Chemistry:Talmessite

Talmesite
Talmessite from Gold Hill Mine, Utah, US
General
Category	Arsenate mineral
Formula (repeating unit)	Ca 2Mg(AsO 4) 2 · 2H2O
Strunz classification	8.CG.05 (10 ed) 7/C.17-50 (8 ed)
Dana classification	40.02.02.05
Crystal system	Triclinic
Crystal class	Pinacoidal (1) (same H-M symbol)
Space group	P1
Identification
Formula mass	418.33 g/mol
Colour	White or colourless, pale green (nickel-rich) or brownish or pink (cobalt-rich). Colourless in transmitted light.
Crystal habit	Prismatic crystals, radiating fibrous aggregates
Twinning	Polysynthetic
Mohs scale hardness	5
Vitreous|re|er}}	Vitreous
Streak	White
Diaphaneity	Transparent to translucent
Specific gravity	3.421, cobaltoan varieties 3.574
Optical properties	Biaxial (–)
Refractive index	nα = 1.672, nβ = 1.685, nγ = 1.698
Birefringence	δ = 0.026
Pleochroism	The cobaltoan variety is pleochroic, colourless to pale rose
Other characteristics	Not radioactive. It loses water of crystallisation at 450o
References

Talmessite is a hydrated calcium magnesium arsenate, often with significant amounts of cobalt or nickel. It was named in 1960 for the type locality, the Talmessi mine, Anarak district, Iran. It forms a series with β-Roselite, where cobalt replaces some of the magnesium, and with gaitite, where zinc replaces the magnesium. All these minerals are members of the fairfieldite group. Talmessite is dimorphic with wendwilsonite (which is not a member of this group).

Members of the fairfieldite group

• Cassidyite Ca
  2(Ni²⁺,Mg)(PO
  4)
  2 · 2H₂O
• Collinsite Ca
  2(Mg,Fe²⁺)(PO
  4)
  2 · 2H₂O
• Fairfieldite Ca
  2(Mn²⁺,Fe²⁺)(PO
  4)
  2 · 2H₂O
• Gaitite Ca
  2Zn(AsO
  4)
  2 · 2H₂O
• Messelite Ca
  2(Fe²⁺,Mn²⁺)(PO
  4)
  2 · 2H₂O
• Nickeltalmessite Ca
  2Ni(AsO
  4)
  2 · 2H₂O
• Parabrandtite Ca
  2Mn²⁺(AsO
  4)
  2 · 2H₂O
• unnamed (Fe²⁺-analogue of parabrandtite) Ca
  2Fe²⁺(AsO
  4)
  2 · 2H₂O
• β-Roselite Ca
  2(Co²⁺,Mg)(AsO
  4)
  2 · 2H₂O
• Talmessite Ca
  2Mg(AsO
  4)
  2 · 2H₂O

Crystallography

The formula for talmessite is Ca₂Mg(AsO₄)₂.2H₂O. It is a triclinic mineral, crystal class 1, space group P1. There is one formula unit per unit cell (Z = 1) and the unit cell parameters are variously given as a = 5.87 Å, b = 6.94 Å, c = 5.53 Å, α = 97.3°, β = 108.7°, γ = 108.1°, or a = 5.89 Å, b = 7.69 Å, c = 5.56 Å, α = 112.633°, β = 70.817°, γ = 119.417°,. These values give a calculated specific gravity varying from 3.42 to 3.63.
The structure is dominated by chains of tetrahedral AsO₄ and octahedral [(cation-O₄(H₂O)₂)] groups that parallel the c crystal axis. The octahedral are compressed, resulting in chain disorder

Appearance

Talmessite occurs as prismatic crystals to 3 mm, as radiating fibrous aggregates or as fine crystalline aggregates; it may also be stalactitic or in crusts. Pure talmessite is white or colourless, and colourless in transmitted light, but nickel-rich varieties are pale green and cobalt-rich varieties may be brownish, pink or the purple colour typical of many cobalt minerals. The streak is white and crystals are transparent to translucent with a vitreous lustre.

Physical properties

Talmessite is a moderately hard mineral, with Mohs hardness 5, harder than fluorite but not as hard as quartz. The specific gravity calculated from the formula and the cell dimensions is 3.49, but the measured value is less for ordinary talmessite, at 3.42 and more for the cobaltoan variety, at 3.57. The mineral displays polysynthetic twinning. It is not radioactive and it loses water of crystallisation at 450^o.

Optical properties

Triclinic crystals (and orthorhombic and monoclinic crystals) have two directions in which light travels with zero birefringence; these directions are called the optic axes, and the crystal is said to be biaxial. Talmessite is triclinic, so it is biaxial.
The speed of a ray of light travelling through the crystal differs with direction. The direction of the fastest ray is called the X direction and the direction of the slowest ray is called the Z direction. X and Z are perpendicular to each other, and a third direction Y is defined as perpendicular to both X and Z; light travelling along Y has an intermediate speed. Refractive index is inversely proportional to speed, so the refractive indices for the X, Y and Z directions increase from X to Z. The refractive indices are n_α = 1.672, n_β = 1.685 and n_γ = 1.698 with slightly higher values for the cobaltoan variety of n_α = 1.695 and n_γ = 1.73 (n_β not specified). The maximum birefringence δ is the difference between the highest and lowest refractive index; for talmessite δ = 0.026.
The angle between the two optic axes is called the optic angle, 2V, and it is always acute, and bisected either by X or by Z. If Z is the bisector then the crystal is said to be positive, and if X is the bisector it is said to be negative. Talmessite may be biaxial (–) or biaxial (+). The measured value of 2V is about 90^o. Also 2V can be calculated from the values of the refractive indices, giving a value of 88°
2V depends on the refractive indices, but refractive index varies with wavelength, and hence with colour. So 2V also depends on the colour, and is different for red and for violet light. This effect is called dispersion of the optic axes, or just dispersion (not to be confused with chromatic dispersion). If 2V is greater for red light than for violet light the dispersion is designated r > v, and vice versa. For talmessite dispersion is strong, with r > v. The cobaltoan variety is pleochroic colourless to pale rose.

Occurrence

Talmessite is a rare secondary mineral formed typically in the oxidized zone of some hydrothermal mineral deposits, as an alteration product of realgar, orpiment, or Cu–Ni arsenides. Cobalt-rich varieties are found in the oxidised zone of cobalt arsenide deposits. It occurs associated with gaitite, erythrite, annabergite, picropharmacolite, pharmacolite, austinite, fluorite, baryte, aragonite, calcite and dolomite. At the type locality it is associated with aragonite and dolomite.

Localities

The type locality is the Talmessi Mine, Anarak District, Nain County, Esfahan Province, Iran, and type material is conserved at the École nationale supérieure des mines de Paris, France and at the Natural History Museum, London, England.