Chemistry:Samarium hexaboride

From HandWiki
Samarium hexaboride
CaHexaboride.png
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 234-536-3
Properties
B6Sm
Molar mass 215.22 g·mol−1
Melting point 2400 °C ±100[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Samarium hexaboride (SmB6) is an intermediate-valence compound where samarium is present both as Sm2+ and Sm3+ ions at the ratio 3:7.[2] It is a Kondo insulator having a metallic surface state.[3]

Early studies

It was first studied by soviet scientists in the early 1960s.[4] Further studies were then undertaken at Bell Laboratories.[4] By 1968 their researchers had noted changes in the electronic configuration at different temperatures.[5] At temperatures above 50 K its properties are typical of a Kondo metal, with metallic electrical conductivity characterized by strong electron scattering, whereas at low temperatures, it behaves as a non-magnetic insulator with a narrow band gap of about 4–14 meV.[6] The cooling-induced metal-insulator transition in SmB6 is accompanied by a sharp increase in thermal conductivity, peaking at about 15 K. The reason for this increase is that electrons do not contribute to thermal conductivity at low temperatures, which is instead dominated by phonons. The decrease in electron concentration reduced the rate of electron-phonon scattering.[7]

Twenty first century research

By the twenty first century condensed matter physicists grew more interested in SmB
6 with claims that it may be a topological insulator.[8][9][10] Other researchers found no evidence of topological surface states.[11]

The increasing electrical resistance with a reduction in temperature indicates that the material behaves as an insulator; however, recent measurements reveal a Fermi surface (an abstract boundary of electrons in momentum space) characteristic of a good metal, indicating a more exotic dual metal-insulating ground state.[12][13] The electrical resistivity at temperatures below 4K displays a distinct plateau,[14] which is thought to be the coexistence of an insulating state (bulk) and a conducting state (surface). At temperatures approaching absolute zero, the quantum oscillations of the material grow as the temperature declines, a behavior that contradicts both the Fermi analysis and the rules that govern conventional metals.[12][15][13] While it has been argued that quantum oscillations on samples grown from aluminium flux[16] may arise from aluminum inclusions,[17] such an explanation is excluded for samples grown by the image furnace method[12][14] rather than by the flux growth method.[16][17]

See also

References

  1. ↑ Plenum Press Handbooks of High-Temperature Materials: No. 1 Materials Index p42
  2. ↑ Nickerson, J.; White, R.; Lee, K.; Bachmann, R.; Geballe, T.; Hull, G. (1971). "Physical Properties of SmB6". Physical Review B 3 (6): 2030. doi:10.1103/PhysRevB.3.2030. Bibcode: 1971PhRvB...3.2030N. 
  3. ↑ Li, Lu; Sun, Kai; Kurdak, Cagliyan; Allen, J. W. (2020). "Emergent mystery in the Kondo insulator samarium hexaboride". Nature Reviews Physics 2 (9): 463–479. doi:10.1038/s42254-020-0210-8. ISSN 2522-5820. Bibcode: 2020NatRP...2..463L. 
  4. ↑ 4.0 4.1 Wolchover, Natalie (2015). "Paradoxical Crystal Baffles Physicists". Quanta Magazine. https://www.quantamagazine.org/samarium-hexaboride-crystal-blurs-metal-insulator-line-20150702/. Retrieved 12 May 2023. 
  5. ↑ Menth, A.; Buehler, E.; Geballe, T. H. (17 February 1969). "Magnetic and Semiconducting Properties of Sm B 6". Physical Review Letters 22 (7): 295–297. doi:10.1103/PhysRevLett.22.295. Bibcode: 1969PhRvL..22..295M. 
  6. ↑ Nyhus, P.; Cooper, S.; Fisk, Z.; Sarrao, J. (1995). "Light scattering from gap excitations and bound states in SmB6". Physical Review B 52 (20): 14308–14311. doi:10.1103/PhysRevB.52.R14308. PMID 9980746. Bibcode: 1995PhRvB..5214308N. 
  7. ↑ Sera, M.; Kobayashi, S.; Hiroi, M.; Kobayashi, N.; Kunii, S. (1996). "Thermal conductivity of RB6 (R=Ce, Pr, Nd, Sm, Gd) single crystals". Physical Review B 54 (8): R5207–R5210. doi:10.1103/PhysRevB.54.R5207. PMID 9986570. Bibcode: 1996PhRvB..54.5207S. 
  8. ↑ Botimer, J.; Kim; Thomas; Grant; Fisk; Jing Xia (2013). "Robust Surface Hall Effect and Nonlocal Transport in SmB6: Indication for an Ideal Topological Insulator". Scientific Reports 3: 3150. doi:10.1038/srep03150. PMID 24193196. Bibcode: 2013NatSR...3E3150K. 
  9. ↑ Xiaohang Zhang; N. P. Butch; P. Syers; S. Ziemak; Richard L. Greene; Johnpierre Paglione (2013). "Hybridization, Inter-Ion Correlation, and Surface States in the Kondo Insulator SmB6". Phys. Rev. X 3 (1): 011011. doi:10.1103/PhysRevX.3.011011. Bibcode: 2013PhRvX...3a1011Z. 
  10. ↑ Wolgast, Steven; Kurdak, Çağlıyan; Sun, Kai; Allen, J. W.; Kim, Dae-Jeong; Fisk, Zachary (2013). "Low-temperature surface conduction in the Kondo insulator SmB6". Phys. Rev. B 88 (18): 180405. doi:10.1103/physrevb.88.180405. ISSN 1098-0121. Bibcode: 2013PhRvB..88r0405W. 
  11. ↑ Hlawenka; Siemensmeyer; Weschke; Varykhalov; Sánchez-Barriga; Shitsevalova; Dukhnenko; Filipov et al. (2018). "Samarium hexaboride is a trivial surface conductor". Nature Communications 9 (1): 1–7. doi:10.1038/s41467-018-02908-7. PMID 29410418. Bibcode: 2018NatCo...9..517H. 
  12. ↑ 12.0 12.1 12.2 B. S. Tan; Y.-T. Hsu; B. Zeng; M. Ciomaga Hatnean; N. Harrison; Z. Zhu; M. Hartstein; M. Kiourlappou et al. (2015). "Unconventional Fermi surface in an insulating state". Science 349 (6245): 287–290. doi:10.1126/science.aaa7974. PMID 26138105. Bibcode: 2015Sci...349..287T. 
  13. ↑ 13.0 13.1 Natalie Wolchover (2 July 2015). "Paradoxical Crystal Baffles Physicists". Quanta Magazine. https://www.quantamagazine.org/samarium-hexaboride-crystal-blurs-metal-insulator-line-20150702/. 
  14. ↑ 14.0 14.1 M. Ciomaga Hatnean; M. R. Lees; D. Mck. Paul; G. Balakrishnan (2013). "Large, high quality single-crystals of the new Topological Kondo Insulator, SmB6". Nature 3 (3071): 3071. doi:10.1038/srep03071. PMID 24166216. Bibcode: 2013NatSR...3E3071H. 
  15. ↑ Borghino, Dario (July 7, 2015). "Puzzling material acts as conductor and insulator at the same time". http://www.gizmag.com/samarium-hexaboride-conductor-insulator/38335/. 
  16. ↑ 16.0 16.1 Li, G.; Xiang, Z.; Yu, F.; Asaba, T.; Lawson, B.; Cai, P.; Tinsman, C.; Berkley, A. et al. (2014-12-05). "Two-dimensional Fermi surfaces in Kondo insulator SmB6" (in en). Science 346 (6214): 1208–1212. doi:10.1126/science.1250366. ISSN 0036-8075. PMID 25477456. Bibcode: 2014Sci...346.1208L. 
  17. ↑ 17.0 17.1 S. M. Thomas; Xiaxin Ding; F. Ronning; V. Zapf; J. D. Thompson; Z. Fisk; J. Xia; P. F. S. Rosa (2019). "Quantum oscillations in flux-grown SmB6 with embedded aluminum". Physical Review Letters 122 (16): 166401. doi:10.1103/PhysRevLett.122.166401. PMID 31075018. Bibcode: 2019PhRvL.122p6401T. 



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