Chemistry:Yttrium(III) arsenide

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Yttrium(III) arsenide[1]
NaCl polyhedra.png
Names
IUPAC name
Yttrium(III) arsenide
Other names
Yttrium arsenide
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 235-507-8
Properties
YAs
Molar mass 163.828 g/mol
Appearance cubic crystals
Density 5.59 g/cm3
Structure
cubic, cF8
Fm3m, No. 225
Related compounds
Other anions
Yttrium nitride
Yttrium phosphide
Yttrium(III) antimonide
Other cations
Scandium arsenide
Lutetium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Yttrium arsenide is an inorganic compound of yttrium and arsenic with the chemical formula YAs. It can be prepared by reacting yttrium and arsenic at high temperature.[2] Some literature has done research on the eutectic system of it and zinc arsenide.[3]

It reacts with iron, iron(III) arsenide, iron(III) oxide and yttrium(III) fluoride (for doping) at high temperature to obtain superconducting material YFeAsO0.9F0.1 (Tc=10.2 K).[4]

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–94, ISBN 0-8493-0594-2 
  2. L.H. Brixner (1960-09-01). "Structure and electrical properties of some new rare earth arsenides, antimonides and tellurides" (in en). Journal of Inorganic and Nuclear Chemistry 15 (1–2): 199–201. doi:10.1016/0022-1902(60)80038-3. https://linkinghub.elsevier.com/retrieve/pii/0022190260800383. Retrieved 2021-09-09. 
  3. Mirzaakhmedov, M.; Khuseinov, B.; Pishchikov, D. I.; Marenkin, S. F. Interaction in the zinc diarsenide-yttrium arsenide system(in Russian). Zhurnal Neorganicheskoi Khimii, 1990. 35 (10): 2622-2624.
  4. Chong, S V; Mochiji, T; Kadowaki, K (2009-03-01). "Superconductivity in yttrium iron oxyarsenide system". Journal of Physics: Conference Series (IOP Publishing) 150 (5): 052036. doi:10.1088/1742-6596/150/5/052036. ISSN 1742-6588. 

External reading