-emitting DNA-stabilized silver nanocluster". Nanoscale Advances 4 (15): 3212–3217. doi:10.1039/D2NA00325B. PMID 36132821. Bibcode: 2022NanoA...4.3212C.  (PDB: 7XLV)
[Ag20{S2P(OPr)2}12]	Dhayal, Rajendra S.; Lin, Yan-Ru; Liao, Jian-Hong; Chen, Yuan-Jang; Liu, Yu-Chiao; Chiang, Ming-Hsi; Kahlal, Samia; Saillard, Jean-Yves et al. (2016). "[Ag20{S2P(OR)2}12: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism"]. Chemistry – A European Journal 22 (29): 9943–9947. doi:10.1002/chem.201602275. PMID 27189869. https://hal-univ-rennes1.archives-ouvertes.fr/hal-01357410/file/Superatom%20With%20Chiral%20Metallic%20Core_accepted.pdf.
[Ag20{S2P(OiPr)2}12]	Dhayal, Rajendra S.; Lin, Yan-Ru; Liao, Jian-Hong; Chen, Yuan-Jang; Liu, Yu-Chiao; Chiang, Ming-Hsi; Kahlal, Samia; Saillard, Jean-Yves et al. (2016). "[Ag20{S2P(OR)2}12: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism"]. Chemistry – A European Journal 22 (29): 9943–9947. doi:10.1002/chem.201602275. PMID 27189869. https://hal-univ-rennes1.archives-ouvertes.fr/hal-01357410/file/Superatom%20With%20Chiral%20Metallic%20Core_accepted.pdf.
[Ag21{S2P(OiPr)2}12]+	Dhayal, Rajendra S.; Liao, Jian-Hong; Liu, Yu-Chiao; Chiang, Ming-His; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2015). "[Ag21{S2P(O i Pr)2}12]+: An Eight-Electron Superatom". Angewandte Chemie International Edition 54 (12): 3702–3706. doi:10.1002/anie.201410332. PMID 25631754.
Ag23(PPh3)8(SC2H4Ph)18	Liu, Chao; Li, Tao; Abroshan, Hadi; Li, Zhimin; Zhang, Chen; Kim, Hyung J.; Li, Gao; Jin, Rongchao (2018). "Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework". Nature Communications 9 (1): 744. doi:10.1038/s41467-018-03136-9. PMID 29467372.
[Ag24(PS4)(iPrSPS3)4{S(tol)}12(dppe)6)]+	Rothenberger, Alexander; Shafaei-Fallah, Maryam; Shi, Weifeng (2007). "A recipe for new organometallic polymers and oligomers? Synthesis and structure of an oligo- and a polymeric arrangement of P–S anions". Chem. Commun. (15): 1499–1501. doi:10.1039/B617177J. PMID 17406686.
[Ag25(SPh(CH3)2)18]−	Joshi, Chakra P.; Bootharaju, Megalamane S.; Alhilaly, Mohammad J.; Bakr, Osman M. (2015). "[Ag25(SR)18]−: The "Golden" Silver Nanoparticle". Journal of the American Chemical Society 137 (36): 11578–11581. doi:10.1021/jacs.5b07088. PMID 26322865.
[Ag28(StBu)23]5+	Zhou, Kun; Qin, Chao; Wang, Xin-Long; Shao, Kui-Zhan; Yan, Li-Kai; Su, Zhong-Min (2014). "Self-assembly of an all-thiol-stabilized {Ag28S23} high-nuclearity luminescent nanocluster with a "crab-like" shape". Dalton Transactions 43 (28): 10695–10699. doi:10.1039/C4DT00762J. PMID 24921974.
Ag29(BDT)12(TPP)4	Abdulhalim, Lina G.; Bootharaju, Megalamane S.; Tang, Qing; Del Gobbo, Silvano; Abdulhalim, Rasha G.; Eddaoudi, Mohamed; Jiang, De-en; Bakr, Osman M. (2015). "Ag29(BDT)12(TPP)4: A Tetravalent Nanocluster". Journal of the American Chemical Society 137 (37): 11970–11975. doi:10.1021/jacs.5b04547. PMID 26104755. Bibcode: 2015JAChS.13711970A.
[Ag29(BDT)12(TPP)4]3-	Nag, Abhijit; Chakraborty, Papri; Bodiuzzaman, Mohammad; Ahuja, Tripti; Antharjanam, Sudhadevi; Pradeep, Thalappil (2018). "Polymorphism of Ag29(BDT)12(TPP)43− cluster: Interactions of secondary ligands and their effect on solid state luminescence". Nanoscale 10 (21): 9851–9855. doi:10.1039/C8NR02629G. PMID 29790561.
[Ag32(DPPE)5(SC6H4CF3)24]2-	Yang, Huayan; Wang, Yu; Zheng, Nanfeng (2013). "Stabilizing subnanometer Ag(0) nanoclusters by thiolate and diphosphine ligands and their crystal structures". Nanoscale 5 (7): 2674–2677. doi:10.1039/C3NR34328F. PMID 23467729. Bibcode: 2013Nanos...5.2674Y.
[Ag32(Dppm)5(SAdm)13Cl8]3+	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
Ag38(SPhF2)26(PPh3)8	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210. Bibcode: 2017JAChS.139...31Y.
Ag38(SPhF2)26(PnBu3)8	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210. Bibcode: 2017JAChS.139...31Y.
[Ag40(SPh(CH3)2)24(PPh3)8]2+	Bodiuzzaman, Mohammad; Ghosh, Atanu; Sugi, Korath Shivan; Nag, Abhijit; Khatun, Esma; Varghese, Babu; Paramasivam, Ganesan; Antharjanam, Sudhadevi et al. (2019). "Camouflaging Structural Diversity: Co-crystallization of Two Different Nanoparticles Having Different Cores but the Same Shell". Angewandte Chemie International Edition 58 (1): 189–194. doi:10.1002/anie.201809469. PMID 30411444.
[Ag40(DMBT)24(PPh3)8H12]2+	Yuan, Xiting; Sun, Cunfa; Li, Xihua; Malola, Sami; Teo, Boon K.; Häkkinen, Hannu; Zheng, Lan-Sun; Zheng, Nanfeng (2019). "Combinatorial Identification of Hydrides in a Ligated Ag40 Nanocluster with Noncompact Metal Core". Journal of the American Chemical Society 141 (30): 11905–11911. doi:10.1021/jacs.9b03009. PMID 31294970. Bibcode: 2019JAChS.14111905Y. http://urn.fi/URN:NBN:fi:jyu-201909044024.
[Ag44(p-MBA)30]4-	Desireddy, Anil; Conn, Brian E.; Guo, Jingshu; Yoon, Bokwon; Barnett, Robert N.; Monahan, Bradley M.; Kirschbaum, Kristin; Griffith, Wendell P. et al. (2013). "Ultrastable silver nanoparticles". Nature 501 (7467): 399–402. doi:10.1038/nature12523. PMID 24005327. Bibcode: 2013Natur.501..399D.
[Ag44(SPhF)30]4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Ag44(SPhF2)30]4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
[Ag44(SPhF3)30]4-	Yang, Huayan; Wang, Yu; Huang, Huaqi; Gell, Lars; Lehtovaara, Lauri; Malola, Sami; Häkkinen, Hannu; Zheng, Nanfeng (2013). "All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures". Nature Communications 4: 2422. doi:10.1038/ncomms3422. PMID 24005600.
Ag44(EBT)26(TPP)4	Bootharaju, Megalamane S.; Lee, Sanghwa; Deng, Guocheng; Malola, Sami; Baek, Woonhyuk; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2021). "Ag44(EBT)26(TPP)4 Nanoclusters with Tailored Molecular and Electronic Structure". Angewandte Chemie International Edition 60 (16): 9038–9044. doi:10.1002/anie.202015907. PMID 33372362. http://urn.fi/URN:NBN:fi:jyu-202102011374.
[Ag45(Dppm)4(StBu)16Br12]3+	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
[Ag46(SPh(CH3)2)24(PPh3)8]2+	Bodiuzzaman, Mohammad; Ghosh, Atanu; Sugi, Korath Shivan; Nag, Abhijit; Khatun, Esma; Varghese, Babu; Paramasivam, Ganesan; Antharjanam, Sudhadevi et al. (2019). "Camouflaging Structural Diversity: Co-crystallization of Two Different Nanoparticles Having Different Cores but the Same Shell". Angewandte Chemie International Edition 58 (1): 189–194. doi:10.1002/anie.201809469. PMID 30411444.
Ag50(Dppm)6(SPh-tBu)30	Du, Wenjun; Jin, Shan; Xiong, Lin; Chen, Man; Zhang, Jun; Zou, Xuejuan; Pei, Yong; Wang, Shuxin et al. (2017). "Ag50(DPPM)6(SR)30 and Its Homologue Au x Ag50– x (DPPM)6(SR)30 Alloy Nanocluster: Seeded Growth, Structure Determination, and Differences in Properties". Journal of the American Chemical Society 139 (4): 1618–1624. doi:10.1021/jacs.6b11681. PMID 28111946. Bibcode: 2017JAChS.139.1618D.
[Ag51(Dppm)4(StBu)16Br6]3+	Zou, Xuejuan; Jin, Shan; Du, Wenjun; Li, Yangfeng; Li, Peng; Wang, Shuxin; Zhu, Manzhou (2017). "Multi-ligand-directed synthesis of chiral silver nanoclusters". Nanoscale 9 (43): 16800–16805. doi:10.1039/C7NR06338E. PMID 29072749.
[Ag62S12(StBu)32]2+	Jin, Shan; Wang, Shuxin; Song, Yongbo; Zhou, Meng; Zhong, Juan; Zhang, Jun; Xia, Andong; Pei, Yong et al. (2014). "Crystal Structure and Optical Properties of the [Ag62S12(SBut)32]2+ Nanocluster with a Complete Face-Centered Cubic Kernel". Journal of the American Chemical Society 136 (44): 15559–15565. doi:10.1021/ja506773d. PMID 25343538. Bibcode: 2014JAChS.13615559J.
[Ag52(SAdm)31Cl13]2+	Zou, Xuejuan; Lv, Ying; Kang, Xi; Yu, Haizhu; Jin, Shan; Zhu, Manzhou (2021). "Structure Determination of the Cl-Enriched [Ag52(SAdm)31Cl13]2+ Nanocluster". Inorganic Chemistry 60 (19): 14803–14809. doi:10.1021/acs.inorgchem.1c02067. PMID 34516083.
[Ag62S13(S-tBu)32]4+	Li, Gen; Lei, Zhen; Wang, Quan-Ming (2010). "Luminescent Molecular Ag−S Nanocluster [Ag62S13(SBu t )32](BF4)4". Journal of the American Chemical Society 132 (50): 17678–17679. doi:10.1021/ja108684m. PMID 21114326.
[Ag63(SPhF2)36(PPh3)8]+	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210. Bibcode: 2017JAChS.139...31Y.
[Ag63(SPhF2)36(PnBu3)8]+	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Su, Haifeng; Gell, Lars; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes". Journal of the American Chemical Society 139 (1): 31–34. doi:10.1021/jacs.6b10053. PMID 27992210. Bibcode: 2017JAChS.139...31Y.
[Ag67(SPhMe2)32(PPh3)8]3+	Alhilaly, Mohammad J.; Bootharaju, Megalamane S.; Joshi, Chakra P.; Besong, Tabot M.; Emwas, Abdul-Hamid; Juarez-Mosqueda, Rosalba; Kaappa, Sami; Malola, Sami et al. (2016). "[Ag67(SPhMe2)32(PPH3)8]3+: Synthesis, Total Structure, and Optical Properties of a Large Box-Shaped Silver Nanocluster". Journal of the American Chemical Society 138 (44): 14727–14732. doi:10.1021/jacs.6b09007. PMID 27733038. Bibcode: 2016JAChS.13814727A.
Ag70S16(SPh)34(PhCO2)4(triphos)4	Wang, Xiu-Jian; Langetepe, Timo; Persau, Claudia; Kang, Bei-Sheng; Sheldrick, George M.; Fenske, Dieter (2002). "Syntheses and Crystal Structures of the New Ag–S Clusters [Ag70S16(SPH)34(PhCO2)4(triphos)4] and [Ag188S94(PR3)30]". Angewandte Chemie International Edition 41 (20): 3818–3822. doi:10.1002/1521-3773(20021018)41:20<3818::AID-ANIE3818>3.0.CO;2-R. PMID 12386858.
Ag78(DPPP)6(SPhCF3)42	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274. Bibcode: 2017JAChS.13916113Y.
Ag78(R-BDPP)6(SPhCF3)42	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274. Bibcode: 2017JAChS.13916113Y.
Ag78(S-BDPP)6(SPhCF3)42	Yang, Huayan; Yan, Juanzhu; Wang, Yu; Deng, Guocheng; Su, Haifeng; Zhao, Xiaojing; Xu, Chaofa; Teo, Boon K. et al. (2017). "From Racemic Metal Nanoparticles to Optically Pure Enantiomers in One Pot". Journal of the American Chemical Society 139 (45): 16113–16116. doi:10.1021/jacs.7b10448. PMID 29053274. Bibcode: 2017JAChS.13916113Y.
SD/Ag90a	Su, Yan-Min; Wang, Zhi; Schein, Stan; Tung, Chen-Ho; Sun, Di (2020). "A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups". Nature Communications 11 (1): 3316. doi:10.1038/s41467-020-17198-1. PMID 32620807.
SD/Ag90b	Su, Yan-Min; Wang, Zhi; Schein, Stan; Tung, Chen-Ho; Sun, Di (2020). "A Keplerian Ag90 nest of Platonic and Archimedean polyhedra in different symmetry groups". Nature Communications 11 (1): 3316. doi:10.1038/s41467-020-17198-1. PMID 32620807.
[Ag115S34(SCH2C6H4tBu)47(dpph)6]	Bestgen, Sebastian; Fuhr, Olaf; Breitung, Ben; Kiran Chakravadhanula, Venkata Sei; Guthausen, Gisela; Hennrich, Frank; Yu, Wen; Kappes, Manfred M. et al. (2017). "[Ag115S34(SCH2C6H4tBu)47(DPPH)6: Synthesis, crystal structure and NMR investigations of a soluble silver chalcogenide nanocluster"]. Chemical Science 8 (3): 2235–2240. doi:10.1039/C6SC04578B. PMID 28507679.
Ag123S35(StBu)50	Fenske, Dieter; Anson, Christopher E.; Eichhöfer, Andreas; Fuhr, Olaf; Ingendoh, Arnd; Persau, Claudia; Richert, Clemens (2005). "Syntheses and Crystal Structures of [Ag123S35(S t Bu)50] and [Ag344S124(S t Bu)96]". Angewandte Chemie International Edition 44 (33): 5242–5246. doi:10.1002/anie.200501414. PMID 16052644.
[Ag136(SPh-tBu)64Cl3]−	Yang, Huayan; Wang, Yu; Chen, Xi; Zhao, Xiaojing; Gu, Lin; Huang, Huaqi; Yan, Juanzhu; Xu, Chaofa et al. (2016). "Plasmonic twinned silver nanoparticles with molecular precision". Nature Communications 7. doi:10.1038/ncomms12809. PMID 27611564. Bibcode: 2016NatCo...712809Y.
[Ag141Cl12(S-Adm)40]3+	Ren, Liting; Yuan, Peng; Su, Haifeng; Malola, Sami; Lin, Shuichao; Tang, Zichao; Teo, Boon K.; Häkkinen, Hannu et al. (2017). "Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)403+ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles"]. Journal of the American Chemical Society 139 (38): 13288–13291. doi:10.1021/jacs.7b07926. PMID 28892364. Bibcode: 2017JAChS.13913288R. http://urn.fi/URN:NBN:fi:jyu-201709273859.
[Ag141Br12(S-Adm)40]3+	Ren, Liting; Yuan, Peng; Su, Haifeng; Malola, Sami; Lin, Shuichao; Tang, Zichao; Teo, Boon K.; Häkkinen, Hannu et al. (2017). "Bulky Surface Ligands Promote Surface Reactivities of [Ag141X12(S-Adm)403+ (X = Cl, Br, I) Nanoclusters: Models for Multiple-Twinned Nanoparticles"]. Journal of the American Chemical Society 139 (38): 13288–13291. doi:10.1021/jacs.7b07926. PMID 28892364. Bibcode: 2017JAChS.13913288R. http://urn.fi/URN:NBN:fi:jyu-201709273859.
Ag188S94(P(C3H7)3)30	Wang, Xiu-Jian; Langetepe, Timo; Persau, Claudia; Kang, Bei-Sheng; Sheldrick, George M.; Fenske, Dieter (2002). "Syntheses and Crystal Structures of the New Ag–S Clusters [Ag70S16(SPH)34(PhCO2)4(triphos)4] and [Ag188S94(PR3)30]". Angewandte Chemie International Edition 41 (20): 3818–3822. doi:10.1002/1521-3773(20021018)41:20<3818::AID-ANIE3818>3.0.CO;2-R. PMID 12386858.
Ag210(SPhiPr)71(PPh3)5Cl	Liu, Jun-Yan; Alkan, Fahri; Wang, Zhi; Zhang, Zhen-Yi; Kurmoo, Mohamedally; Yan, Zier; Zhao, Quan-Qin; Aikens, Christine M. et al. (2019). "Different Silver Nanoparticles in One Crystal: Ag210( i PRPHS)71(Ph3P)5Cl and Ag211( i PRPHS)71(Ph3P)6Cl". Angewandte Chemie International Edition 58 (1): 195–199. doi:10.1002/anie.201810772. PMID 30411441.
Ag211(SPhiPr)71(PPh3)6Cl	Liu, Jun-Yan; Alkan, Fahri; Wang, Zhi; Zhang, Zhen-Yi; Kurmoo, Mohamedally; Yan, Zier; Zhao, Quan-Qin; Aikens, Christine M. et al. (2019). "Different Silver Nanoparticles in One Crystal: Ag210( i PRPHS)71(Ph3P)5Cl and Ag211( i PRPHS)71(Ph3P)6Cl". Angewandte Chemie International Edition 58 (1): 195–199. doi:10.1002/anie.201810772. PMID 30411441.
Ag344S124(StBu)96	Fenske, Dieter; Anson, Christopher E.; Eichhöfer, Andreas; Fuhr, Olaf; Ingendoh, Arnd; Persau, Claudia; Richert, Clemens (2005). "Syntheses and Crystal Structures of [Ag123S35(S t Bu)50] and [Ag344S124(S t Bu)96]". Angewandte Chemie International Edition 44 (33): 5242–5246. doi:10.1002/anie.200501414. PMID 16052644.
[Ag374(SPh-tBu)113Br2Cl2]−	Yang, Huayan; Wang, Yu; Chen, Xi; Zhao, Xiaojing; Gu, Lin; Huang, Huaqi; Yan, Juanzhu; Xu, Chaofa et al. (2016). "Plasmonic twinned silver nanoparticles with molecular precision". Nature Communications 7. doi:10.1038/ncomms12809. PMID 27611564. Bibcode: 2016NatCo...712809Y.

Copper

Table of the crystal structures of copper MPCs.

Formula	References
[(Me3-tach)3Cu6-(μ6-H)Cl4]2+	Köhn, Randolf D.; Pan, Zhida; Mahon, Mary F.; Kociok-Köhn, Gabriele (2003). "Trimethyltriazacyclohexane as bridging ligand for triangular Cu3units and C–H hydride abstraction into a Cu6cluster". Chem. Commun. (11): 1272–1273. doi:10.1039/B302670A. PMID 12809226.
[Cu7(H){S2C(aza-15-crown-5)}6]+	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu7(H){S2C(aza-15-crown-5)}6]". Inorganic Chemistry 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
[Cu7(H)S(C5H9)7(PPh3)3]	Biswass, Sourav; Pal, Amit; Jena, Milan Kumar; Hossain, Sakiat; Jin, Sakai; Das, Saikat; Sahoo, Basudev; Pathak, Biswarup et al. (2024). "Luminescent Hydride-Free [Cu7(H)S(C5H9)7(PPh3)3] Nanocluster: Facilitating Highly Selective C–C Bond Formation". Journal of the American Chemical Society 146 (30): 20937–20944. doi:10.1021/jacs.4c05678. PMID 38979882. Bibcode: 2024JAChS.14620937B.
[Cu8(H){S2(NEt2)}6]+	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu7(H){S2C(aza-15-crown-5)}6]". Inorganic Chemistry 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
[Cu8(H){S2(NnPr2)}6]+	Liao, Ping-Kuei; Fang, Ching-Shiang; Edwards, Alison J.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2012). "Hydrido Copper Clusters Supported by Dithiocarbamates: Oxidative Hydride Removal and Neutron Diffraction Analysis of [Cu7(H){S2C(aza-15-crown-5)}6]". Inorganic Chemistry 51 (12): 6577–6591. doi:10.1021/ic300135w. PMID 22663192.
Cu11H3(Tf-dpf)6(OAc)2	Liu, Chun-Yu; Yuan, Shang-Fu; Wang, Song; Guan, Zong-Jie; Jiang, De-en; Wang, Quan-Ming (2022). "Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters". Nature Communications 13 (1): 2082. doi:10.1038/s41467-022-29819-y. PMID 35440582. Bibcode: 2022NatCo..13.2082L.
Cu12S6(dppo)4	Yang, Xiao-Xun; Issac, Ibrahim; Lebedkin, Sergej; Kühn, Michael; Weigend, Florian; Fenske, Dieter; Fuhr, Olaf; Eichhöfer, Andreas (2014). "Red-luminescent biphosphine stabilized 'Cu12S6' cluster molecules". Chemical Communications 50 (75): 11043–11045. doi:10.1039/C4CC04702H. PMID 25098944.
[Cu12H3(Tf-dpf)6(OAc)2]+	Liu, Chun-Yu; Yuan, Shang-Fu; Wang, Song; Guan, Zong-Jie; Jiang, De-en; Wang, Quan-Ming (2022). "Structural transformation and catalytic hydrogenation activity of amidinate-protected copper hydride clusters". Nature Communications 13 (1): 2082. doi:10.1038/s41467-022-29819-y. PMID 35440582. Bibcode: 2022NatCo..13.2082L.
[Cu13(S2CNnBu2)6(CC(C(O)OCH3))4]+	Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia; Liu, Yu-Chiao; Chiang, Ming-Hsi; Saillard, Jean-Yves; Liu, C. W. (2016). "[Cu13{S2CN n Bu2}6(acetylide)4+: A Two-Electron Superatom"]. Angewandte Chemie International Edition 55 (47): 14704–14708. doi:10.1002/anie.201608609. PMID 27781357. https://hal-univ-rennes1.archives-ouvertes.fr/hal-01416451/file/A%20Two-Electron%20Superatom_accepted.pdf.
[Cu13(S2CNnBu2)6(CC(C6H4F))4]+	Chakrahari, Kiran Kumarvarma; Liao, Jian-Hong; Kahlal, Samia; Liu, Yu-Chiao; Chiang, Ming-Hsi; Saillard, Jean-Yves; Liu, C. W. (2016). "[Cu13{S2CN n Bu2}6(acetylide)4+: A Two-Electron Superatom"]. Angewandte Chemie International Edition 55 (47): 14704–14708. doi:10.1002/anie.201608609. PMID 27781357. https://hal-univ-rennes1.archives-ouvertes.fr/hal-01416451/file/A%20Two-Electron%20Superatom_accepted.pdf.
[Cu14H12(phen)6(PPh3)4]2+	Nguyen, Thuy-Ai D.; Goldsmith, Bryan R.; Zaman, Homaira T.; Wu, Guang; Peters, Baron; Hayton, Trevor W. (2015). "Synthesis and Characterization of a Cu14 Hydride Cluster Supported by Neutral Donor Ligands". Chemistry – A European Journal 21 (14): 5341–5344. doi:10.1002/chem.201500422. PMID 25702682.
[Cu17(tBuCC)16(MeOH)]+	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters". Journal of the American Chemical Society 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875. Bibcode: 2016JAChS.138.2909Z.
[Cu18(tBuCC)16(H2O)2]2+	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters". Journal of the American Chemical Society 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875. Bibcode: 2016JAChS.138.2909Z.
Cu18H7(S(C6H4)PPh2)10I	Huertos, Miguel A.; Cano, Israel; Bandeira, Nuno A. G.; Benet-Buchholz, Jordi; Bo, Carles; Van Leeuwen, Piet W. N. M. (2014). "Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters". Chemistry – A European Journal 20 (49): 16121–16127. doi:10.1002/chem.201404763. PMID 25284300.
[Cu18H17(PPh3)10]+	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R.; Buratto, William R.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2015). "A Cu25 Nanocluster with Partial Cu(0) Character". Journal of the American Chemical Society 137 (41): 13319–13324. doi:10.1021/jacs.5b07574. PMID 26422670. Bibcode: 2015JAChS.13713319N.
Cu20(H)11(S2P(OiPr)2)9	Dhayal, Rajendra S.; Liao, Jian-Hong; Lin, Yan-Ru; Liao, Ping-Kuei; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W. (2013). "A Nanospheric Polyhydrido Copper Cluster of Elongated Triangular Orthobicupola Array: Liberation of H2 from Solar Energy". Journal of the American Chemical Society 135 (12): 4704–4707. doi:10.1021/ja401576s. PMID 23472670. Bibcode: 2013JAChS.135.4704D.
Cu23(tBuCC)13(CF3COO)6	Han, Bao-Liang; Liu, Zhen; Feng, Lei; Wang, Zhi; Gupta, Rakesh Kumar; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2020). "Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel". Journal of the American Chemical Society 142 (12): 5834–5841. doi:10.1021/jacs.0c01053. PMID 32126754. Bibcode: 2020JAChS.142.5834H.
[Cu23(tBuCC)13(CF3COO)6]·CHCl3	Han, Bao-Liang; Liu, Zhen; Feng, Lei; Wang, Zhi; Gupta, Rakesh Kumar; Aikens, Christine M.; Tung, Chen-Ho; Sun, Di (2020). "Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel". Journal of the American Chemical Society 142 (12): 5834–5841. doi:10.1021/jacs.0c01053. PMID 32126754. Bibcode: 2020JAChS.142.5834H.
[Cu25H22(PPh3)12]+	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Goldsmith, Bryan R.; Buratto, William R.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2015). "A Cu25 Nanocluster with Partial Cu(0) Character". Journal of the American Chemical Society 137 (41): 13319–13324. doi:10.1021/jacs.5b07574. PMID 26422670. Bibcode: 2015JAChS.13713319N.
[Cu25H10(SPhCl2)18]3–	Sun, Cunfa; Mammen, Nisha; Kaappa, Sami; Yuan, Peng; Deng, Guocheng; Zhao, Chaowei; Yan, Juanzhu; Malola, Sami et al. (2019). "Atomically Precise, Thiolated Copper–Hydride Nanoclusters as Single-Site Hydrogenation Catalysts for Ketones in Mild Conditions". ACS Nano 13 (5): 5975–5986. doi:10.1021/acsnano.9b02052. PMID 31067029.
[Cu28(H)1515(S2CNR)12]+	Edwards, Alison J.; Dhayal, Rajendra S.; Liao, Ping-Kuei; Liao, Jian-Hong; Chiang, Ming-Hsi; Piltz, Ross O.; Kahlal, Samia; Saillard, Jean-Yves et al. (2014). "Chinese Puzzle Molecule: A 15 Hydride, 28 Copper Atom Nanoball". Angewandte Chemie International Edition 53 (28): 7214–7218. doi:10.1002/anie.201403324. PMID 24803070.
[Cu28H20(S2P(OiPr)2)9]−	Liu, Xianhu; Shen, Hui; Gao, Yang; Deng, Guocheng; Deng, Hongwen; Han, Ying-Zi; Teo, Boon K.; Zheng, Nanfeng (2022). "Cu28H20: A peculiar chiral nanocluster with an exposed Cu atom and 13 surface hydrides". Chemical Communications 58 (55): 7670–7673. doi:10.1039/D1CC06415K. PMID 35727172.
[Cu29Cl4H22(Ph2phen)12]+	Nguyen, Thuy-Ai D.; Jones, Zachary R.; Leto, Domenick F.; Wu, Guang; Scott, Susannah L.; Hayton, Trevor W. (2016). "Ligand-Exchange-Induced Growth of an Atomically Precise Cu29 Nanocluster from a Smaller Cluster". Chemistry of Materials 28 (22): 8385–8390. doi:10.1021/acs.chemmater.6b03879.
Cu32(H)20(S2P(OiPr)2)12	Dhayal, Rajendra S.; Liao, Jian-Hong; Kahlal, Samia; Wang, Xiaoping; Liu, Yu-Chiao; Chiang, Ming-Hsi; Van Zyl, Werner E.; Saillard, Jean-Yves et al. (2015). "[Cu32(H)20{S2P(O i Pr)2}12]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction". Chemistry – A European Journal 21 (23): 8369–8374. doi:10.1002/chem.201501122. PMID 25899822.
[Cu32(PET)24H8Cl2]2-	Lee, Sanghwa; Bootharaju, Megalamane S.; Deng, Guocheng; Malola, Sami; Baek, Woonhyuk; Häkkinen, Hannu; Zheng, Nanfeng; Hyeon, Taeghwan (2020). "[Cu32(PET)24H8Cl2(PPH4)2: A Copper Hydride Nanocluster with a Bisquare Antiprismatic Core"]. Journal of the American Chemical Society 142 (32): 13974–13981. doi:10.1021/jacs.0c06577. PMID 32672452. Bibcode: 2020JAChS.14213974L. http://urn.fi/URN:NBN:fi:jyu-202007215369.
[Cu33(tBuCC)24(Mo4O16)]+	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters". Journal of the American Chemical Society 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875. Bibcode: 2016JAChS.138.2909Z.
[Cu48S20(OtBu)2(Ph2PS2)2(dppm−)4(dppm)4]	Shafaei-Fallah, Maryam; Anson, Christopher E.; Fenske, Dieter; Rothenberger, Alexander (2005). "Functionalised trimethylsilyl reagents in cluster synthesis: Reactions of Ph2P(S)SSiMe3 with group 11 salts". Dalton Transactions (13): 2300–2304. doi:10.1039/B501360G. PMID 15962051.
[Cu53(COOCF3)10(CCtBu)20Cl2H18]+	Yuan, Peng; Chen, Ruihao; Zhang, Xiaomin; Chen, Fengjiao; Yan, Juanzhu; Sun, Cunfa; Ou, Daohui; Peng, Jian et al. (2019). "Ether-Soluble Cu53 Nanoclusters as an Effective Precursor of High-Quality CuI Films for Optoelectronic Applications". Angewandte Chemie International Edition 58 (3): 835–839. doi:10.1002/anie.201812236. PMID 30406951.
[Cu62(tBuCC)16(Mo5O19)2(MoO4)2(OTf)2(OH)4]2+	Zhang, Li-Min; Mak, Thomas C. W. (2016). "Comproportionation Synthesis of Copper(I) Alkynyl Complexes Encapsulating Polyoxomolybdate Templates: Bowl-Shaped Cu33 and Peanut-Shaped Cu62 Nanoclusters". Journal of the American Chemical Society 138 (9): 2909–2912. doi:10.1021/jacs.5b12103. PMID 26899875. Bibcode: 2016JAChS.138.2909Z.

Aluminium

Table of the crystal structures of aluminum MPCs.

Formula	References
{Al(μ5-C5Me5)}4	Dohmeier, Carsten; Robl, Christian; Tacke, Matthias; Schnöckel, Hansgeorg (1991). "The Tetrameric Aluminum(<SCP>I</SCP>) Compound [{Al(η5-C5Me5)}4]". Angewandte Chemie International Edition in English 30 (5): 564–565. doi:10.1002/anie.199105641.
Al4[Si(tBu)3]4	Purath, Andreas; Dohmeier, Carsten; Ecker, Achim; Schnöckel, Hansgeorg; Amelunxen, Kerstin; Passler, Thomas; Wiberg, Nils (1998). "Synthesis and Crystal Structure of the Tetraaluminatetrahedrane Al4[Si( t -Bu)3]4, the Second Al4R4 Compound". Organometallics 17 (9): 1894–1896. doi:10.1021/om971015h.
[Al7{N(SiMe3)2}6]−	Purath, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (1999). "[Al7{N(SiMe3)2}6]−: A First Step towards Aluminum Metal Formation by Disproportionation". Angewandte Chemie International Edition 38 (19): 2926–2928. doi:10.1002/(SICI)1521-3773(19991004)38:19<2926::AID-ANIE2926>3.0.CO;2-B. PMID 10540395.
[Al12(tBu)12]2-	Klinkhammer, Karl-Wilhelm; Uhl, Werner; Wagner, Jürgen; Hiller, Wolfgang (1991). "K2[Al12 i Bu12], a Compound with Al12 Icosahedra". Angewandte Chemie International Edition in English 30 (2): 179–180. doi:10.1002/anie.199101791.
[Al12(N(SiMe3)2)18]1-	Purath, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (1999). "An Al12R8− cluster as an intermediate on the way from aluminium(I) compounds to aluminium metal†". Chemical Communications (19): 1933–1934. doi:10.1039/A904247D.
[Al14{N(SiMe3)2}6I6]2−	Köhnlein, Harald; Stösser, Gregor; Baum, Elke; Möllhausen, Evelyn; Huniar, Uwe; Schnöckel, Hansgeorg (2000). "A Metalloid Al14 Cluster with the Structure of a "Nano-Wheel"". Angewandte Chemie International Edition 39 (4): 799–801. doi:10.1002/(SICI)1521-3773(20000218)39:4<799::AID-ANIE799>3.0.CO;2-B. PMID 10760874.
Al22Cl20(THF)12	Klemp, Christoph; Bruns, Michael; Gauss, Jürgen; Häussermann, Ulrich; Stösser, Gregor; Van Wüllen, Leo; Jansen, Martin; Schnöckel, Hansgeorg (2001). "Al22Cl20·12L (L = THF, THP): The First Polyhedral Aluminum Chlorides". Journal of the American Chemical Society 123 (37): 9099–9106. doi:10.1021/ja004022x. PMID 11552817.
Al22Cl20(THP)12	Klemp, Christoph; Bruns, Michael; Gauss, Jürgen; Häussermann, Ulrich; Stösser, Gregor; Van Wüllen, Leo; Jansen, Martin; Schnöckel, Hansgeorg (2001). "Al22Cl20·12L (L = THF, THP): The First Polyhedral Aluminum Chlorides". Journal of the American Chemical Society 123 (37): 9099–9106. doi:10.1021/ja004022x. PMID 11552817.
Al50(C5Me5)12	Vollet, Jean; Hartig, Jens R.; Schnöckel, Hansgeorg (2004). "Al50C120H180: A Pseudofullerene Shell of 60 Carbon Atoms and 60 Methyl Groups Protecting a Cluster Core of 50 Aluminum Atoms". Angewandte Chemie International Edition 43 (24): 3186–3189. doi:10.1002/anie.200453754. PMID 15199573.
[Al69{N(SiMe3)2}18]3-	Köhnlein, H.; Purath, A.; Klemp, C.; Baum, E.; Krossing, I.; Stösser, G.; Schnöckel, H. (2001). "Synthesis and Characterization of an Al693- Cluster with 51 Naked al Atoms: Analogies and Differences to the Previously Characterized Al772- Cluster". Inorganic Chemistry 40 (19): 4830–4838. doi:10.1021/ic0104297. PMID 11531428.
[Al77(N(SiMe3)2)20]2-	Ecker, A.; Weckert, E.; Schnöckel, H. (1997). "Synthesis and structural characterization of an AI77 cluster". Nature 387 (6631): 379–381. doi:10.1038/387379a0.

Gallium

Table of the crystal structures of gallium MPCs.

Formula	References
Ga4(Si(SiMe3)3)4	Linti, Gerald (1996). "Zur chemie des galliums, 61: Tris(trimethylsilyl) silylgallium(I) —eine experimentelle und theoretische studie". Journal of Organometallic Chemistry 520 (1–2): 107–113. doi:10.1016/0022-328X(96)06317-6.
Ga8(C(SiMe3)3)6	Schnepf, Andreas; Köppe, Ralf; Schnöckel, Hansgeorg (2001). "A Ga8R6 Cluster as an Ideal Model for a Metal-Metal Bond?". Angewandte Chemie International Edition 40 (7): 1241–1243. doi:10.1002/1521-3773(20010401)40:7<1241::AID-ANIE1241>3.0.CO;2-J. PMID 11301437.
Ga9(tBu)9	Uhl, Werner; Cuypers, Lars; Harms, Klaus; Kaim, Wolfgang; Wanner, Matthias; Winter, Rainer; Koch, Rainer; Saak, Wolfgang (2001). "Ga9(CMe3)9, an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds EnRn (E=B-In)". Angewandte Chemie International Edition 40 (3): 566–568. doi:10.1002/1521-3773(20010202)40:3<566::AID-ANIE566>3.0.CO;2-T. http://nbn-resolving.de/urn:nbn:de:bsz:352-138172.
Ga10[Si(SiMe3)3]6	Kehrwald, Michael; Köstler, Wolfgang; Rodig, Alexander; Linti, Gerald; Blank, Thomas; Wiberg, Nils (2001). "Ga10[Si(SiMe3)3]6, [Ga10(Si t Bu3)6]−, and [Ga13(Si t Bu3)6]−Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Organometallics 20 (5): 860–867. doi:10.1021/om000703p.
[Ga10(SitBu3)6]−	Kehrwald, Michael; Köstler, Wolfgang; Rodig, Alexander; Linti, Gerald; Blank, Thomas; Wiberg, Nils (2001). "Ga10[Si(SiMe3)3]6, [Ga10(Si t Bu3)6]−, and [Ga13(Si t Bu3)6]−Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Organometallics 20 (5): 860–867. doi:10.1021/om000703p.
[Ga12(C13H9)10]2−	Schnepf, Andreas; Stößer, Gregor; Köppe, Ralf; Schnöckel, Hansgeorg (2000). "[Li(THF)4]2+[Ga12(C13H9)10]2−: The First Molecular Compound with an Icosahedral Ga12 Framework". Angewandte Chemie International Edition 39 (9): 1637–1639. doi:10.1002/(SICI)1521-3773(20000502)39:9<1637::AID-ANIE1637>3.0.CO;2-O. PMID 10820460.
[Ga18(SitBu3)8]	Donchev, Alexander; Schnepf, Andreas; Stößer, Gregor; Baum, Elke; Schnöckel, Hansgeorg; Blank, Thomas; Wiberg, Nils (2001). "[Ga18(SitBu3)8] and [Ga22(SitBu3)8]—Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Chemistry - A European Journal 7 (15): 3348–3353. doi:10.1002/1521-3765(20010803)7:15<3348::AID-CHEM3348>3.0.CO;2-8. PMID 11531121.
[Ga19(C(SiMe3)3)6]−	Schnepf, A.; Stösser, G.; Schnöckel, H. (2000). "Synthesis, Structure, and Bonding of a Molecular Metalloid Ga19 Cluster Anion". Journal of the American Chemical Society 122 (38): 9178–9181. doi:10.1021/ja000990o. Bibcode: 2000JAChS.122.9178S.
[Ga22(SitBu3)8]	Donchev, Alexander; Schnepf, Andreas; Stößer, Gregor; Baum, Elke; Schnöckel, Hansgeorg; Blank, Thomas; Wiberg, Nils (2001). "[Ga18(SitBu3)8] and [Ga22(SitBu3)8]—Syntheses and Structural Characterization of Novel Gallium Cluster Compounds". Chemistry - A European Journal 7 (15): 3348–3353. doi:10.1002/1521-3765(20010803)7:15<3348::AID-CHEM3348>3.0.CO;2-8. PMID 11531121.
[Ga22{N(SiMe3)2}10]2−	Template:Cite journal
Ga23{N(SiMe3)2}11	Template:Cite journal
[Ga26(Si(SiMe3)3)8]−	Template:Cite journal
[Ga84{N(SiMe3)2}20]4−	Template:Cite journal

Germanium

Table of the crystal structures of germanium MPCs.

Formula	References
[Ge9{Si(SiMe3)3}3]−	Template:Cite journal
ZnGe18{Si(SiMe3)3}4{Ge(SiMe3)3}2	Template:Cite journal
[Ge9(Si(SiMe3)2(SiPh3))2]–	Template:Cite journal
[Ge9(Si(SiMe3)3)(Si(SiMe3)2(SiPh3))2]–	Template:Cite journal
[Ge9(Si(SiMe3)2(SiiPr3))3]–	Template:Cite journal
[Ge9(SiHtBu2)3]–	Template:Cite journal
(Ge9{Si(TMS)3}2)(PtBu2CuNHCMes)	Template:Cite journal
NHCDippCu[η3-(Ge9{Si(TMS)3}2)(PMes2)]	Template:Cite journal
[(Ge9{Si(TMS)3}2)(tBu2PCu)Ge9(Si(TMS)3)2]	Template:Cite journal
Ge18[Si(SiMe3)3]6	Template:Cite journal

Palladium

Table of the crystal structures of palladium MPCs.

Formula	References
[Pd10(μ-CO)8(μ3-CO)4(PEt3)6]	D. Michael P. Mingos and Christopher M. Hill. Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croat. Chem. Acta 1995, 68, 4, 745-767
[Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]	D. Michael P. Mingos and Christopher M. Hill. Synthesis and Characterisation of [Pd10(μ-CO)(μ3-CO)4(PEt3)6] and [Pd10(μ-CO)6(μ3-CO)2(μ-CNXylyl)2(PEt3)6]. Croat. Chem. Acta 1995, 68, 4, 745-767
Pd10(CO)14(PBun3)4	Template:Cite journal
Pd12(CO)12(PBun3)6	Template:Cite journal
Pd12(CO)12(PPh3)6	Template:Cite journal
Pd16(CO)13(PMe3)9	Template:Cite journal
[Pd29(CO)28(PPh3)7]2-	Template:Cite journal
Pd30(CO)26(PEt3)10	Template:Cite journal
Pd35(CO)23(PMe3)15	Template:Cite journal
Pd39(CO)23(PMe3)16	Template:Cite journal
Pd54(CO)40(PEt3)14	Template:Cite journal
Pd55(PiPr3)12(μ3-CO)20	Template:Cite journal
Pd59(CO)32(PMe3)21	Template:Cite journal
Pd59(CO)32(PMe3)21	Template:Cite journal
Pd69(CO)36(PEt3)18	Template:Cite journal
Pd145(CO)51(PEt3)30	Template:Cite journal

Mixed metal

Table of the crystal structures of alloy and doped MPCs.

Formula	References
[Au{Pt3(μ-CO)3(PPh3)3}2]+	Template:Cite journal
[Cu{Pt3(μ-CO)3(PPh3)3}2]+	Template:Cite journal
Au2Cu6(SAdm)6(PPh3)2	Template:Cite journal
[Au4Cu4(DPPM)2(SAdm)5]+	Template:Cite journal
[Au4Cu5(C6H11S)6(DPPM)2]+	Template:Cite journal
Au5Cu6(Dppf)2(SAdm)6)	Template:Cite journal
((C5Me5)*AlCu)6H4	Template:Cite journal
((C5Me5)*AlCu)6H3(N=CHPh)	Template:Cite journal
[Ag12Au1(Pz(CF3)2)6(CCPh)8)]−	Template:Cite journal
[Ag12Au1(Pz(CF3)2)6(CCPhF)8)]−	Template:Cite journal
[Ag12Au1(Pz(CF3)2)6(CCPhOMe)8)]−	Template:Cite journal
[Au13Cu2(PPh3)6(SPy)6)]+	Template:Cite journal
[Au7Ag6Cu2(SCH2Ph)6]+	Template:Cite journal
[Au2Pd14(μ3-CO)7(μ2-CO)2(PMe3)11]2+	Template:Cite journal
[Au13Cu4(PPh2Py)4(SC6H4-tBu)8)]+	Template:Cite journal
[Au13Cu4(PPh2Py)3(SePh)9]	Template:Cite journal
[Au7Cu12(dppy)6(TBBT)6Br4]3+	Template:Cite journal
[Pd16Ni4(CO)22(PPh3)4]2-	Template:Cite journal
[Au13Cu8(PPh2Py)12]+	Template:Cite journal
Au20Ag(S-tBu)15	Template:Cite journal
Au16Ag5(S-tBu)15	Template:Cite journal
Au16Cu5(S-tBu)15	Template:Cite journal
Au22Cd(SAdm)16	Template:Cite journal
[PdAg24(SPhCl2)18]2–	Template:Cite journal
[PtAg24(SPhCl2)18]2–	Template:Cite journal
Au24Cd(PET)18	Template:Cite journal
[Au13Ag12(PPh3)10Cl8]+	Template:Cite journal
[Ag24Au(SC6H11)18]−	Template:Cite journal
[Ag20Au5(SC6H11)18]−	Template:Cite journal
[Ag19Au6(SC6H11)18]−	Template:Cite journal
[Cu2Au23(PPh3)10(SC2H4Ph)5Cl2]2+	Template:Cite journal
Pd2Au23(PPh3)10Br7	Template:Cite journal
[Au25–xCux(PET)18]−	Template:Cite journal
Au24–xPtCux(PET)18	Template:Cite journal
Ag23Pd2(PPh3)10Cl7	Template:Cite journal
[Au13Ag16(C10H6NO)24]3-	Template:Cite journal
[Ag22Cu7(C≡CR)16(PPh3)5Cl6]−	Template:Cite journal
Au24Cu6(SPhtBu)22	Template:Cite journal
Au30–xAgx(S-tBu)18	Template:Cite journal
Au30-xAgx(S-tBu)18	Template:Cite journal
Pd29Ni3(CO)22(PMe3)13	Template:Cite journal
[Pt2Cu34(PET)22Cl4]2-	Template:Cite journal
[Cu3Au34(PPh3)13(SCH2PhtBu)6S2]3+	Template:Cite journal
Au34Ag4(SCH2CH2Ph)24	Template:Cite journal
Au37Cu(2,4-(CH3)2C6H3S)24	Template:Cite journal
[Pd33Ni9(CO)41(PPh3)6]4-	Template:Cite journal
[Ag28Cu12(S(PhCl2))24]4–	Template:Cite journal
[Au12Ag32(SPhF)30]4-	Template:Cite journal
[Au12Ag32(SPhF2)30]4-	Template:Cite journal
[Au12Ag32(SPhF3)30]4-	Template:Cite journal
[Au12Ag32(SPhF2)30]4-	Template:Cite journal
[Au12Ag32(SPhCF3)30]4-	Template:Cite journal
[Au10Ag34(SC6H3F2)30]4–	Template:Cite journal
[Au12Ag32(SC6H3F2)30]4–	Template:Cite journal
Cd12Ag32(SePh)36	Template:Cite journal
[Au12+nCu32(SPhCF3)30+n]4–	Template:Cite journal
Au5.34Ag44.66(Dppm)6(SPh-tBu)30	Template:Cite journal
[Cu43Al12](C5Me5)12	Template:Cite journal
[Au80Ag30(C≡CPh)42Cl9]+	Template:Cite journal
Au57Ag53(C≡CPh)40Br12	Template:Cite journal
[Au74Ag60(C≡CPh)40Br12]2−	Template:Cite journal
[Au78Ag66(C≡CPh)48Cl8]q−	Template:Cite journal
Pd164−xPtx(CO)72(PPh3)20	Template:Cite journal

Partially experimentally determined

Table of partially experimentally determined structures of MPCs.

Formula	References
Ag29(LA)12∩CB1	Template:Cite journal
Ag29(LA)12@β-CD1	Template:Cite journal
Au68(SH)32	Template:Cite journal
Au144(3-MBA)x	Template:Cite journal

References

Template:Reflist

External links

• Template:Cite journal this work

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