Chemistry:Propylamine
From HandWiki
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| Names | |
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| Preferred IUPAC name
Propan-1-amine | |
| Other names
Propylamine
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| Identifiers | |
3D model (JSmol)
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| 1098243 | |
| ChEBI | |
| ChEMBL | |
| ChemSpider | |
| EC Number |
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| 1529 | |
PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 1277 |
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| Properties | |
| C3H9N | |
| Molar mass | 59.112 g·mol−1 |
| Appearance | Colorless liquid |
| Odor | fishy, ammoniacal |
| Density | 0.719 g mL−1 |
| Melting point | −83.00 °C; −117.40 °F; 190.15 K |
| Boiling point | 47 to 51 °C; 116 to 124 °F; 320 to 324 K |
| Miscible | |
| log P | 0.547 |
| Vapor pressure | 33.01 kPa (at 20 °C) |
Henry's law
constant (kH) |
660 μmol Pa−1 kg−1 |
| Acidity (pKa) | 10.71 |
Refractive index (nD)
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1.388 |
| Thermochemistry | |
Heat capacity (C)
|
162.51 J K−1 mol−1 |
Std molar
entropy (S |
227.44 J K−1 mol−1 |
Std enthalpy of
formation (ΔfH⦵298) |
−101.9–−101.1 kJ mol−1 |
Std enthalpy of
combustion (ΔcH⦵298) |
−2.368–−2.362 MJ mol−1 |
| Hazards | |
| GHS pictograms |   
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| GHS Signal word | DANGER |
| H225, H302, H311, H314, H331 | |
| P210, P261, P280, P305+351+338, P310 | |
| Flash point | −30 °C (−22 °F; 243 K) |
| Explosive limits | 2–10.4% |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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| Related compounds | |
Related alkanamines
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
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| Infobox references | |
Tracking categories (test):
Propylamine, also known as n-propylamine, is an amine with the chemical formula CH3(CH2)2NH2.[1] It is a colorless volatile liquid.[2]
Propylamine is a weak base. Its Kb (base dissociation constant) is 4.7 × 10−4.
Preparation
Propyl amine hydrochloride can be prepared by reacting 1-propanol with ammonium chloride at high temperature and pressure using a Lewis acid catalyst such as ferric chloride.
References
- ↑ "Propylamine". https://pubchem.ncbi.nlm.nih.gov/compound/Propylamine.
- ↑ Karsten Eller, Erhard Henkes, Roland Rossbacher, Hartmut Höke "Amines, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. doi:10.1002/14356007.a02_001
External links
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