Chemistry:Nitronium tetrafluoroborate

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Nitronium tetrafluoroborate
Nitronium-tetrafluoroborate-xtal-CM-3D-ellipsoids-A.png
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Names
Other names
nitronium fluoroborate, NO2BF4
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 237-533-5
Properties
BNO2F4
Molar mass 132.81
Hazards
Safety data sheet [1]
GHS pictograms GHS05: CorrosiveGHS07: HarmfulGHS08: Health hazard
GHS Signal word Danger
H314, H317, H334
P260, P261, P264, P272, P280, P285, P301+330+331, P302+352, P303+361+353, P304+340, P304+341, P305+351+338, P310, P321, P333+313, P342+311, P363, P405, P501
Related compounds
Other cations
Nitrosonium tetrafluoroborate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents.

Preparation

Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide.[1]

Applications

Nitronium tetrafluoroborate is used as a nitration agent.

References

  1. Kenneth Schofield (1980). Aromatic nitration. CUP Archive. p. 88. ISBN 0-521-23362-3.