Chemistry:Samarium(III) perchlorate
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3D model (JSmol)
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PubChem CID
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| Properties | |
| Cl3O12Sm | |
| Molar mass | 448.70 g·mol−1 |
| Appearance | white solid[1] pale yellow crystals[2] |
| soluble in water and ethanol[2] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Samarium(III) perchlorate is an inorganic compound with the chemical formula Sm(ClO4)3.
Preparation
Samarium(III) perchlorate can be obtained by the reaction of perchloric acid and samarium(III) oxide.[3] The hydrate precipitated from the solution can be dehydrated with dichlorine hexoxide to obtain the anhydrous form.[1]
Properties
Anhydrous samarium(III) perchlorate forms hexagonal crystals, space group P63/m, unit cell parameters a=9.259 Å, c=5.746 Å, Z=2.[4] It reacts with ammonium thiocyanate and 1-butyl-3-methylimidazolium thiocyanate ([BMIM]SCN) in absolute ethanol to obtain the ionic liquid [BMIM]4[Sm(NCS)7(H2O)].[5]
References
- ↑ 1.0 1.1 Favier, Frédéric; Pascal, Jean-Louis (1992). "Synthesis and structural analysis of a homogeneous series of anhydrous rare-earth-metal perchlorates" (in en). Journal of the Chemical Society, Dalton Transactions (13): 1997–2002. doi:10.1039/dt9920001997. ISSN 0300-9246.
- ↑ 2.0 2.1 Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. pp. 2930–. ISBN 978-0-412-30120-9. https://books.google.com/books?id=9eJvoNCSCRMC&pg=PA2930.
- ↑ Wickleder, Mathias S.; Schäfer, Wolfgang (Feb 1999). "Synthesis and Structure of Anhydrous Rare-Earth Perchlorates M(ClO4)3 (M = La, Ce-Er, Y): Derivatives of the UCl3 Type of Structure" (in de). Zeitschrift für anorganische und allgemeine Chemie 625 (2): 309–312. doi:10.1002/(SICI)1521-3749(199902)625:2<309::AID-ZAAC309>3.0.CO;2-6. ISSN 0044-2313.
- ↑ Pascal, J.L.; Favier, F.; Cunin, F.; Fitch, A.; Vaughan, G. (Sep 1998). "Crystalline and Molecular Structures of Anhydrous Lanthanide PerchloratesLn(ClO4)3 with Ln=La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu" (in en). Journal of Solid State Chemistry 139 (2): 259–265. doi:10.1006/jssc.1998.7838. Bibcode: 1998JSSCh.139..259P.
- ↑ Nockemann, Peter; Thijs, Ben; Postelmans, Niels; Van Hecke, Kristof; Van Meervelt, Luc; Binnemans, Koen (2006-10-01). "Anionic Rare-Earth Thiocyanate Complexes as Building Blocks for Low-Melting Metal-Containing Ionic Liquids" (in en). Journal of the American Chemical Society 128 (42): 13658–13659. doi:10.1021/ja0640391. ISSN 0002-7863. PMID 17044672.
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