Chemistry:Praseodymium(III) perchlorate
From HandWiki
_perchlorate.svg)
| |
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| UN number | 3098[2] |
| |
| Properties | |
| Pr(ClO4)3 | |
| Molar mass | 439.259[1] |
| Density | 1.563[2] |
| Melting point | liquid at room temperature[2] |
| Vapor pressure | 0.21 psi (20 °C)[2] |
| Hazards | |
| R-phrases (outdated) | R8，R34[2] |
| S-phrases (outdated) | S17，S26，S27，S36/37/39，S45[2] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Praseodymium(III) perchlorate is the perchlorate salt of praseodymium, with the chemical formula of Pr(ClO4)3.[3]
Preparation
Praseodymium(III) perchlorate can be prepared from praseodymium(III,IV) oxide.[4][5] Dissolving praseodymium(III,IV) oxide in a slight excess of hydrochloric acid and adding a small amount of hydrogen peroxide can prepare praseodymium perchlorate.[5]
Chemical properties
Praseodymium perchlorate can form two complexes with crown ether 18-crown-6 in stoichiometric ratios of 1:1 and 1:2.,[6] and can form complexes with L-proline,[7] glutamic acid,[4] mandelic acid,[4] penicillamine.[4] It can also form complexes with imidazole and alanine.[5]
References
- ↑ 1.0 1.1 1.2 "Praseodymium perchlorate" (in en). http://www.chemspider.com/Chemical-Structure.11233420.html.
- ↑ 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 "Praseodymium perchlorate 13498-07-2". http://www.chemicalbook.com/ChemicalProductProperty_CN_CB6206855.htm.
- ↑ PubChem. "Praseodymium(3+) perchlorate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/13783608.
- ↑ 4.0 4.1 4.2 4.3 张若桦, 陈敬堂、江冬青 (1995). "镨(III)溶液光谱研究:高氯酸镨─谷氨酸/苦杏仁酸/青霉胺配合物". Acta Scientiarum Naturalium Universitatis Nankaiensis (1): 44－48. ISSN 0465-7942. http://www.ixueshu.com/document/87586e70d7258d12318947a18e7f9386.html. Retrieved 2017-10-21.
- ↑ 5.0 5.1 5.2 但悠梦, 胡卫兵、余华光、董家新、刘义、屈松生 (2006). "稀土配合物[Pr(C3H7NO2)2(C3H4N2)(H2O)(ClO4)3的标准生成焓及热分解动力学研究"]. Acta Chimica Sinica 64 (1): 70－78. doi:10.3321/j.issn:0567-7351.2006.01.012. ISSN 0567-7351. http://sioc-journal.cn/Jwk_hxxb/CN/abstract/abstract332941.shtml. Retrieved 2017-10-21.
- ↑ Xue Ganglin; Li Qianding; Hu Shaoming; Xu Hong; Ren Dehou; Zhuang Quanzhen (1996). "三水合高氯酸镨与18—冠—6配合物的研究" (in zh). Acta Chimica Sinica 54 (6): 568－574. ISSN 0567-7351. http://sioc-journal.cn/Jwk_hxxb/CN/Y1996/V54/I6/568. Retrieved 2017-10-14.
- ↑ 张忠海, 姜晓娟, 库宗军. 高氯酸镨与L-脯氨酸配合物的合成及热化学和热分解动力学研究[C]// 中国化学会全国化学热力学和热分析学术会议. 2006.
 |  |
