Chemistry:Cerium(IV) perchlorate
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| Names | |
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| IUPAC name
Cerium(IV) perchlorate
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Other names
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| Ce(ClO4)4 | |
| Molar mass | 537.92 g/mol |
| Density | 1.556 g/cm−3 (25 °C)[1] |
| Melting point | 725 °C (1,337 °F; 998 K) |
| Hazards | |
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| GHS Signal word | Warning |
| H272 | |
| P210, P220, P280, P370+378, P501 | |
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Other cations
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Titanium perchlorate, Zirconium perchlorate |
Related compounds
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Cerium(III) perchlorate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Cerium(IV) perchlorate is an inorganic compound composed of cerium and perchloric acid. It has the chemical formula of Ce(ClO4)4.
Uses
Cerium(IV) perchlorate is used as a catalyst in organic chemistry for the determination of strontium and for cerimetry.[3][4][5][6] It has a very high redox potential at Ce4+/Ce3+ of +1.87 V in 8 M HClO4.[7]
References
- ↑ Sigma-Aldrich Co., product no. {{{id}}}.
- ↑ "Cerium(4+) perchlorate" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/167073#section=Safety-and-Hazards.
- ↑ Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode (2016) (in German), Essential Reagents for Organic Synthesis, John Wiley & Sons, p. 80, ISBN 978-1-119-27983-9, https://books.google.com/books?id=_Ro3Fqtz4xgC&pg=PA306
- ↑ W.J. Mijs, C.R.H.I. de Jonge (2013) (in German), Organic Syntheses by Oxidation with Metal Compounds, Springer Science & Business Media, p. 601, ISBN 978-1-4613-2109-5, https://books.google.com/books?id=ow63DAAAQBAJ&pg=PA80
- ↑ E. Gagliardi, E. Wolf: Bestimmung von Strontium mit Cer(IV)-perchlorat. In: Microchimica Acta. 51, 1963, S. 578, doi:10.1007/BF01217587.
- ↑ P. H. List, L. Hörhammer (2013) (in German), Allgemeiner Teil. Wirkstoffgruppen I, Springer-Verlag, p. 301, ISBN 978-3-642-47985-4, https://books.google.com/books?id=qUfTBwAAQBAJ&pg=PA601
- ↑ K.A. Gschneidner, Jr., J.-C.G. Bünzli and V.K. Pecharsky (2006) (in German), Handbook on the Physics and Chemistry of Rare Earths, Elsevier, p. 306, ISBN 978-0-08-046672-9, https://books.google.com/books?id=ErLPBgAAQBAJ&pg=PA301
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