Chemistry:Geerite

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Short description: Copper sulfide mineral
Geerite
JL geerite 3mm.jpg
General
CategorySulfide mineral
Formula
(repeating unit)
Cu8S5
Strunz classification2.BA.05c
Crystal systemTrigonal
Crystal class32, 3m, 3m
Unit cella = 3.83 Å, c = 46.84 Å; Z = 1
Identification
Formula mass668.70 g/mol
ColorBluish white in reflected light
Crystal habitPlaty – sheet forms (e.g. micas); pseudocubic
Mohs scale hardness3.5-4
|re|er}}Metallic
DiaphaneityOpaque
Specific gravity5.61
PleochroismWeak
References[1][2][3]

Geerite is a copper sulfide mineral with the chemical formula Cu8S5. The mineral is named after the original collector, Adam Geer, of Utica, New York, US.

Crystallography

Geerite is in the crystal class 3. This means that the crystal could be inverted and then rotated by 120 degrees to return to its original position. The optical class of geerite is unknown. Geerite is anisotropic which means that it will show interference colors when it is rotated in cross polarized light and that the mineral has different properties in different directions

Discovery and occurrence

It was first described in 1980 for an occurrence as thin coatings or platelets replacing sphalerite in the type locality in De Kalb Township, Saint Lawrence County, New York. It also occurs in a magnetitechromite a serpentinite-hosted deposit in Eretria, Greece.[2] It occurs associated with spionkopite, sphalerite, tetrahedrite, chalcopyrite, malachite, azurite, brochantite, chrysocolla, cervantite, stibiconite, hemimorphite and calcite in the type locality; and with spionkopite, chalcopyrite, cobaltian pentlandite, magnetite, chromite, andradite, chlorite, diopside in the Eretria deposit.[2] It has also been reported from a variety of locations worldwide, including the Logatchev-1 hydrothermal field along the Mid-Atlantic Ridge complex.[1]

It has been used to study crystal structure and bonding in copper sulfides.[1]

See also

References

  1. 1.0 1.1 1.2 Mindat.org
  2. 2.0 2.1 2.2 Handbook of Mineralogy
  3. Webmineral data
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W.