Chemistry:Tsumebite
| Tsumebite | |
|---|---|
 Tsumebite from the Bluebell Claims, California, US. | |
| General | |
| Category | Phosphate minerals |
| Formula (repeating unit) | Pb 2Cu(PO 4)(SO 4)(OH) |
| Strunz classification | 8.BG.05 |
| Dana classification | 43.4.2.1 |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P21/m |
| Identification | |
| Formula mass | 685.99 g/mol |
| Color | Emerald-green, green in transmitted light |
| Crystal habit | Crusts of intergrown crystals on matrix |
| Twinning | Almost always twinned. Twins may be multiple, with serrated re-entrants. |
| Cleavage | None |
| Fracture | Uneven |
| Tenacity | Brittle |
| Mohs scale hardness | 3 1⁄2 |
| |re|er}} | Adamantine to vitreous |
| Streak | Green |
| Diaphaneity | Transparent |
| Specific gravity | 6.13 |
| Optical properties | Biaxial (+) |
| Refractive index | Nx = 1.885 to 1.900, Ny = 1.920, Nz = 1.942 to 1.956 |
| Pleochroism | Faint: X = Y = very pale blue to colorless; Z = robin’s-egg-blue[1][2] |
| Solubility | Readily soluble in HCl and slowly soluble in HNO 3.[3] |
| References | [1][3][4][5] |
Tsumebite is a rare phosphate mineral named in 1912 after the locality where it was first found, the Tsumeb mine in Namibia, well known to mineral collectors for the wide range of minerals found there. Tsumebite is a compound phosphate and sulfate of lead and copper, with hydroxyl, formula Pb
2Cu(PO
4)(SO
4)(OH). There is a similar mineral called arsentsumebite, where the phosphate group PO
4 is replaced by the arsenate group AsO
4, giving the formula Pb
2Cu(AsO
4)(SO
4)(OH). Both minerals are members of the brackebuschite group.
The brackebuschite group
The minerals in the brackebuschite group have the general formula A
2B(H
2O,OH)(TO
4)
2 and crystallise in the monoclinic system, space group P21/m. The group includes:[4]
- brackebuschite Pb
2Mn3+(VO
4)
2(OH) - arsenbrackebuschite Pb
2(Fe3+,Zn)(AsO
4)
2(OH,H
2O) - gamagarite Ba
2Fe3+(VO
4)
2(OH) - goedkenite Sr
2Al(PO
4)
2(OH) - bearthite Ca
2Al(PO
4)
2OH - tsumebite Pb
2Cu(PO
4)(SO
4)(OH) - arsentsumebite Pb
2Cu(AsO
4)(SO
4)(OH) - vauquelinite Cu2+Pb
2(CrO
4)(PO
4)(OH) - fornacite CuPb
2(CrO
4)(AsO
4)(OH) - molybdofornacite CuPb
2MoO
4AsO
4(OH)
Structure
The structure of the brackebuschite group minerals is composed of B-(O,OH)6 octahedra, two non-equivalent TO4 tetrahedra, TO4(1) and TO4(2), and two different irregular polyhedra of large cations. B and T represent different elements in different members of the group. Chains formed from the B octahedra link through the oxygens of TO4(2) tetrahedra, while the large cation polyhedra form double chains parallel to the b crystal axis through edge sharing with TO4(1) tetrahedra. The result is a tight three-dimensional structure.[4] In tsumebite copper ions occupy the B sites, and phosphorus and sulfur occupy the T sites. Lead is the large cation.
Unit cell
Tsumebite belongs to the monoclinic crystal class 2/m, meaning that it has one twofold axis of symmetry perpendicular to a mirror plane. The space group is P 21/m, meaning that the crystal lattice is a primitive lattice, with structural elements only at the vertices of the unit cell. These structural elements are made up of two formula units (Z = 2).
Unit cell parameters are a = 8.69 Å, b = 5.78 Å, c = 7.86 Å, β = 111.87°[3][4][5] or a = 8.70 Å, b = 5.80 Å, c = 7.85 Å, β = 111.5°.[1][2]
Optical properties
Tsumebite is an emerald-green color, transparent and green in transmitted light, with a green streak and an adamantine (diamond-like) to vitreous (glassy) luster. It is biaxial (+) with refractive indices Nx = 1.885 to 1.900, Ny = 1.920 and Nz = 1.942 to 1.956. It is faintly pleochroic with X = Y = very pale blue to colorless and Z = robin's-egg-blue.[1][2]
Physical properties
The mineral typically occurs as crusts of intergrown crystals on matrix. Cleavage is absent, but twinning is almost universal, and twins may be multiple, with serrated re-entrants.[1] It is brittle, with an uneven fracture, hardness 3 1⁄2 and specific gravity 6.13. It is readily soluble in hydrochloric acid HCl and slowly soluble in nitric acid HNO3.[3] It is not radioactive.[5]
Environment
Tsumebite is a rare secondary mineral in the oxidised zone of some arsenic-bearing lead-copper deposits, with other lead-bearing phosphates and sulfates.[1] Associated minerals include azurite, smithsonite, malachite, cerussite, mimetite, wulfenite and olivenite.[1] The type locality is the Tsumeb mine, Tsumeb, Otjikoto Region, Namibia.[3] The Handbook of Mineralogy[1] states that the type material was destroyed by bombing, but does not indicate when or where.
Tsumebite occurs at Morenci, Arizona, predominantly as twinned crystals associated with wulfenite, olivenite and the hyalite variety of opal.[2] At Broken Hill, New South Wales, Australia, tsumebite has been found as lustrous pale blue to bluish green crystals. It usually occurs with yellow crusts of corkite-hinsdalite, colorless to white pyromorphite needles and sprays of pale greyish green zincian libethenite. Less commonly found with scholzite and torbernite.[7]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Handbook of Mineralogy
- ↑ 2.0 2.1 2.2 2.3 American Mineralogist (1966) 51: 258–259 and 267
- ↑ 3.0 3.1 3.2 3.3 3.4 Mindat.org
- ↑ 4.0 4.1 4.2 4.3 Gaines et al (1997) Dana’s New Mineralogy Eighth Edition, Wiley
- ↑ 5.0 5.1 5.2 Webmineral data
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W. https://www.cambridge.org/core/journals/mineralogical-magazine/article/imacnmnc-approved-mineral-symbols/62311F45ED37831D78603C6E6B25EE0A.
- ↑ Australian Journal of Mineralogy (1997) 3-1:53
- LaForge (1938) American Mineralogist: 23: 772
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